中国东南沿海晚白垩世长屿火山的活动过程与古环境意义SCIEI北大核心CSCD

火山是唯一能够直接反映地球深部存在岩浆的地球动力学现象,对于地球气候演变和宜居性具有重要影响。相比年轻火山,古老火山因其活动过程完整、且可能剥蚀出露多阶段火山喷发产物及岩浆通道、岩浆房等,从而为揭示火山岩浆系统演化和火山活动过程提供重要的研究窗口。本文选择中国东南沿海晚白垩世长屿破火山为研究对象,对其开展火山地质、岩石学、年代学及地球化学研究,以期揭示其火山活动历史及其对中国东南沿海白垩纪古环境的启示意义。长屿火山出露面积约100km^(2),呈近圆形分布,具有较厚的火山地层厚度(总厚度约570m),类似于破火山内的火山堆积特点。由早至晚三个喷发阶段形成的流纹质角砾凝灰岩都显示了典型的火山碎屑流相的特点,发育典型的条纹斑状结构,但表现出不同的晶屑、玻屑及岩屑含量以及熔结程度等岩相学特征,反映火山喷发从初始到高峰、再到减弱的过程,最后岩浆沿火山通道侵出形成流纹斑岩穹隆,标志着火山活动的结束。长屿火山的火山碎屑流式喷发伴随着快速的岩浆房塌陷,以及缺少普林尼式空落堆积,反映了火山活动发生在伸展的构造背景。系统的LA-ICP-MS锆石U-Pb年代学研究获得了不同阶段火山岩一致的形成年龄(97~96Ma),暗示它们具有较短的形成时限,是由同期火山岩浆活动先后喷发形成的。长屿火山岩高的SiO_(2)含量(67%~76%)以及分异的锆石微量元素地球化学特征,表明喷发岩浆来自晶粥提取的熔体,并有晶粥来源晶体的混入。此外,我们在长屿火山岩中发现了南洋杉型丝炭化木(贝壳杉型木属),暗示晚白垩世中国东南沿海地区可能为温暖湿润的亚热带山地气候环境,表明中国东南沿海白垩纪大规模火山活动,在古武夷山脉以东地区形成了地形高耸的海岸山脉。     

Mineralogical and geochemical implications of weathering rates in coastal dunes and beach sands close to a volcanic rock source in the western Gulf of Mexico,Mexico

Coastal dune (CD) and beach sand samples were mineralogically and chemically studied to assess the weathering rates in a coastal area surrounded by the Trans-Mexican Volcanic Belt (TMVB). The study area is a narrow coastal plain with sub-humid warm weather and vigorous coastal dynamics located in the Western Gulf of Mexico (WGM). Our results show that the grain size parameters remain homogeneous along nine CD and beach sites, probably due to the hydrodynamic mechanisms prevailing in the area, i.e. wind deflation, longshore currents, and waves. The minerals found in the CD and beach sands are enriched in recycled, highly corroded monocrystalline quartz (Qm), with loss of plagioclase (P) and olivine (ol), with ilmenite fractions (op) especially in the northern sites. The geochemical data show that the sands are controlled by the exhumation of the TMVB rocks composed of a high volcanic lithic content with lathwork, microlithic, and negligible vitric textures. These volcanic fractions are in agreement with the presence of lavas of calc alkaline, andesite, Na-alkaline lavas, and rhyolite tuffs derived from the TMVB. Significant Spearman Rank Correlations (SRCs) resulted from high silica, titanium, iron, magnesium, calcium, vanadium, chromium, cobalt, associated with the presence of Qm, ilmenite, clinopyroxene, shell fragments, and volcanic lithics. Monocrystalline quartz enrichments, compared to a quartz dilution effect (<Qm; < Qm) at the northern and southern beach sites, reflect the vigorous coastal dynamics. The presence of ilmenite lag deposits in the northern sites indicate that high energy hydrodynamic conditions prevail at the site. The rare earth element (REE) patterns support the mineralogical and compositional framework of the CD and beach sands as part of the TMVB exhumation. We used various chemical indices such as the Chemical Index of Alteration (CIA), the Chemical Index of Weathering (CIW), the Plagioclase Index of Alteration (PIA), and the Weathering Index of Plagioclase (WIP). The WIP values reflect the depletion of mobile elements such as Ca, Na, K, and enrichment of Qm at the northern beach sites, e.g. the Istirinchiá site. The CIA/WIP ratio of 2.13 indicates intermediate weathering under warm climatic conditions and recycling of CD and beach sands.     

伊洛瓦底江上游水系形成时代研究——以滇西龙川江为例

研究伊洛瓦底江水系的发育历史对理解青藏高原东南缘的生长具有重要意义,但是长期以来对其形成时代的研究一直比较薄弱。通过研究伊洛瓦底江上游支流的演化可为认识其水系的发育提供重要线索。龙川江是伊洛瓦底江的一级支流,发源于高黎贡山,流经腾冲芒棒盆地。研究表明在上新世时期芒棒盆地曾被一中型湖泊所占据,现代意义上的龙川江并不存在。龙川江在芒棒盆地内同时切割了上新世中晚期和早更新世的火山岩,腾冲地区早更新世火山岩的K-Ar年龄为0.84~1.4 Ma,说明现代龙川江的出现可能不会早于0.80 Ma,由此推测伊洛瓦底江上游水系可能也是0.80 Ma以来形成的。晚新生代以来东喜马拉雅构造结的强烈构造活动可能是其水系形成与演化的动力来源。     

藏南仲巴地区早白垩世日朗组物源分析及其构造意义

藏南仲巴地区早白垩世日朗组出露于特提斯喜马拉雅北亚带,整体为黄绿色火山岩屑砂岩,局部层位可见页岩与泥岩,分析为一套深海海底扇沉积组合。本文仔细分析了日朗组砂岩岩石学特征及鲍马序列和槽模沉积构造等沉积学特征,结果表明:日朗组砂岩成分成熟度和结构成熟度均不高,具有近源物源的特点;槽模构造古水流数据统计表明古流向由南向北,指示物质组分来源于南侧特提斯喜马拉雅和/或印度克拉通。砂岩碎屑组分统计结果表明日朗组的物源区构造背景属于克拉通内部及石英再旋回区。碎屑锆石U-Pb年龄频谱图对比进一步表明其物源区为印度稳定大陆边缘,外加一套早白垩世火山碎屑物质的输入。仲巴地区日朗组物源特征反映了印度大陆北缘早白垩世由深部断裂引起的一次强烈的火山事件,可能与印度大陆从澳大利亚-南极大陆裂解有关。     

西藏那曲中酸性火山岩的锆石U-Pb年龄、Hf同位素和地球化学特征及岩石成因

西藏拉萨地块北部广泛分布着中生代岩浆岩,然其岩浆源区和岩石成因仍存在多种争议。本文对那曲地区中酸性火山岩进行了全岩地球化学、LA-ICPMS锆石U-Pb年龄和Hf同位素的研究。结果显示:1)那曲地区粗面安山岩的时代为111.9±1.2Ma,英安岩为109.2±3.5Ma,二者在误差范围内一致,均为早白垩世;2)火山岩Si O2为51.88%~74.62%,具有低MgO含量(0.37%~3.65%),并且样品大多显示较低的Mg#(16~40)值。岩石为过铝质特征,在原始地幔标准化蛛网图上显示Th-U正异常,而Nb、Ta、P、Ti等负异常。稀土元素整体表现为轻稀土富集、重稀土亏损的趋势,且轻重稀土分异程度强,(La/Yb)N=8.79~14.85,具负Eu异常(δEu=0.46);3)那曲中酸性火山岩体的锆石Ti温度计为720℃左右。锆石Ce(Ⅳ)/Ce(Ⅲ)300,普遍在2~250之间,指示岩浆具有低的氧逸度;4)那曲中酸性火山岩锆石εHf(t)值大多集中在-7.7~0.5之间,对应的Hf模式年龄(tCDM)为918~1336Ma。综合以上岩石学和地球化学数据,认为那曲中酸性火山岩为壳幔混合成因,可能是在班公湖-怒江洋壳南向俯冲引起板片断离背景下,羌塘与拉萨地块碰撞引起地壳加厚继而发生部分熔融,并加入了少量的受早期流体交代的安多微陆块古老岩石圈地幔物质,且其熔融产物经历了不同程度的分离结晶作用。     

三江造山带兰坪盆地东缘火山岩锆石U-Pb年代学、Hf同位素组成

青藏高原东南缘"三江"复合造山带南、北两段发育若干火山-岩浆岩带,随着火山岩年代学、地球化学数据的积累,其时空关系渐趋清晰。但由于中-新生界沉积覆盖,这些火山岩带向南常终止于兰坪盆地附近,致使火山岩时空构架不明。兰坪盆地东部弥沙地区出露盆地基底岩石,由两个构造层组成,上部为碎屑岩及生物碎屑灰岩,下部出现大量火山碎屑物质。含火山岩段出露厚约150m,可分为三个喷发-沉积韵律,由流纹质熔结凝灰岩、晶屑岩屑熔结凝灰岩组成的火山碎屑岩与紫红、灰黑色泥岩、大理岩组成的沉积岩相间组成。火山岩锆石LA-ICP-MS U-Pb数据表明,岩浆活动始于或早于258Ma,一直持续到248Ma。锆石原位Lu-Hf分析结果显示,早期岩浆包含较多幔源物质,而晚期岩浆则几乎完全由古老地壳局部熔融形成。本文提供的新数据表明,兰坪盆地东缘火山岩与三江造山带其它地区古特提斯洋俯冲阶段火山岩具有一致的年代学组成、相同的Hf同位素变化规律,可能属于发育在扬子板块西缘之上江达-维西-云县弧火山岩带。     

西准噶尔塔尔巴哈台-谢米斯台地区火山热液型铜矿床(点)地质及含矿火山岩年代学、地球化学特征

西准噶尔塔尔巴哈台-谢米斯台地区研究和找矿勘探工作十分薄弱,近年来随着谢米斯台铜矿的发现,本项目组陆续发现了喀因德、乌兰浩特、阿依德、巴汗等铜矿点,指示该区具有与火山热液活动有关的铜成矿作用有的潜力。本文对这些矿床(点)开展了地质特征、年代学和地球化学研究显示,区内发育的阿尔木强、谢米斯台铜矿床以及喀因德、乌兰浩特、阿依德、巴汗等铜矿点与火山岩地层密切相关,矿化主要表现为黄铁矿化、孔雀石化,发育绿帘石化、绿泥石化、硅化、碳酸岩化等蚀变,具有火山热液型铜矿特点。锆石LA-ICP-MS U-Pb测年获得喀因德铜矿点火山岩年龄为455.1±5.4Ma,乌兰浩特铜矿点火山岩年龄为428.6±4.6Ma,阿依德铜矿点火山岩年龄为428.8±7.2Ma,谢米斯台铜矿床火山岩年龄为424.3±4.3Ma,阿尔木强铜矿床火山岩年龄为426.7Ma,巴汗铜矿点火山岩年龄为411.7±4.7Ma,可分为晚奥陶世、中志留世、早泥盆世三个阶段,以中志留世为主。地球化学特征显示晚奥陶世、中志留世、早泥盆世三个阶段的火山岩均形成于岛弧环境;且具有类似的岩浆源区和演化过程;岩浆在上升侵位过程中没有明显的受到外来物质混染。综合地质、年代学和地球化学特征显示,塔尔巴哈台-谢米斯台地区与火山热液有关的铜矿床(点)主要受控于构造背景、地层组合、岩石类型、蚀变、控矿构造等因素,其中中志留世中基性火山岩、与火山机构相关的深部可能存在的次火山岩或浅成侵入岩分布区具有较好的找矿潜力。     

Paleoenvironmental reconstruction of the coastal Monte Léon and Santa Cruz formations (Early Miocene) at Rincón del Buque,Southern Patagonia: A revisited locality

Sedimentological, ichnological and paleontological analyses of the Early Miocene uppermost Monte León Formation and the lower part of the Santa Cruz Formation were carried out in Rincón del Buque (RDB), a fossiliferous locality north of Río Coyle in Santa Cruz Province, Patagonia, Argentina. This locality is of special importance because it contains the basal contact between the Monte Léon (MLF) and the Santa Cruz (SCF) formations and because it preserves a rich fossil assemblage of marine invertebrates and marine trace fossils, and terrestrial vertebrates and plants, which has not been extensively studied. A ∼90 m-thick section of the MLF and the SCF that crops out at RDB was selected for this study. Eleven facies associations (FA) are described, which are, from base to top: subtidal–intertidal deposits with Crassotrea orbignyi and bioturbation of the Skolithos-Cruziana ichnofacies (FA1); tidal creek deposits with terrestrial fossil mammals and Ophiomorpha isp. burrows (FA2); tidal flat deposits with Glossifungites ichnofacies (FA3); deposits of tidal channels (FA4) and tidal sand flats (FA5) both with and impoverish Skolithos ichnofacies associated; marsh deposits (FA6); tidal point bar deposits recording a depauperate mixture of both the Skolithos and Cruziana ichnofacies (FA7); fluvial channel deposits (FA8); fluvial point bar deposits (FA9); floodplain deposits (FA10); and pyroclastic and volcaniclastic deposits of the floodplain where terrestrial fossil mammal remains occur (FA11).The transition of the MLF–SCF at RDB reflects a changing depositional environment from the outer part of an estuary (FA1) through the central (FA2–6) to inner part of a tide-dominated estuary (FA7). Finally a fluvial system occurs with single channels of relatively low energy and low sinuosity enclosed by a broad, low-energy floodplain dominated by partially edaphized ash-fall, sheet-flood, and overbank deposits (FA8–11). Pyroclastic and volcaniclastic materials throughout the succession must have been deposited as ash-fall distal facies in a fluvial setting and also were carried by fluvial streams and redeposited in both estuarine and fluvial settings. These materials preserve most of the analyzed terrestrial fossil mammals that characterize the Santacrucian age of the RDB's succession. Episodic sedimentation under volcanic influence, high sedimentation rates and a relatively warm and seasonal climate are inferred for the MLF and SCF section.Lateral continuity of the marker horizons at RDB serve for correlation with other coastal localities such as the lower part of the coastal SCF south of Río Coyle (∼17.6–17.4 Ma) belonging to the Estancia La Costa Member of the SCF.     

松辽盆地含CO_2火山岩气藏的形成和分布

松辽盆地特有的深部构造背景和裂谷演化特征,造成盆地内含CO_2火山岩气藏的形成和富集。松辽裂谷盆地中新生代火山岩浆活动发育,总体上具有多期喷发、分布广泛和储集条件良好的特点。火山活动以中心式喷发为主,主要发育中基性-酸性火山岩,发育流纹岩、凝灰岩等多种岩石类型,爆发相和溢流相2种火山岩相。中生代火山岩在盆地内分布广泛,营域组构成深层有利储层,新生代火山岩在盆地外围出露较多,而在盆内出露较少。盆地高含量的二氧化碳为无机幔源成因,由青山口期和新生代幔源岩浆脱气形成。含CO_2火山岩气藏的形成主要受深部构造背景、深大断裂和中新生代火山岩控制。已发现含CO_2火山岩气藏主要分布于古中央隆起带及其两侧断陷的营城组火山岩中,具有点状、带状分布,局部富集的特点。根据主控因素分析,预测了5个CO_2富集区带。     

Geochronological and petrological investigations of Miocene felsic igneous rocks in the Amakusa Islands,southwest Japan: Possible extension of the Setouchi Volcanic Belt

The opening of the Japan Sea led to the separation of southwest Japan from the Eurasian continent. Subsequent to this event, a diverse range of igneous activities occurred in southwest Japan. On the back-arc side of the region, igneous activity commenced at approximately 22 Ma and persisted for an extended period. In the trench-proximal region of southwest Japan, magmatism initiated around 15.6 Ma, immediately following the cessation of the Japan Sea opening, in correlation with the subduction of the Philippine Sea plate beneath southwest Japan. The Amakusa Islands in western Kyushu host felsic to intermediate igneous rocks with Miocene radiometric ages. There has been a debate regarding the attribution of the igneous rocks in Amakusa Island among the Miocene igneous rocks in southwest Japan. To address this issue, we conducted zircon U–Pb dating and analyzed the major- and trace-element compositions of felsic igneous rocks in the Amakusa Islands to elucidate their characteristics. The obtained U–Pb ages range from 14.5 to 14.8 Ma, suggesting contemporaneity between magmatism in the Amakusa Islands and the Setouchi Volcanic Rocks in the trench-proximal region of southwest Japan. The major and trace element compositions of the felsic igneous rocks exhibit similarities to the dacites of the Setouchi Volcanic Rocks. These findings support previous suggestions that the magmatism in the Amakusa Islands can be correlated with the Setouchi Volcanic Rocks, based on the discovery of a high-Mg andesite dike and paleo-stress analysis utilizing the direction of dikes and sills. Therefore, the Setouchi Volcanic Belt is proposed to extend further west than the previously identified Ohno volcanic rocks in eastern Kyushu. The subduction of the Shikoku Basin of the Philippine Sea plate toward western Kyushu supports the hypothesis that the Kyushu-Palau Ridge was positioned west of Kyushu at ~15 Ma.