Physicochemical properties of fine aerosols at Plan d'Aups during ESCOMPTE

The physical and chemical properties of aerosol particles were investigated at Plan d'Aups, one of the ESCOMPTE sites located in the St. Baume mountain area (700 m a.s.l.), 50 km east of Marseilles (France). The site is ideally located for assessing the vertical and horizontal extent of the pollution plume from the Marseilles–Berre area.Our study showed that polluted air masses from the Marseilles–Berre area are advected to Plan d'Aups in the early afternoon. Average daily concentration of particles reaches up to 40 μg m⁻³ while 1-h average particle number concentration is greater than 30,000 cm⁻³. Most of the particle mass is composed of SO₄²⁻ and organic carbon (OC). The chemical properties of the particles revealed that an additional source, possibly from the industrial area of Gardanne, contributes to the aerosol mass. This last source is characterised by significant emissions of elements, such as Zn, V, Al and Si.In addition to transport, we found that gas-to-particle conversion takes place at the interface between the free troposphere and the boundary layer. We estimated that on average, 30% of the particle number is accounted for by direct nucleation. This is potentially a major aerosol source to the free troposphere.     

Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil

Effect of chemical fertilizers (urea, NH₄Cl, Ca(NO₃)₂, KCl and KH₂PO₄) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure, it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil. Applying urea (CO(NH₂)₂) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH₄Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH₂)₂ raised the soil pH from 4.51 to 4.96, whereas NH₄Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH₂PO₄ reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual (RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH₄Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH₂PO₄ decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil.     

化学试剂管理数据库的设计与开发——以华东地质学院化学试剂管理数据库为例

论述了采用客户／服务器模型设计、实现化学试剂管理数据库的方法和技术。通过网络平台完成院各部门的年度化学试剂申报、统计和管理工作，可以充分发挥校园网的通讯优势。解决了长期存在的化学试剂手工管理所带来的效率低、申报不及时甚至重复申报等问题。     

从已发现的油气田看中国海相油气勘探

中国海相油气勘探的主要目标是古生界碳酸盐岩,在漫长的演化历程中它的主要成藏类型是准原生型。对形成保存至今的工业油气藏来说,碳酸盐岩中有效烃源岩的总有机碳含量下限应≥0.5%,滨海相或海陆交互相煤系可对生烃作出重大贡献。碳酸盐岩中的储集体受裂缝—岩溶发育程度的控制而分为三种基本类型:(1)以孤立的缝洞储集体为主者称纳溪型,各储集体内的流体性质、压力均可有不同;(2)各储集体间相互连通从而有统一的压力和气、油、水界面,若其似块状者称任丘型,若其似层状者则称威远型;(3)居于这两个端元间的过渡类型为塔河型,其各部分之间的流体性质和压力可有一定差别,无统一油水界面。应注意对似层状储集体的勘探研究,保存条件的好坏对海相油气田有决定性的意义。在分析复杂的多期成藏史中,要注意古隆起和晚期成藏的辩证关系。我国的海相油气勘探有难度,要重新评价有效和高效烃源岩,从较浅部和次生油气蒇入手逼近油气源,寻找主力油气藏,要重视岩性圈闭和各构造(形变)层间的不吻合性。中国的海相油气勘探方向可分为优先勘探、立争突破、劣中选优三个层次。     

农业生态的化学元素分类及其与作物优质高产的关系

利用国家科学技术成果，并根据国内外研究现状，将103个化学元素分成对作物生长发育、增产起显著作用、起一定作用、起有害作用和起未知作用4个农业生态元素类型，进而论述了它们与作物优质高产的关系。     

不同方案求解非线性化学动力学方程组的比较

在一个简化的气相化学模式的基础上，比较了Ｈｙｂｒｉｄ、ＱＳＳＡ、Ｓｋｌａｒｅｗ三种计算方案求解非线性化学动力学方程组的差异，并引入误差分配和线性组合两种质量守恒技术，分析它们对模拟结果的影响．研究结果表明：不同方案对有机烃类浓度的计算几乎没有影响，但对其它气态物浓度有一定的影响．用ＱＳＳＡ和Ｓｌａｒｅｗ方案预测的结果更为相近，而采用Ｈｙｂｒｉｄ方案得到的气态物浓度的平衡时间略为提前．从计算效率来看，ＱＳＳＡ方案优于其它两种方案，两种质量守恒技术均能改善模拟结果．     

The Geothermal Study of the Mid-Segment of the Tancheng-Lujiang Fault Zone and Its Neighboring Region

In this paper,25 new terrestrial heat flow values newly observed along the mid-segment of the Tancheng-Lujiang fault zone are listed.With these geothermal data and 37 other terrestrial heat flow values(previously published),we describe the distribution features of terrestrial heat flows in the area.In this research,the two-dimensional temperature structure from the surface to lithospheric bottom of the Huaibei-Sixian-Jinhu profile is inferred by using the finite-element method and the temperature and heat flow of sedimentary,granitic,and basaltic layers is calculated.     

激光荧光遥感系统在地物识别上的应用研究

应用我国自行研制组装的激光荧光遥感系统,测试了包括岩石、土壤、植物、水体以及人工建筑材料在内的各种样品的激光诱导荧光光谱。研究结果表明,应用地物荧光峰的位置、强度及它们的组合指标,不仅能区分上述各基本类型的地物,而且还能往下级单元续分。还表明,激光荧光遥感系统具有相当广泛的应用前景,在某些方面可望超过当前常用的、以反射光谱为基础的被动式遥感。     

广义Radon变换与叠前地震数据处理

在本文中,首先讨论了与几种地震层析成像对应的Radon变换公式,并导出了叠前地震记录的数学模型.在分析叠前地震记录与广义Radon变换的关系的基础上,讨论了速度分析、滤波、动校正、叠加等地震数据处理的数学物理意义.为展示广义Radon变换在地震数据处理中的应用,给出了用于滤波和消除多次波的方法及算例.     

福建上杭紫金山铜金矿床地质简介

以宏观角度介绍紫金山铜金矿床地质背景,论述了火山机构、次火山岩、隐爆角砾岩、围岩及围岩蚀变、矿化带及矿化特征,着重总结该矿床找矿标志,以期在地质找矿中得以借鉴。