GRADIENT DISTRIBUTION OF ACID RAIN IN THE SCENIC RESORT OF THE BAIYUN MOUNTAIN IN GUANGZHOU

1 INTRODUCTION Sitting in the central part of the Pearl River Delta, Guangzhou is one of the cities in China that are most polluted by acid rain. Broad attention has been brought to the problem. Since the early 1980s, a series of observation and studies h…     

The Shape and Volume of the Skaergaard Intrusion, Greenland: Implications for Mass Balance and Bulk Composition

Re-examination of the Skaergaard intrusion in the context ofits regional setting, combined with new data from explorationdrilling, has resulted in a revised structural model for theintrusion. It is modelled as an irregular box, c. 11 km fromnorth to south, up to 8 km from east to west, and 3·4–4km from the lower to the upper contact. The walls of the intrusionare inferred to follow pre-existing and penecontemporaneoussteep faults, and the floor and roof seem largely controlledby bedding planes in the host sediments and lavas, similar toregional sills. The suggested shape and volume are in agreementwith published gravimetric modelling. Crystallization alongall margins of the intrusion concentrated the evolving meltin the upper, central part of the intrusion, best visualizedas an ‘onion-skin’ structure inside the box. Thetotal volume is estimated to c. 280 ± 23 km³, of which13·7% are referred to the Upper Border Series (UBS),16·4% to the Marginal Border Series (MBS) and 69·9%to the Layered Series (LS). In the LS, the Lower Zone (LZ) isestimated to constitute 66·8%, the Middle Zone (MZ) 13·5%and the Upper Zone (UZ) 19·7%. The new volume relationshipsprovide a mass balance estimate of the major and trace elementbulk composition of the intrusion. The parental magma to theSkaergaard intrusion is similar to high-Ti East Greenland tholeiiticplateau basalts with Mg number c. 0.45. The intrusion representsthe solidification of contemporary plateau basalt magma trappedand crystallized under closed-system conditions in a crustalreservoir at the developing East Greenland continental margin. KEY WORDS: bulk composition; emplacement; mass proportions; Skaergaard intrusion; structure     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.     

HJ-1复合型钻井液的研究及应用

分析和探讨了HJ-1复合型钻井液对复杂地层护壁的作用机理及护壁性能试验情况，介绍了其在寨上矿区复杂地层钻探中的成功应用。     

Texture and petrology of modern river, beach and shelf sands in a volcanic back-arc setting, northeastern Japan

Abstract The focus in the present study is on characterizing spatial patterns of textural and petrological variabilities, and on evaluating mechanisms influencing the textural and petrological components of modern river, beach and shelf sands in a volcanically active back‐arc tectonic setting. Abashiri Bay and the surrounding area in eastern Hokkaido, Japan, has volcanic source land within a back‐arc region associated with subduction of the Pacific Plate beneath the Okhotsk (North American) Plate. A total of 41 river, beach and shelf sands were obtained for grain‐size and modal composition analyses. Multivariate analytical techniques of hierarchical cluster and principal component analyses were performed on the textural and petrological data for investigating relations among quantitative variables. On the basis of grain‐size data, four sedimentary zones were identified: zone I, palimpsest zone; zone II, relict zone; zone III, modern (proteric) zone; zone IV, coastal sedimentary zone. All sands are feldspatholithic and quartz‐deficient. The framework (quartz, feldspar and rock fragment) modal compositions were also classified into four clusters, A–D. The characteristic components of each cluster are as follows: cluster A, felsic volcanic rock fragments; cluster B, andesitic–basaltic volcanic rock fragments; cluster C, mixed or plagioclase; cluster D, sedimentary rock fragments. Almost all sands in western and central Abashiri Bay belong to cluster A, where the original compositions are influenced by Kutcharo pyroclastic flow deposits. Andesitic–basaltic lava and Neogene volcaniclastic and sedimentary rocks have a major influence on the compositions of shelf sands in eastern Abashiri Bay. The modal compositions are basically controlled by the source lithology. Compositional maturity (percentage of quartz to feldspar and rock fragments; Q/FR%) slightly increased, in order, from river (1.2), zone IV (coastal, 1.7), zone II (relict, 2.2), zone I (palimpsest, 3.6), to zone III (modern proteric, 7.0). Greater maturity in the recycled sediments is indicative of weathering under the sea or abrasion by transportation induced by sea‐level fluctuations, waves, or sea currents. Several controlling factors – (i) source lithological; (ii) mineralogical; (iii) climatic; and (iv) geomorphological controls – might still cause low maturity through all sedimentary zones other than the continental margin sands previously reported.     

Energetic Particles Observed in the CUSP Region During a Storm Recovery Phase

In this paper we report energetic ion behavior and its composition variations observed by the Cluster/RAPID instrument when the spacecraft was travelling in the high latitude magnetospheric boundary region on the day of the 31 March, 2001, strongest magnetic storm in the past 50 years. The Dst index reached −360 nT at about 09:00 UT. During its early recovery phase, large amounts of oxygen and helium ions were observed; the ratio of oxygen to hydrogen in the RAPID energy range reached as high as 250%, which suggests that the observed energetic particles might be of magnetospheric origin. The observations further show that enhanced energetic electron fluxes are confined in a very narrow region, while protons have occupied a larger region, and heavy ions have been observed in an even larger region. The flux of energetic electrons show a slight enhancement in a region where the magnetic field magnitude is around zero. These observed energetic ions could be quasi-trapped by the current sheet in the stagnation region of the cusp.     

Variations of U and Sr isotope ratios in Alsace and Luxembourg rain waters: origin and hydrogeochemical implications

Major and trace element concentrations, as well as Sr and U isotope ratios, were measured in rainwater samples collected in three different locations in Alsace (East of France) and Luxembourg: a mid-altitude mountain site (Aubure Environment HydroGeochemical Observatory), an urban site (Strasbourg) and a peri-urban site located in an area of well developed industrial activity (Esch-sur-Alzette in Luxembourg). Results highlight the quite high spatial and temporal variability of the chemical and isotopic characteristics of rainwater at the regional scale. They also suggest a quite systematic contribution of a local component in the chemical composition of rainwater. In urban and peri-urban sites, the local component is certainly linked to human activities, as it is well illustrated in this study with the Esch-sur-Alzette samples. On the other hand, for the Aubure site, i.e. a small forested watershed of mid-altitude mountain, data presented in this study demonstrate the influence of the vegetation on the chemical composition of rainwater for alkali and calc-alkali elements, as well as for the Sr isotope ratios. Such a result questions the reliability of the method classically used to estimate the rainwater contribution on the river chemical budget. In addition, data of the present study confirm the very low content of uranium in rainwater and demonstrate, especially through the U isotope analysis of Aubure rainwater, the negligible effect of rainwater on U budget of river waters. This work thus outlines the property of U to be a geochemical tracer specific of weathering fluxes carried by rivers. To cite this article: F. Chabaux et al., C. R. Geoscience 337 (2005).     

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).