Automatic equipment to monitor groundwater radon

Prototype instrumentation, able to automatically measure groundwater radon content variations, is presented. The equipment is made of stainless steel and has spherical valves with automatic and pneumatic control. The deemanation of the gases from the water is obtained by evacuating a suitable expansion chamber. The instrumentation can make discrete sampling ranging from 1 per hour to 1 per 99 hours. The equipment was tested in the laboratory: the efficiency was measured by means of a²⁶⁶Ra solution. A mean value of (0.65±0.07) count/s/Bq was obtained. A calibration test was carried out by comparing countings from the automatic equipment with those obtained by the standard laboratory cell. Results of an operational check over a period of approximately one year indicate that variations in radon at the calibration site are attributable more to meteorological than to tectonic causes.     

Strain analysis in Jurassic argillites of the Monte Sirino area (Lagonegro Zone,southern Apennines,Italy) and implications for deformation paths in pelitic rocks

Analysis of strain in Jurassic argillites forming part of the folded and thrusted sedimentary succession of the Lagonegro basin (southern Italian Apennines) has been carried out using ellipsoid-shaped reduction spots as strain markers. Most of the determined finite strain ellipsoids are of oblate type and show a peculiar distribution of the maximum extension direction (X), with maxima either subparallel or subperpendicular to the local fold axes. Using the strain matrix method, two different deformation histories have been considered to assist the interpretation of the observed finite strain pattern. A first deformation history involved vertical compaction followed by horizontal shortening (occurring by a combination of true tectonic strain and volume loss), whereby all strain is coaxial and there is no change in the intermediate axis of the strain ellipsoid. By this type of deformation sequence, which produces a deformation path where total strain moves from the oblate to the prolate strain field and back to the oblate field, prolate strain ellipsoids can be generated and may be recorded where tectonic deformation has not been large enough to reverse pretectonic compaction. This type of deformation history may be of local importance within the study area (i.e. it may characterize some fold hinge regions) and, more generally, is probably of limited occurrence in deformed pelitic rocks. A second deformation sequence considered the superposition of pre-tectonic compaction and tectonic strain consisting of initial layer-parallel shortening followed by layer-parallel shear (related to flexural folding). Also in this instance, volume change during tectonic deformation and tectonic plane strain have been assumed. For geologically reasonable amounts of volume loss due to compaction and of initial layer-parallel shortening, this type of deformation history is capable of producing a deformation path entirely lying within the oblate strain field, but still characterized by a changeover, during deformation, of the maximum extension axis (X) from a position parallel to the fold axis to one perpendicular to it. This type of deformation sequence may explain the main strain features observed in the study area, where most of the measured finite strain ellipsoids, determined from the limb regions of flexural folds, display an oblate shape, irrespective of the orientation of their maximum extension direction (X) with respect to the local structural trends. More generally, this type of deformation history provides a mechanism to account for the predominance of oblate strains in deformed pelitic rocks.     

青藏高原腹地湖泊沉积对第四纪晚期古季风变化的响应

通过对青藏高原腹地的综合科学考察和对中心钻孔岩芯剖面的最新研究,用层序地层学与年代地层学和气候地层学相结合的方法,分辨出可可西里地区湖泊沉积记录(孔深7.25 m)的第四纪晚期距今3万余年以来的古气候变化,沉积物磁化率等因子综合表征的高原古季风变化是波动发展的,发生在仙女木期地质环境事件中的季风活动具有强烈暴发的特点,是高原季风发展中的突变事件,而且地表热点效应对其起到了激发作用。综合分析的研究成果表明,它的变化频谱与激变因子及其运行机制是伴随着青藏高原地质效应的演变而发展的,为研究第四纪冰消期以来的气候变化提供了新的信息。     

Tectonic relation between northeastern China and the Korean peninsula revealed by interpretation of GRACE satellite gravity data

The major continental blocks in northeastern Asia are the North China block and the South China block, which have collided starting from the Korean peninsula. Geologic and geophysical interpretations reveal a well defined suture zone in northeastern China from Qinling through Dabie to Jiaodong. The discovery of high-pressure metamorphic rocks in the Hongseong area of the Korean peninsula, prominent evidence for the collision zone, indicates extension of the collision zone in northeastern China into the Korean peninsula. Interpretation of the GRACE satellite gravity dataset shows two prominent structural boundaries in the Yellow Sea. One extends from the Jiaodong Belt in eastern China to the Imjingang Belt in the Korean peninsula. The other extends from near Nanjing, eastern China, to Hongseong. Tectonic movement in or near the suture zone may be responsible for seismic activity in the western Korean peninsula and the development of the Yellow Sea sedimentary basin.     

Palaeozoic and Mesozoic tectonic evolution and palaeogeography of East Asian crustal fragments: The Korean Peninsula in context

East and Southeast Asia comprises a complex assembly of allochthonous continental lithospheric crustal fragments (terranes) together with volcanic arcs, and other terranes of oceanic and accretionary complex origins located at the zone of convergence between the Eurasian, Indo-Australian and Pacific Plates. The former wide separation of Asian terranes is indicated by contrasting faunas and floras developed on adjacent terranes due to their prior geographic separation, different palaeoclimates, and biogeographic isolation. The boundaries between Asian terranes are marked by major geological discontinuities (suture zones) that represent former ocean basins that once separated them. In some cases, the ocean basins have been completely destroyed, and terrane boundaries are marked by major fault zones. In other cases, remnants of the ocean basins and of subduction/accretion complexes remain and provide valuable information on the tectonic history of the terranes, the oceans that once separated them, and timings of amalgamation and accretion. The various allochthonous crustal fragments of East Asia have been brought into close juxtaposition by geological convergent plate tectonic processes. The Gondwana-derived East Asia crustal fragments successively rifted and separated from the margin of eastern Gondwana as three elongate continental slivers in the Devonian, Early Permian and Late Triassic–Late Jurassic. As these three continental slivers separated from Gondwana, three successive ocean basins, the Palaeo-Tethys,. Meso-Tethys and Ceno-Tethys, opened between these and Gondwana. Asian terranes progressively sutured to one another during the Palaeozoic to Cenozoic. South China and Indochina probably amalgamated in the Early Carboniferous but alternative scenarios with collision in the Permo–Triassic have been suggested. The Tarim terrane accreted to Eurasia in the Early Permian. The Sibumasu and Qiangtang terranes collided and sutured with Simao/Indochina/East Malaya in the Early–Middle Triassic and the West Sumatra terrane was transported westwards to a position outboard of Sibumasu during this collisional process. The Permo–Triassic also saw the progressive collision between South and North China (with possible extension of this collision being recognised in the Korean Peninsula) culminating in the Late Triassic. North China did not finally weld to Asia until the Late Jurassic. The Lhasa and West Burma terranes accreted to Eurasia in the Late Jurassic–Early Cretaceous and proto East and Southeast Asia had formed. Palaeogeographic reconstructions illustrating the evolution and assembly of Asian crustal fragments during the Phanerozoic are presented.     

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.     

Studies on environment protection of vanadium exploitation in open air

Vanadium, improving mechanism and jointing capacity of steel products, is a kind of excellent additive during steel-making and its industry gets support from national industry policy. On account of shallow buried depth and low technique request of exploitation, there is much exploitation by local people lacking system management and technique guidance in area rich in vanadium since years ago, which damages regional environment dramatically. Accordingly, taking stone coal-vanadium as an example, the paper focuses on environment impact on water environment and eco-environment caused by exploitation in open air. Impact of exploitation on surface water mainly includes mining drainage and eluviated water of stock yard. According to civilian exploitation in the area, the rock suffers man-made disturbance, therefore, water quality indicators of mining drainage like heavy metal, permanganate, CI, SO4^2-, F are able to be analogies of ground water quantity in the region since the primary component of drainage is surrounding rock ground water. Water monitoring result of local well shows as follows： pH 6.68, SO4^2- 5.76 mg/L, F- 0.005 mg/L, Fe 0.025 mg/L, Mo 8.08 μg/L, Ni 5.91 μg/L, Co 0.61 μg/L, and all of them reach corresponding standard of water quality. Ground water turns into acid mine water by oxygenation after it discharges and with the help of sulfur the acid water contains nocuous elements which permeate in groundwater and surface water arousing pollution. The value of pH in the range of standard indicates that the acidification of mine water is relatively weak in the diggings. Eco-environment damage is another aspect that cannot be ignored, it acts as： （1） peeling work and establishment construction destroy landform; （2） stack of waste soil and rock occupies amounts of land; （3） various exploitation activities like vegetation peeling, landform change will enlarge the scope or enhance the intensity of soil erosion, which destroys eco-environment by leading water and soil loss;     

Heavy metal contents in soil of major towns in the east coast of Peninsular Malaysia

A total of 63 soil samples from 3 different soil profiles （urban, suburban and industrial areas） in major towns in the east coast of Peninsular Malaysia were analyzed for the total concentrations of Cu, Zn, Pb, Ni and Cr. The soil samples were subjected to acid digestion and the concentrations of total metals extracted were measured or flame atomic absorption spectrometry and inductively coupled plasma - atomic emission spectrometry. According to the result of this study, Pb and Zn concentrations in urban soils are much higher than those of industrial and suburban soils. Total concentrations of Cu and Cr in industrial soil samples are high compared to other two soil profiles and Ni concentrations in the suburban area are slightly higher those of urban and industrial soils. Since Malaysia has not yet to come up with her own soil maximum allowable limit, the heavy metal concentrations were compared with the Dutch maximum allowable limit. The results indicated that the median of heavy metals values in the three different soil profiles is still below the Dutch system limit. From the maximum allowable value obtained from the Dutch system, a contamination/pollution （C/p） index for each site was calculated for the set of these five heavy metals. An advantage of using this method is to make a differentiation between pollution （C/p〉1） and contamination （C/p〈1） status in soils as well as being able to characterize each status into 5 different categories （slight, moderate, severe, very severe and excessive）.     

Changes in manganese and lead in the environment and young children associated with the introduction of MMT in gasoline

This is a 4-year longitudinal study to evaluate changes to the environment and exposure of young children associated with the introduction of methylcyclopentadienyl manganese tricarbonyl （MMT） into Australia in 2000. The cohort includes 57 females and 56 males; age range of 0.29 to 3.9 years. Samples are collected every 6 months from children in residences located at varying distances from major traffic thoroughfares in Sydney. Environmental samples： air, house and day care dustfall, soil, dust sweepings and gasoline. Samples from children： blood, urine, handwipes prior to and after playing outdoors, and a 6-day duplicate diet. All samples are analyzed for a suite of 20 elements using ICP-MS. Results are presented for the first three 6-month sampling periods for Pb and Mn. For dustfall accumulation, there was no significant change over the 3 sampling periods （time） for Pb or Mn, and a positive relationship between ‘traffic exposure＇ （traffic volume and proximity to the road） and Pb but not Mn. For handwipes, Pb and Mn in wipes taken from children after playing outdoors were usually significantly greater than for wipes taken prior to playing. There was no significant association between Pb or Mn in handwipes with traffic exposure. Dustfall accumulation was a significant predictor for Pb in the handwipes, and dust sweepings were a significant predictor of Mn in handwipes.