解决污水快速渗滤土地处理系统占地突出的新方法

根据污水快速渗滤土地处理系统的主要特点和局限 ,针对该系统占地突出这一问题 ,提出了通过采用人工填料 ,提高水力负荷 ,加快污水在系统中的渗透速度 ,从而减小系统占地面积的新方法。对随水力负荷的提高使系统可能产生的出水水质变差、介质堵塞以及投资费用增高等问题进行了分析 ,并且对在涿州进行的现场小型工程的试验进行了验证。得出结论认为改进的人工构建快速渗滤系统切实可行。     

Geochemistry and magnetostratigraphy of deccan flows at Anjar, Kutch

Chemical analysis of nine Deccan flow basalts at Anjar, Kutch, western India, indicates that all, except the uppermost flow F-9, are alkaline. In their major and trace element composition, the alkali basalts resemble Ocean island basalts (OIB). Similarities of many diagnostic trace element ratios (e.g. Sm/Nd, Ba/Nb,Y/Nb and Zr/Nb) are similar to those found in the Réunion Island basalts. The uppermost basalt is tholeiitic and chemically resembles the least contaminated Deccan basalt (Ambenali type). The Anjar basalts have iridium concentration ranging between 2 and 178 pg/g. Some of these values are higher by about an order of magnitude compared to the Ir concentration in other basalts of the Deccan. A synthesis of chemical, palaeomagnetic and geochronologic data enables us to construct a chemical and magnetic stratigraphy for these flows. The three flows below the iridium enriched intertrappean bed (IT III) show normal magnetic polarity whereas all except one of the upper basalts show reversed magnetic polarity. The sequence seems to have started in polarity zones 31N and probably continued up to 28R or 27R. The results presented here support the view that Deccan volcanism in Kutch occurred on a time span of a few million years.     

Modeling of dioctahedral 2:1 phyllosilicates by means of transferable empirical potentials

 Dioctahedral 2:1 phyllosilicates with different interlayer charge have been studied theoretically by using transferable empirical interatomic potentials. The crystal structures of pyrophyllite, muscovite, margarite, beidellite, montmorillonite, and different smectites and illites have been simulated. The interatomic potentials were able to reproduce the experimental structure of phyllosilicates with high, medium and low interlayer charge. The calculated structures are in agreement with experiment for the main structural features of the crystal lattice. The effect of the cation substitution in the octahedral and tetrahedral sheets on the structural features has been also studied. Good linear relationships have been found, and the calculated effects are consistent with experimental results. Some unknown structural features of the crystal structures of clays are predicted in this work. Received: 8 March 2000 / Accepted: 19 September 2000     

Electronic absorption spectra of Fe2+ ions in oxygen-based rock-forming minerals at temperatures between 297 and 600 K

 Polarized electronic single crystal spectra of natural Fe²⁺ ion-bearing oxygen-based minerals, in which ferrous ions enter octahedral sites of different symmetry and distortion (olivine, cordierite, ortho- and clinopyroxene, amphibole), eightfold sites in garnet (almandine) and clinopyroxene (M2), and tetrahedral sites in spinel, were studied at temperatures from 300 to ca. 600 K. In the minerals studied, the spin-allowed bands of Fe²⁺ display rather variable temperature behaviour. In most cases, due to the thermal expansion of the Fe²⁺-bearing polyhedra, bands shift to lower energies upon increasing temperature, though there are some exceptions to this rule: in cases of other than sixfold octahedral or close to octahedral coordination, in almandine and spinel the bands shift to higher energies, which can be explained by an increase in distortions of the Fe²⁺-bearing polyhedra. Splitting of the excited ⁵ E _g-level of Fe²⁺ ions usually, but not always, increases with temperature, reflecting thermally induced increase in distortion of the Fe²⁺-bearing sites in the minerals studied. Integral intensities of the bands in question do not always obey the general rule, according to which intensity should increase with temperature, when the 3d ^N-centred site is centrosymmetric, or should remain unchanged when the 3d ^N site lacks an inversion centre. The experimental results show that the response of the characteristics of absorption bands such as width, intensity and energy caused by dd transitions of Fe²⁺ in oxygen-based minerals to increasing temperature is not always uniform and is at variance with expectation. This temperature dependence cannot be used directly to solve band assignment problems, as earlier proposed in the literature. Received: 22 December 1999 / Accepted: 30 October 2000     

离子色谱法测定水样中S~(2-)、SO_3~(2-)、SO_4~(2-)、S_2O_3~(2-)

该种方法利用离子色谱仪的电导检测器与电化学检测器串联 ,十几分钟即可连续完成水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3 的测定 ,方法具有快速、高效、方便、灵敏、选择性好等特点。方法的检出限分别为 :S2 - 12 5 μg/L ;SO2 - 3 2 2 4 μg/L ;SO2 - 45 0 μg/L ;S2 O2 - 35 0 μg/L。相对标准偏差在 1 5 %～ 6 9%之间 ,能够满足水中S2 - 、SO2 - 3 、SO2 - 4、S2 O2 - 3四种阴离子分析测试的需要。     

广西巴里—龙头山100号锡多金属矿床成矿物理化学环境研究——氧逸度(f_(o_2))、CO_2逸度(f_(co_2))、硫逸度(f_(s_2))、mΣs

根据已知的 10 0号矿体的成矿温度及成矿压力 ,并结合矿体的矿物组合推算出10 0号矿体是在相对低硫、氧和二氧化碳逸度 ,溶液为酸性至弱碱性的物理化学环境下形成的。     

Aragonite from Mulanshan Glaucophane Schist: Implications for Regional Evolution of Southwestern Dabie Mountains, Central China

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High iridium concentration of alkaline rocks of Deccan and implications to K/T boundary

We report here an unusually high concentration of iridium in some alkali basalts and alkaline rocks of Deccan region having an age of about 65Ma, similar to the age of the Cretaceous-Tertiary boundary. The alkali basalts of Anjar, in the western periphery of Deccan province, have iridium concentration as high as 178pg/g whereas the alkaline rocks and basalts associated with the Amba Dongar carbonatite complex have concentrations ranging between 8 and 80 pg/g. Some of these values are more than an order of magnitude higher than the concentration in the tholeiitic basalts of Deccan, indicating the significance of alkaline magmatism in the iridium inventory at the Cretaceous-Tertiary boundary. Despite higher concentration, their contribution to the global inventory of iridium in the Cretaceous-Tertiary boundary clays remains small. The concentration of iridium in fluorites from Amba Dongar was found to be <30 pg/g indicating that iridium is not incorporated during their formation in hydrothermal activity.     

气侯时间序列变点的推断

本文研究时间序列的变点问题。所给出的统计方法可用来推断一个时间序列是否存在变点，存在几个变点以及变点在什么位置。这种统计推断方法可用于气候阶段的划分。     

中国大陆卫星反演云参数的评估

该文选取１９８３年７月和１９８４年１月份代表夏季和冬季，利用中国地面气象月报的云量资料以及多年平均的地面观测云气修资料，与中国大陆地区ＩＳＣＣＰ卫星反演的去量和云状资料进行了对比分析。参照大气环流和云天气气候特征，从卫星得到的从云状是比较合理的，但干旱沙漠地区的高云量的估计不足，低云估计偏多。