岩浆型Cu-Ni-PGE硫化物矿床研究的几个问题探讨

文章简述了岩浆型Cu—Ni—PGE硫化物矿床的主要特点和研究现状,探讨了矿床的成矿机制,认为其成矿的首要条件是岩浆中硫达到饱和而使硅酸盐岩浆与硫化物熔体发生熔离。综述了如何利用同位素方法确定其成矿物质来源,介绍了如何判别硫饱和度的方法。     

Combining machine learning techniques,microanalyses and large geochemical datasets for tephrochronological studies in complex volcanic areas: New age constraints for the Pleistocene magmatism of central Italy

Characterization, correlation and provenance determination of tephra samples in sedimentary sections (tephrochronological studies) are powerful tools for establishing ages of depositional events, volcanic eruptions, and tephra dispersion. Despite the large literature and the advancements in this research field, the univocal attribution of tephra deposits to specific volcanic sources remains too often elusive. In this contribution, we test the application of a machine learning technique named Support Vector Machine to attempt shedding new light upon tephra deposits related to one of the most complex and debated volcanic regions on Earth: the Pliocene-Pleistocene magmatism in Italy. The machine learning algorithm was trained using one of the most comprehensive global petrological databases (GEOROC); 17 chemical elements including major (SiO₂, TiO₂, Al₂O₃, Fe₂O_3T, CaO, MgO, MnO, Na₂O, K₂O, P₂O₅) and selected trace (Sr, Ba, Rb, Zr, Nb, La, Ce) elements were chosen as input parameters. We first show the ability of support vector machines in discriminating among different Pliocene-Pleistocene volcanic provinces in Italy and then apply the same methodology to determine the volcanic source of tephra samples occurring in the Caio outcrop, an Early Pleistocene sedimentary section located in Central Italy. Our results show that: 1) support vector machines can successfully resolve high-dimensional tephrochronological problems overcoming the intrinsic limitation of two- and three-dimensional discrimination diagrams; 2) support vector machines can discriminate among different volcanic provinces in complex magmatic regions; 3) in the specific case study, support vector machines indicate that the most probable source for the investigated tephra samples is the so-called Roman Magmatic Province. These results have strong geochronological and geodynamical implications suggesting new age constraints (1.4 Ma instead of 0.8 Ma) for the starting of the volcanic activity in the Roman Magmatic Province.     

Tectonic nature of the NE Asian continental margin during the Late Jurassic–Early Cretaceous: constraints from the geochronology and geochemistry of igneous rocks in the NE North China Craton

ABSTRACT

This paper presents geochronological, geochemical, and zircon Hf–O isotope data for late Mesozoic intrusive rocks from the northeastern North China Craton (NCC), with the aim of constraining the late Mesozoic tectonic nature of the NE Asian continental margin. U–Pb zircon data indicate that the Late Mesozoic magmatism in the northeastern NCC can be subdivided into two stages: Late Jurassic (161 ? 156 Ma) and Early Cretaceous (125 ? 120 Ma). Late Jurassic magmatism consists mainly of monzogranites. These monzogranites display high Sr/Y ratios and the tetrad effect in their REE, respectively, and have negative ε_Hf(t) values (?22.6 to ?15.8). The former indicates that the primary magma was generated by partial melting of thickened NCC lower crust, the latter suggests that the monzogranites were crystallized from highly fractionated magma, with the primary magma derived from partial melting of lower continental crust. Combined with the spatial distribution and rock associations of the Late Jurassic granitoids, we conclude that the Late Jurassic magmatism in the eastern NCC formed in a compressional environment related to oblique subduction of the Paleo-Pacific Plate beneath the Eurasia. The Early Cretaceous magmatism consists mainly of granitoids and quartz diorites. The quartz diorites formed by mixing of melts derived from the mantle and lower crust. The coeval granitoids are classified as high-K calc-alkaline and metaluminous to weakly peraluminous series. Some of the granitoids are similar to A-type granites. The granitoid ε_Hf(t) values and T_DM2 range from ?14.3 to ?1.4 and 2089 to 1274 Ma, respectively. These values indicate that their primary magma was derived from partial melting of lower crustal material of the NCC, but with a contribution of mantle-derived material. We therefore conclude that Early Cretaceous magmatism in the northeastern NCC occurred in an extensional environment related to westward subduction of the Paleo-Pacific Plate beneath Eurasia.     

Geochemistry,petrogenesis and tectonic setting of the peraluminous granites in the nacheng gold deposit,Yongning, Guangdong北大核心

The Nacheng granite locates in the Yong ning area, Guangdong Province. This paper studied petrographical and chronological characteristics of this granite as well as its petrogenesis and geological significance. The Nacheng granite mainly consists of quartz (40%-50%), orthoclase (25%-30%), palgioxlase (15%-20%) with minor accessory minerals of quartz apatite and magnetite. Geochemical analyses show that the manziying granite has high content of SiO2 (75. 56%) , K2O (4.72%), Al2O3 (13. 34%) and total alkali (Na2O+K2O=7. 49%), but relatively low MgO (0. 04%-1. 29%) and CaO (0. 39%-2. 21%). The ratios of K2O/Na 2O are generally higher than 1. The Rittmann indexes are between 1-2. 43, belonging to the high-K calc-alkaline series. The values of A/CNK vary from 1. 12 to 1. 32 with an average of 1. 10, showing the characteristics of peraluminous S type granites. Trace element analyses show that the Nacheng granite has relatively high REE content of 82. 6 × 10-6 225. 68 × 10-1, and displays right-inclined V-shape REE patterns with relatively high fractionations of LREE and HREE[(La/Yb)N = 1. 51-9. 66] and pronounced negative Eu anomalies (δEu = 0. 31-0. 74) in the chondrite-normalized REE diagrams, suggesting a typical crust-derived grandite. The magmas may be divided into two types: "low-temperature" type from mudstones and "high-temperature" type from sandstones. The Nacheng granites were formed from the post-orogenic tectonic setting.     

论碰撞作用时间

以中国及欧洲大陆一些碰撞带所测得的同位素年龄为基础,讨论板块从俯冲到碰撞的过程,认为依次发生了如下事件：俯冲板块的运移速度减慢,洋壳在地表消失,开始碰撞,形成强构造变形与动力变质作用,发生一系列的岩浆活动,最后才隆升成山。这些事件都具有不同的同位素年龄。碰撞的初始作用时间,应该在所测年龄最新的洋壳消失以后,在强构造变形与动力变质作用发生之前。显然,如果只想使用任何一种地质事件的年龄来确定碰撞作用的初始作用时间都是很困难的。俯冲板块运移的初次减速很可能是由于从原来具有典型大洋岩石圈结构的板块俯冲,转变为洋陆过渡型板块俯冲所致。对于较小的、强度不大的板块来说,如中国大陆地块群,在板块碰撞与拼合之后,大陆板块仍可发生地壳转动或大幅度的位移。沿碰撞带主断层面贯入的“钉合岩体”可以是同构造期形成的,也可能是继续碰撞作用的产物。     

Early Triassic Volcanic Rocks in the Western Yarlung Zangbo Suture Zone: Implications for the Opening of the Neo-Tethys Ocean

In this study, zircon U-Pb dating of volcanic rocks from the Zhongba ophiolite of the Yarlung Zangbo Suture Zone (YZSZ) in southern Xizang (Tibet) yielded an age of 247 ± 3 Ma. According to whole rock geochemical and Sr-Nd-Pb isotopic data, the Early Triassic samples could be divided into two groups: Group 1 with P-MORB affinity, showing initial 87Sr/86Sr ratios of 0.70253–0.70602, εNd(t) values of 4.2–5.3, (206Pb/204Pb)t ratios of 16.353–18.222, (207Pb/204Pb)t ratios of 15.454–15.564, and (208Pb/204Pb)t ratios of 35.665–38.136; Group 2 with OIB affinity, showing initial 87Sr/86Sr ratios of 0.70249–0.70513, εNd(t) values of 4.4–4.9, (206Pb/204Pb)t ratios of 17.140–18.328, (207Pb/204Pb)t ratios of 15.491–15.575, and (208Pb/204Pb)t ratios of 36.051–38.247. Group 2 rocks formed by partial melting of the mantle source enriched by a former plume, and assimilated continental crustal material during melt ascension. The formation of Group 1 rocks corresponds to the mixing of OIB melts, with the same components as Group 2 and N-MORBs. The Zhongba Early Triassic rocks belong to the continental margin type ophiolite and formed in the continental–oceanic transition zone during the initial opening of the Neo-Tethys in southern Xizang (Tibet).     

Combined zircon and cassiterite U–Pb dating of the Piaotang granite-related tungsten–tin deposit,southern Jiangxi tungsten district,China

The large low-grade Piaotang W–Sn deposit in the southern Jiangxi tungsten district of the eastern Nanling Range, South China, is related to a hidden granite pluton of Jurassic age. The magmatic-hydrothermal system displays a zonation from an inner greisen zone to quartz veins and to peripheral veinlets/stringers (Five-floor zonation model). Most mineralization is in quartz veins with wolframite > cassiterite. The hidden granite pluton in underground exposures comprises three intrusive units, i.e. biotite granite, two-mica granite and muscovite granite. The latter unit is spatially associated with the W–Sn deposit.Combined LA-MC-ICP-MS U–Pb dating of igneous zircon and LA-ICP-MS U–Pb dating of hydrothermal cassiterite are used to constrain the timing of granitic magmatism and hydrothermal mineralization. Zircon from the three granite units has a weighted average ²⁰⁶Pb/²³⁸U age of 159.8 ± 0.3 Ma (2 σ, MSWD = 0.3). The cathodoluminescence (CL) textures indicate that some of the cassiterite crystals from the wolframite-cassiterite quartz vein system have growth zonations, i.e. zone I in the core and zone II in the rim. Dating on cassiterite (zone II) yields a weighted average ²⁰⁶Pb/²³⁸U age of 159.5 ± 1.5 Ma (2 σ, MSWD = 0.4), i.e. the magmatic and hydrothermal systems are synchronous. This confirms the classical model of granite-related tin–tungsten mineralization, and is against the view of a broader time gap of >6 Myr between granite magmatism and W–Sn mineralization which has been previously proposed for the southern Jiangxi tungsten district. The elevated trace element concentrations of Zr, U, Nb, Ta, W and Ti suggest that cassiterite (zone II) formed in a high-temperature quartz vein system related to the Piaotang granite pluton.     

Evolution of the Proto-Tethys in the Baoshan block along the East Gondwana margin: constraints from early Palaeozoic magmatism

Zircon U–Pb ages and geochemical and isotopic data for Late Ordovician granites in the Baoshan Block reveal the early Palaeozoic tectonic evolution of the margin of East Gondwana. The granites are high-K, calc-alkaline, metaluminous to strongly peraluminous rocks with A/CNK values of 0.93–1.18, are enriched in SiO₂, K₂O, and Rb, and depleted in Nb, P, Ti, Eu, and heavy rare earth elements, which indicates the crystallization fractionation of the granitic magma. Zircon U–Pb dating indicates that they formed at ca. 445 Ma. High initial ⁸⁷Sr/⁸⁶Sr ratios of 0.719761–0.726754, negative ?_Nd(t) values of –6.6 to –8.3, and two-stage model ages of 1.52–1.64 Ga suggest a crustal origin, with the magmas derived from the partial melting of ancient metagreywacke at high temperature. A synthesis of data for the early Palaeozoic igneous rocks in the Baoshan Block and adjacent Tengchong Block indicates two stages of flare-up of granitic and mafic magmatism caused by different tectonic settings along the East Gondwana margin. Late Cambrian to Early Ordovician granitic rocks (ca. 490 Ma) were produced when underplated mafic magmas induced crustal melting along the margin of East Gondwana related to the break-off of subducted Proto-Tethyan oceanic slab. In addition, the cession of the mafic magmatism between late Cambrian-Early Ordovician and Late Ordovician could have been caused by the collision of the Baoshan Block and outward micro-continent along the margin of East Gondwana and crust and lithosphere thickening. The Late Ordovician granites in the Baoshan Block were produced in an extensional setting resulting from the delamination of an already thickened crust and lithospheric mantle followed by the injection of synchronous mafic magma.     

藏南冈底斯岩基晚白垩世构造岩浆作用:以拉萨白堆复合岩体中-基性岩脉群为例

拉萨白堆复合岩体寄主为含包体的花岗闪长岩,并被一系列平行-近平行东西走向中-基性岩脉群穿插,总体形成类似"条纹码"般的构造形式。锆石U-Pb定年表明,这些基性岩脉主要形成于85~68Ma。同期中性和基性脉岩都表现出富集大离子亲石元素和LREE,亏损高场强元素,Sr同位素初始比值较低,但Nd同位素比值(εNd(t)+3.1)和锆石Hf同位素组成(εHf(t)+10.7)较高,都不具有Eu异常。与中性脉岩相比,基性脉岩具有(1)Mg O含量较高和较高的Mg#(50.6);(2)较高的Cr、Ni、Co含量;(3)较富集HREE且平坦分布。但中性脉岩Y含量较低,Sr/Y比值(38~72)较高,具有高Sr-低Y的特征;这些特征表明:这些岩浆岩的源区可能为受流体交代的岩石圈地幔。中-基性脉岩之间具有岩浆演化关系,在岩浆演化过程中以角闪石的分离结晶为主。结合文献数据,这些新数据表明冈底斯岩基的在晚白垩世(85~68Ma)经历了弧上伸展构造作用,岩浆作用持续活动,可能与新特提斯洋板片的北向斜俯冲相关。     

Geochemistry, Geochronology and Lu-Hf Isotopes of Peraluminous Granitic Porphyry from the Walegen Au Deposit, West Qinling Terrane

Walegen Au deposit is closely correlated with granitic intrusions of Triassic age, which are composed of granite and quartz porphyries. Both granite porphyry and quartz porphyry consist of quartz, feldspar and muscovite as primary minerals. Weakly peraluminous granite porphyry(A/CNK=1.10–1.15) is enriched in LREE, depleted in HREE with Nb-Ta-Ti anomalies, and displays subduction-related geochemistry. Quartz porphyry is strongly peraluminous(A/CNK=1.64–2.81) with highly evolved components, characterized by lower TiO_2, REE contents, Mg~#, K/Rb, Nb/Ta, Zr/Hf ratios and higher Rb/Sr ratios than the granite porphyry. REE patterns of quartz porphyry exhibit lanthanide tetrad effect, resulting from mineral fractionation or participation of fluids with enriched F and Cl. LAICP-MS zircon U-Pb dating indicates quartz porphyry formed at 233±3 Ma. The ages of relict zircons from Triassic magmatic rocks match well with the detrital zircons from regional area. In addition, ε_(Hf)(t) values of Triassic magmatic zircons from the granite and quartz porphyries are -14.2 to -9.1(with an exception of +4.1) and -10.8 to -8.6 respectively, indicating a crustal-dominant source. Regionally, numerous Middle Triassic granitoids were previously reported to be formed under the consumption of Paleotethyan Ocean. These facts indicate that the granitic porphyries from Walegen Au deposit may have been formed in the processes of the closing of Paleotethyan Ocean, which could correlate with the arc-related magmatism in the Kunlun orogen to the west and the Qinling orogen to the east.