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Type III (humic) organic matter from the Mahakam delta (Indonesia) was chosen to compare artificial and natural coal series. Powdered and concentrated immature organic matter was heated in sealed gold tubes for 24 hr at temperatures ranging from 250 to 550°C and under pressures ranging from 0.5 to 4 kb, with and without water. Both elemental and Rock-Eval analyses were used to characterize the products. A comparison between our results, published data and the natural model shows that, quantitatively, natural maturation is simulated better when pyrolysis is performed under confined conditions (no free volume, no diluting inert gas). Thus, pyrolysis in a medium swept by an inert gas, vacuum pyrolysis and some pyrolysis in sealed glass tubes must be considered to be poor simulation tools. The presence of water does not seem to have an essential effect. Allowing the hydrocarbons formed to reach a certain value of partial pressure seems to be important. Results are unchanged when external pressure varies from 0.5 to 4 kb. 相似文献
14.
Two hydrogen-rich lithobodies of highly alipathic character from a coal occurring in southwest Utah, have been studied. Bituminite (>50%), vitrinite (25–30%) and liptodetrinite (7–12%) are the principal macerals. The hexane-soluble products of hydrogenating the lithotypes at 400° with tetralin and hydrogen have been analyzed by GC-MS. Products identified include homologous series of alkylated naphthalenes, phenols, furans, cyclohexenones and hydroxy-pyridines. In the case of furans, the alkyl groups extend beyond C30. Materials released by Soxhlet extraction with pyridine consist chiefly of homologous series of fatty acids and their methyl esters and of methyl alkyl ketones, which were not found in the hydrogenation products. The long alkyl chains in these substances can account for about 75% of the alkanes found in the hydrogenation products but not in the extracts. Most of the compounds mentioned in the foregoing are thought to be physically held or trapped in the coal, rather than chemically combined in its macromolecular network. Except for the fatty acids, the origins of these substances are difficult to identify. 相似文献
15.
Six North American bituminous coals (four Carboniferous and two Cretaceous) and eight maceral concentrates from Carboniferous British seams have been heated with tetralin and hydrogen to 400°C. The hexane-soluble parts of the products were separated by column chromatography and the fractions were then analyzed by gas chromatography/mass spectrometry. In all cases the aromatic hydrocarbon fraction was a very complex mixture containing a number of alkylated biphenyls, diphenylmethanes and -ethanes, and polycyclic compounds. However single ioncchromatography (m/z = 142) showed that, in addition to these, the products from five of the six American coals contained homologous series of long chain n-alkylnapththalenes with alkyl groups extending to C16. In other fractions from the American coals, homologous series of n-alkylfurans and alkylphenols were found to be major components, as also were many alkylcyclohexenones related to isophorone. Extensive homologous series of n-alkyl aromatics were not detected in products from any of six vitrinites from British seams, though series of n- and iso-alkylphenols were found in the products from two sporinite concentrates. A number of polycyclic ketones apparently related to sterols were found in the products from the British vitrinites but not from any American coals. Reasons for what appear to be systematic structural differences between the American and British coals are discussed. Differences in stratigraphy are noted and it seems not impossible that differences in source vegetation are significant. 相似文献
16.
K. M. Tomkins G. S. Humphreys M. T. Wilkinson D. Fink P. P. Hesse S. H. Doerr R. A. Shakesby P. J. Wallbrink W. H. Blake 《地球表面变化过程与地形》2007,32(7):1013-1031
Short‐term (contemporary) and long‐term denudation rates were determined for the Blue Mountains Plateau in the western Sydney Basin, Australia, to explore the role of extreme events (wildfires and catastrophic floods) in landscape denudation along a passive plate margin. Contemporary denudation rates were reconstructed using 40 years of river sediment load data from the Nattai catchment in the south‐west of the basin, combined with an analysis of hillslope erosion following recent wildfires. Long‐term denudation rates (10 kyr–10 Myr) were determined from terrestrial cosmogenic nuclides, apatite fission track thermochronology and post‐basalt flow valley incision. Contemporary denudation rates average several times lower than the long‐term average (5·5 ± 4 mm kyr?1 versus 21·5 ± 7 mm kyr?1). Erosion of sediment following wildfires accounts for only a small proportion (5%) of the contemporary rate. Most post‐fire sediment is stored on the lower slopes and valley floor, with the amount transported to the river network dependent on rainfall–run‐off conditions within the first few years following the fire. Historical catastrophic floods account for a much larger proportion (35%) of the contemporary erosion rate, and highlight the importance of these events in reworking stored material. Evidence for palaeofloods much larger than those experienced over the past 200 years suggests even greater sediment export potential. Mass movement on hillslopes along valleys incised into softer lithology appears to be a dominant erosion process that supplies substantial volumes of material to the valley floor. It is possible that a combination of infrequent mass movement events and high fluvial discharge could account for a significant proportion of the discrepancy between the contemporary and long‐term denudation rates. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
17.
Most studies of ethnic residential segregation in Australian cities have used single-measure indices of dissimilarity and segregation, which access the degree of unevenness between two maps. Segregation is a multi-dimensional concept, however, and in this paper we introduce an alternative way of measuring residential concentration which incorporates several of the key dimensions. The procedure is illustrated using birthplace and language-used-at-home data for collection districts in metropolitan Sydney in 1996. Results show no evidence of extreme spatial concentration of ethnic groups. 相似文献
18.
Brenda S. Pierce Artur Martirosyan Gourgen Malkhasian Samvel Harutunian Grigory Harutunian 《International Journal of Coal Geology》2001,45(4):307
The Antaramut–Kurtan–Dzoragukh (AKD) coal deposit is a previously unrecognized coal field in north-central Armenia. Coal has been known to exist in the general vicinity since the turn of the century, but coal was thought to be restricted to a small (1 km2) area only near the village of Antaramut. However, through detailed field work and exploratory drilling, this coal deposit has been expanded to at least 20 km2, and thus renamed the Antaramut–Kurtan–Dzoragukh coal field, for the three villages that the coal field encompasses. The entire coal-bearing horizon, a series of tuffaceous sandstones, siltstones, and claystones, is approximately 50 m thick. The AKD coal field contains two coal beds, each greater than 1 m thick, and numerous small rider beds, with a total resource of approximately 31,000,000 metric tonnes. The coals are late Eocene in age, high volatile bituminous in rank, relatively high in ash yield (approximately 40%, as-determined basis) and moderate in sulfur content (approximately 3%, as-determined basis). The two coal beds (No. 1 and No. 2), on a moist, mineral-matter-free basis, have high calorific values of 32.6 MJ/kg (7796 cal/g) and 36.0 MJ/kg (8599 cal/g), respectively. Coal is one of the few indigenous fossil fuel resources occurring in Armenia and thus, the AKD coal field could potentially provide fuel for heating and possibly energy generation in the Armenian energy budget. 相似文献
19.
Tatyana K. Dimitrova Erwin L. Zodrow Christopher J. Cleal Barry A. Thomas 《Geological Journal》2010,45(4):388-396
The palynology of clastic samples from seven stratigraphical levels in the late Moscovian Sydney Mines Formation, exposed along the shore at Bras d'Or, Nova Scotia, has been investigated. Most of the samples were from roof shales of major coals; the one sample that was not yielded a much higher proportion of pollen derived from extra‐basinal vegetation. The four stratigraphically lower roof shale samples yielded essentially similar palynological spectra, with 39 ± 4% lycophytes, 9 ± 4% sphenophylls, 23 ± 4% tree‐ferns, 12 ± 4% other ferns and 5 ± 3% cordaites. The palynology of the upper part of the investigated succession suggests a shift in vegetation towards one favouring more marattialean tree‐ferns, cordaites and conifers, and fewer lycophytes. This correlates with changes in drainage patterns as the alluvial plain migrated seawards and thus changed water tables. No evidence was found to suggest significant climate change at this time. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
20.
This paper reviews various coal seam gas (CSG) models that have been developed for the Sydney Basin, and provides an alternative interpretation for gas composition layering and deep-seated CO2 origins. Open file CSG wells, supplemented by mine-scale information, were used to examine trends in gas content and composition at locations from the margin to the centre of the basin. Regionally available hydrochemistry data and interpretations of hydrodynamics were incorporated with conventional petroleum well data on porosity and permeability. The synthesised gas and groundwater model presented in this paper suggests that meteoric water flow under hydrostatic pressure transports methanogenic consortia into the subsurface and that water chemistry evolves during migration from calcium-rich freshwaters in inland recharge areas towards sodium-rich brackish water down-gradient and with depth. Groundwater chemistry changes result in the dissolution and precipitation of minerals as well as affecting the behaviour of dissolved gases such as CO2. Mixing of carbonate-rich waters with waters of significantly different chemistries at depth causes the liberation of CO2 gas from the solution that is adsorbed into the coal matrix in hydrodynamically closed terrains. In more open systems, excess CO2 in the groundwater (carried as bicarbonate) may lead to precipitation of calcite in the host strata. As a result, areas in the central and eastern parts of the basin do not host spatially extensive CO2 gas accumulations but experience more widespread calcite mineralisation, with gas compositions dominated by hydrocarbons, including wet gases. Basin boundary areas (commonly topographic and/or structural highs) in the northern, western and southern parts of the basin commonly contain CO2-rich gases at depth. This deep-seated CO2-rich gas is generally thought to derive from local to continental scale magmatic intrusions, but could also be the product of carbonate dissolution or acetate fermentation. 相似文献