This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments. 相似文献
Argillaceous rocks cover about one thirds of the earth's surface. The major engineering problems encountered with weak- to medium-strength argillaceous rocks could be slaking, erosion, slope stability, settlement, and reduction in strength. One of the key properties for classifying and determining the behavior of such rocks is the slake durability. The concept of slake durability index (SDI) has been the subject of numerous researches in which a number of factors affecting the numerical value of SDI were investigated. In this regard, this paper approaches the matter by evaluating the effects of overall shape and surface roughness of the testing material on the outcome of slake durability indices.
For the purpose, different types of rocks (marl, clayey limestone, tuff, sandstone, weathered granite) were broken into chunks and were intentionally shaped as angular, subangular, and rounded and tested for slake durability. Before testing the aggregate pieces of each rock type, their surface roughness was determined by using the fractal dimension. Despite the variation of final values of SDI test results (values of Id), the rounded aggregate groups plot relatively in a narrow range, but a greater scatter was obtained for the angular and subangular aggregate groups. The best results can be obtained when using the well rounded samples having the lowest fractal values. An attempt was made to analytically link the surface roughness with the Id parameter and an empirical relationship was proposed. A chart for various fractal values of surface roughness to use as a guide for slake durability tests is also proposed. The method proposed herein becomes efficient when well rounded aggregates are not available. In such condition, the approximate fractal value for the surface roughness profile of the testing aggregates could be obtained from the proposed chart and be plugged into the empirical relation to obtain the corrected Id value. The results presented herein represent the particular rock types used in this study and care should be taken when applying these methods to different type of rocks. 相似文献
For more than hundred years it has been debated whether blockfields in mountain summit areas can be used to delimit the vertical extent of Pleistocene ice sheets. In this study the relationship between blockfields, developed in quartzites and sandstones on the Varanger Peninsula, northern Norway, and glacially derived features have been evaluated. Erratics and circular ablation moraines are superimposed on the blockfields and lateral meltwater channels are eroded into them. Glacial striations and other signs of glacial sculpturing are restricted to low-lying areas with channelled ice flow. Relative ages of the blockfields and the features in them are inferred, and the first measurements of in-situ produced cosmogenic nuclides from the Varanger Peninsula are reported. We conclude that the blockfields have survived underneath at least one thick, cold-based ice sheet. Thus, these blockfields cannot be used as indicators of ice-free conditions as previously suggested for southern Norway. Our results have implications for the potential for land surface preservation beneath ice sheets and for glacial reconstructions in northern Fennoscandia. 相似文献
Ni and Cu mining and ore processing in Hitura, Western Finland, have resulted in emissions of metal-rich wastewaters into the nearby Kalajoki River since 1970. The wastewaters are discharged into the river 3 km upstream from the eutrophic Lake Pidisjärvi, which is a widening of the river by the town of Nivala. The water level of the lake was elevated by 1.5 m and the extensive macrophyte stands were cut in 1979, profoundly changing the environmental conditions. The effects of the decreasing metal emissions and nutrient concentrations since 1979 on the now open 3.9 km2 lake were studied with paleolimnological techniques. A 2-m sediment core was taken from the lake in February 2004 and analysed for sediment chemistry and diatom assemblages. At the coring site, 13 cm of sediment had been deposited since 1979, on top of a bed of undecomposed macrophyte remains. When the sediment chemistry was compared with records of decreasing metal loading since 1979, no correlation was found because post-depositional mobility and changes in sediment characteristics affect the sediment metal profiles. Thus, the reduced emissions from the mine and the lower lake water phosphorus levels have not caused a corresponding decrease in sediment metal and P concentrations. However, both of these environmental variables accounted for a statistically significant percentage of variation in the sedimentary diatom assemblages in a redundancy analysis constrained to a single variable. This relationship persisted for Ni loading even in a partial analysis, while the importance of nutrients was confirmed by the good correlation between diatom-inferred and measured P concentrations. The results suggest that reductions in metal and nutrient loading have had an effect on the algal assemblages even though the sediment concentrations of Ni, Cu or P have not decreased. 相似文献
The Zlata Idka village is a typical mountainous settlement. As a consequence of more than 500 years of mining activity, its environment has been extensively affected by pollution from potentially toxic elements. This paper presents the results of an environmental-geochemical and health research in the Zlata Idka village, Slovakia. Geochemical analysis indicates that arsenic (As) and antimony (Sb) are enriched in soils, groundwater, surface water and stream sediments. The average As and Sb contents are 892 mg/kg and 818 mg/kg in soils, 195 mg/kg and 249 mg/kg in stream sediments, 0.028 mg/l and 0.021 mg/l in groundwater and 0.024 mg/l and 0.034 mg/l in surface water. Arsenic and Sb concentrations exceed upper permissible limits in locally grown vegetables. Within the epidemiological research the As and Sb contents in human tissues and fluids have been observed (blood, urine, nails and hair) in approximately one third of the village’s population (120 respondents). The average As and Sb concentrations were 16.3 μg/l and 3.8 μg/l in blood, 15.8 μg/l and 18.8 μg/l in urine, 3,179 μg/kg and 1,140 μg/kg in nails and 379 μg/kg and 357 μg/kg in hair. These concentrations are comparatively much higher than the average population. Health risk calculations for the ingestion of soil, water, and vegetables indicates a very high carcinogenic risk (>1/1,000) for as content in soil and water. The hazard quotient [HQ=average daily dose (ADD)/reference dose (RfD)] calculation method indicates a HQ>1 for groundwater As and Sb concentrations. 相似文献