The role of fog,orography, and seasonality on precipitation in a semiarid,tropical island

Isotopes of water (²H/¹H and ¹⁸O/¹⁶O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.     

Spatial variability in specific discharge and streamwater chemistry during low flows: Results from snapshot sampling campaigns in eleven Swiss catchments

Catchments consist of distinct landforms that affect the storage and release of subsurface water. Certain landforms may be the main contributors to streamflow during extended dry periods, and these may vary for different catchments in a given region. We present a unique dataset from snapshot field campaigns during low‐flow conditions in 11 catchments across Switzerland to illustrate this. The catchments differed in size (10 to 110 km²), varied from predominantly agricultural lowlands to Alpine areas, and covered a range of physical characteristics. During each snapshot campaign, we jointly measured streamflow and collected water samples for the analysis of major ions and stable water isotopes. For every sampling location (basin), we determined several landscape characteristics from national geo‐datasets, including drainage area, elevation, slope, flowpath length, dominant land use, and geological and geomorphological characteristics, such as the lithology and fraction of quaternary deposits. The results demonstrate very large spatial variability in specific low‐flow discharge and water chemistry: Neighboring sampling locations could differ significantly in their specific discharge, isotopic composition, and ion concentrations, indicating that different sources contribute to streamflow during extended dry periods. However, none of the landscape characteristics that we analysed could explain the spatial variability in specific discharge or streamwater chemistry in multiple catchments. This suggests that local features determine the spatial differences in discharge and water chemistry during low‐flow conditions and that this variability cannot be assessed a priori from available geodata and statistical relations to landscape characteristics. The results furthermore suggest that measurements at the catchment outlet during low‐flow conditions do not reflect the heterogeneity of the different source areas in the catchment that contribute to streamflow.     

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.     

Assessing basin storage: Comparison of hydrometric- and tracer-based indices of dynamic and total storage

Storage is a fundamental but elusive component of drainage basin function, influencing synchronization between precipitation input and streamflow output and mediating basin sensitivity to climate and land use/land cover (LULC) change. We compare hydrometric and isotopic approaches to estimate indices of dynamic and total basin storage, respectively, and assess inter-basin differences in these indices across the Oak Ridges Moraine (ORM) region of southern Ontario, Canada. Dynamic storage indices for the 20 study basins included the ratio of baseflow to total streamflow (baseflow index BFI), Q ₉₉ flow and flow duration curve (FDC) slope. Ratios of the standard deviation of the streamflow stable isotope signal relative to that of precipitation were determined for each basin from a 1 year bi-weekly sampling program and used as indicators of total storage. Smaller ratios imply longer water travel times, smaller young water fractions (F _yw, < ~2–3 months in age) in streamflow and greater basin storage. Ratios were inversely related to BFI and Q ₉₉, and positively related to FDC slope, suggesting longer travel times and smaller F _yw for basins with stable baseflow-dominated streamflow regimes. Inter-basin differences in all indices reflected topographic, hydrogeologic and LULC controls on storage, which was greatest in steep, forest-covered headwaters underlain by permeable deposits with thick and relatively uniform unsaturated zones. Nevertheless, differential sensitivity of indices to controls on storage indicates the value of using several indices to capture more completely how basin characteristics influence storage. Regression relationships between storage indices and basin characteristics provided reasonable predictions of aspects of the streamflow regime of test basins in the ORM region. Such relationships and the underlying knowledge of controls on basin storage in this landscape provide the foundation for initial predictions of relative differences in streamflow response to regional changes in climate and LULC.     

Identification of groundwater mean transit times of precipitation and riverbank infiltration by two‐component lumped parameter models

Groundwater transit time is an essential hydrologic metric for groundwater resources management. However, especially in tropical environments, studies on the transit time distribution (TTD) of groundwater infiltration and its corresponding mean transit time (mTT) have been extremely limited due to data sparsity. In this study, we primarily use stable isotopes to examine the TTDs and their mTTs of both vertical and horizontal infiltration at a riverbank infiltration area in the Vietnamese Mekong Delta (VMD), representative of the tropical climate in Asian monsoon regions. Precipitation, river water, groundwater, and local ponding surface water were sampled for 3 to 9 years and analysed for stable isotopes (δ¹⁸O and δ²H), providing a unique data set of stable isotope records for a tropical region. We quantified the contribution that the two sources contributed to the local shallow groundwater by a novel concept of two‐component lumped parameter models (LPMs) that are solved using δ¹⁸O records. The study illustrates that two‐component LPMs, in conjunction with hydrological and isotopic measurements, are able to identify subsurface flow conditions and water mixing at riverbank infiltration systems. However, the predictive skill and the reliability of the models decrease for locations farther from the river, where recharge by precipitation dominates, and a low‐permeable aquitard layer above the highly permeable aquifer is present. This specific setting impairs the identifiability of model parameters. For river infiltration, short mTTs (<40 weeks) were determined for sites closer to the river (<200 m), whereas for the precipitation infiltration, the mTTs were longer (>80 weeks) and independent of the distance to the river. The results not only enhance the understanding of the groundwater recharge dynamics in the VMD but also suggest that the highly complex mechanisms of surface–groundwater interaction can be conceptualized by exploiting two‐component LPMs in general. The model concept could thus be a powerful tool for better understanding both the hydrological functioning of mixing processes and the movement of different water components in riverbank infiltration systems.     

Spatially distributed tracer‐aided modelling to explore water and isotope transport,storage and mixing in a pristine,humid tropical catchment

Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km² San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.     

洞庭湖流域降水同位素与ENSO关系研究

基于洞庭湖流域内长沙市2010年1月至2012年12月降水事件、GNIP(Global Network for Isotopes in Precipitation)长沙站1988~1992年月降水同位素资料及ENSO（厄尔尼诺/拉尼娜和南方涛动）的2个常用指标（南方涛动指数SOI和Nino3区海面温度SST）,分析了流域降水同位素与ENSO关系。结果表明：洞庭湖流域降水中δ¹⁸O与降水量、气温在日、月尺度上均呈负相关且只有月度上与降水量的负相关不显著。洞庭湖流域降水中δ¹⁸O与ENSO的SST指标则呈显著正相关。ENSO对洞庭湖流域降水同位素的影响机制可能如下：春季,La Nina年源自西太平洋的东南风强盛,其转向为西南风的区域达到印度洋,而El Nino年,东南风转向为西南风的发生区域位于印度洋以东,前者有利于挟带印度洋远源水汽向中国东部区域输送,进而造成降水同位素的贫化;夏季,La Nina年印度洋水汽输送在中国南海转为经向继而向北延伸,而El Nino年,源自印度洋的水汽沿纬向穿过南海,在东海转向往北延伸,后者有利于挟带西太平洋的近源水汽输送到中国东部季风区,进而引起降水同位素的富集。     

A reconnaissance study of oxygen, hydrogen and strontium isotopes in geochemically diverse lakes, Western Nebraska, USA

Reconnaissance ¹⁸O,, D, and ⁸⁷Sr data for fifteen lakes in the Western Lakes Region of the Sand Hills of Nebraska indicate dynamic hydrologic systems. The rather narrow range of ⁸⁷Sr from lake water (1.1 to 2.1) and groundwater (0.9 to 1.7) indicates that the groundwater is generally unradiogenic. Groundwater residence times and relatively unradiogenic volcanic ash within the dune sediments control the ⁸⁷Sr values. Based on the mutual variations of ¹⁸O and D, the lakes can be divided into three groups. In Group 1, both ¹⁸O and D values increase from spring to fall. The ¹⁸O and D values in Group 2 decreased from spring to fall. Group 3 are ephemeral lakes that went dry some time during 1992. The data and isotopic modeling show that variations in the ratio of evaporation relative to groundwater inflow, local humidity conditions, and the _a has substantial influence on the isotopic composition. In addition, isotopic behavior in ephemeral lakes can be rather unusual because of the changing activities of water and mineral precipitation and redissolution. The annual and interannual isotopic variability of these lakes which is reflected in the paleonvironmental indicators may be the rule rather than the exception in these types of systems.     

华北克拉通北缘柴胡栏子金矿富甲烷流体包裹体的发现及地质意义

柴胡栏子金矿位于华北克拉通北缘赤峰-朝阳金矿集区西段,是区内典型的石英脉型为主的金矿床,也是赤峰-朝阳地区首次发现的含大量单相甲烷包裹体群的金矿床.矿体呈脉状产于太古宙建平群大营子组下岩段含石墨绢云母片岩切层断裂中,金主要产出在蚀变含石墨绢云母片岩和石英脉中.根据野外观察和包裹体测温结果,将柴胡栏子金矿流体成矿过程划分...