湖北宜昌地区寒武系—下奥陶统的碳氧同位素记录

对宜昌地区寒武系和下奥陶统的碳酸盐碳、氧同位素进行测定,所得δ18O大 于－10‰且与δ13C不相关,表明研究区碳酸盐样品基本上保存了碳、氧同位素的初 始比值。δ18O在白云岩样品中呈现正漂移而在非白云岩样品中呈现负漂移,认为δ 18O反映海水古盐度变化,即δ18O随着古盐度升高而增大;δ13 C在缺氧沉积物中呈现负漂移,但负漂移的δ13C却不限于缺氧沉积物,推测δ13 C可能反映古海洋的初级生产力,即δ13C随着初级生产力的提高而降低。研究还指 出,由于Z值与δ13C密切正相关（相关系数为0.99）,综合运用δ18O和δ 13C的经典盐度公式不适用于研究区古盐度环境的重建。     

云南九顶山正长斑岩年代学、岩石地球化学及Sr-Nd-Hf同位素特征

九顶山复式岩体沿北西向金沙江–红河断裂与南北向程海断裂交汇处发育,处于南北地洼区与滇西地洼区接触带,是滇西地洼期斑岩成矿带中段的代表性富碱斑岩体之一。该岩体由呈岩株、岩脉、岩墙或岩床等产出的斑状花岗岩、正长斑岩、(二长)花岗斑岩、碱长花岗斑岩和煌斑岩等组成。本文着重对正长斑岩的形成年代、岩石地球化学和成因特征开展研究,结果表明:正长斑岩的LA-ICP-MS锆石U-Pb年龄为34.6±0.7 Ma,即岩浆侵位于始新世(E2),属滇西地洼激烈期及新生代富碱岩浆活动高峰期(45~30 Ma)的产物;岩石具高硅(Si O256%)、高钾(K2O=3.38%~8.92%,K2O/Na2O1)、富碱(ALK=8.15%~11.15%)和低Mg O(3%)的特征,属钾玄岩系列–高钾钙碱性系列过铝质(A/CNK=0.71~1.22)花岗岩;在微量元素组成上,岩石高Sr(400×10-6)、低Y(18×10-6)和Yb(1.9×10-6),与陆内造山环境形成的"C型"钾质埃达克岩地球化学特征类似;全岩的Sr-Nd-Hf同位素组成特征显示岩浆源区是壳幔物质混合的"EMII型"富集地幔源。正长斑岩的形成应与印度–欧亚板块碰撞俯冲背景下,金沙江–红河断裂大规模左行走滑引起的热扰动和局部引张作用有关,在这种区域热–动力学条件下,地幔部分熔融与地壳物质发生混合作用,形成活化型壳幔混合源高钾富碱岩浆。     

粤东桃子窝锡矿区火山-次火山岩和花岗岩锆石U-Pb年龄、Hf同位素特征及其意义

桃子窝锡矿位于莲花山断裂带西段,是典型的火山-次火山岩型锡矿。本文以桃子窝锡矿赋矿火山-次火山岩及花岗岩为研究对象,首次开展LA-ICP-MS锆石U-Pb定年和Hf同位素特征研究。获得两个次火山岩样品的锆石206Pb/238 U加权平均年龄为172.1±1.1 Ma和171.8±0.9 Ma,一个花岗岩样品的锆石206 Pb/238 U加权平均年龄为168.9±1.5 Ma,表明桃子窝锡矿火山-侵入岩为中侏罗世同一岩浆事件不同阶段的产物。锆石εHf(t)值大多数为负值,只有3个点的值大于0,变化于-13.96~9.53之间,平均值为-7.92。在εHf(t)-t图解上,εHf(t)值大多落在球粒陨石演化线之下,有3个点落在球粒陨石与亏损地幔演化线之间。二阶段模式年龄除3个点介于609.6~795.5 Ma外,其余点年龄为1 450.8~2 102.5 Ma,Hf同位素特征指示成岩物质主要来源于早中元古代古老地壳的部分熔融,还有新元古代新生地壳物质的加入。结合区内已有的研究成果,认为桃子窝锡矿及有关的火山-次火山岩与中生代太平洋板块向欧亚大陆俯冲有关。     

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.     

陕西渭北东部岩溶水环境同位素

陕西渭北东部岩溶水系统是一个复杂的地下水系统，碳酸盐岩大面积隐伏与深埋。使用传统手段和方法勘查岩溶地下水和研究可持续开发利用方案遇到诸多困难，不仅费时，而且耗资大。本文通过系统分析研究陕西渭北东部地区岩溶地下水T、D、^180、^14C环境同位素特征，揭示岩溶水的补给迳流排泄条件、岩溶水系统边界性质以及岩溶水与黄河洛河地表水、黄河岩溶泉与洛河岩溶泉之间的补排关系。结果显示环境同位素方法简便有效，能够达到预期目的。     

广西新元古代BIF的铁同位素特征及其地质意义

通过分析广西三江地区新元古代条带状含铁建造的Fe同位素和主量元素组成,对海水的氧化还原状态提供了制约,为富禄期的地球处于间冰期提供了证据。相对于标准物质IRMM-014,新元古代含铁建造不同条带全岩样品的δ57Fe值变化范围1.60‰～2.20‰,平均值为1.85‰,表明BIF样品富集铁的重同位素。条带状含铁建造主要由Fe2O3和SiO2组成,但却具有较高的Al2O3含量。这表明条带状含铁建造样品不是纯净的化学沉积物,而是具有一定的碎屑物质输入。碎屑输入量的不同引起深色和浅色条带之间铁同位素组成存在着0.4‰的差别。剔除碎屑的影响,新元古代BIF从海水中沉淀的赤铁矿δ57Fe的平均值在2‰左右,略高于太古代条带状铁建造的Fe同位素组成,这表明当时海水的氧逸度可能比太古代还低。这说明在富禄期绝大部分海洋仍旧被冰盖覆盖,只在局部出现融化。因此,富禄期的地球可能出于冰期的相对温暖阶段,而不是间冰期。     

Variation in the composition of Lake Bonneville marl: a potential key to lake-level fluctuations and paleoclimate

Lake Bonneville marl provides a stratigraphic record of lake history preserved in its carbonate minerals and stable isotopes. We have analyzed the marl in shallow cores taken at three localities in the Bonneville basin. Chronology for the cores is provided by dated volcanic ashes, ostracode biostratigraphy, and a distinctive lithologic unit believed to have been deposited during and immediately after the Bonneville Flood.A core taken at Monument Point at the north shore of Great Salt Lake encompasses virtually the entire Bonneville lake cycle, including the 26.5 ka Thiokol basaltic ash at the base and deposits representing the overflowing stage at the Provo shoreline at the top of the core. Two cores from the Old River Bed area near the threshold between the Sevier basin and the Great Salt Lake basin (the main body of Lake Bonneville) represent deposition from the end of the Stansbury oscillation ( 20 ka) to post-Provo time ( 13 ka), and one core from near Sunstone Knoll in the Sevier basin provides a nearly complete record of the period when Lake Bonneville flooded the Sevier basin (20–13 ka).In all cores, percent calcium carbonate, the aragonite to calcite ratio, and percent sand were measured at approximately 2-cm intervals, and ¹⁸O and ¹³C were determined in one core from the Old River Bed area. The transgressive period from about 20 ka to 15 ka is represented in all cores, but the general trends and the details of the records are different, probably as a result of water chemistry and water balance differences between the main body and the Sevier basin because they were fed by different rivers and had different hypsometries. The Old River Bed marl sections are intermediate in position and composition between the Monument Point and Sunstone Knoll sections. Variations in marl composition at the Old River Bed, which are correlated with lake-level changes, were probably caused by changes in the relative proportions of water from the two basins, which were caused by shifts in water balance in the lake.This is the second paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.     

东川铜矿床同位素地球化学研究:I.地层年代与铅同位素化探应用

采用Ｐｂ－Ｐｂ等时线法测定了昆阳群中亚群落雪组白云岩、黑山组碳质板岩和上亚群大营盘组碳质板岩样品，获得了（１７１６±５６）Ｍａ、（１６０７±１２８）Ｍａ和（１２５８±７０）Ｍａ的年龄，确定了昆阳群中亚群时代约为１６００—１８００Ｍａ，属晚古元古代，上亚群大营盘组约为１２００—１３００Ｍａ，属中元古代。还应用铅同位素化探技术系统研究了汤丹铜矿１号硐中段西１４穿脉岩石－矿石的铅同位素组成，结果表明铅同位素Ｖ１值与铜含量呈反相关系。这是运用系统剖面方法开展铅同位素化探的首次尝试。     

Petrogenesis of plio-quaternary intra-plate continental alkaline lavas from the İskenderun Gulf (Southern Turkey): Evidence for metasomatized lithospheric mantle

The Quaternary alkaline volcanic field of Southern Turkey is characterized by intra-continental plate-type magmatic products, exposed to the north of the ?skenderun Gulf along a NE-SW trending East Anatolian Fault, to the west of its intersection with the N–S trending Dead Sea Fault zone. The ?skenderun Gulf alkaline rocks are mostly silica-undersaturated with normative nepheline and olivine and are mostly classified as basanites and alkaline basalts with their low-silica contents ranging between 43 and 48?wt.% SiO₂. They display Ocean Island Basalt (OIB)–type trace element patterns characterized by enrichments in large-ion-lithophile elements (LILE) and light rare earth element (LREE), and have (La/Yb)_N?=?8.8–17.7 and (Hf/Sm)_N?=?0.9–1.6 similar to those of basaltic rocks found in intraplate suites. The basanitic rocks have limited variations Sr-Nd isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.70307–0.70324, ¹⁴³Nd/¹⁴⁴Nd?=?0.512918–0.521947), whereas the alkali basalts display more evolved Sr-Nd isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.70346-0.70365, ¹⁴³Nd/¹⁴⁴Nd?=?0.512887–0.521896). The ?skenderun Gulf alkaline rocks also display limited Pb isotopic variations with ²⁰⁶Pb/²⁰⁴Pb?=?18.75–19.09 ²⁰⁷Pb/²⁰⁴Pb?=?15.61–15.66 and²⁰⁸Pb/²⁰⁴Pb?=?38.65–39.02, indicating that they originated from an enriched lithospheric mantle source. Calculated fractionation vectors indicate that clinopyroxene and olivine are the main fractionating mineral phases. Similarly, based on Sr-Nd isotopic ratios, the assimilation and fractional crystallization (AFC) modeling shows that the alkali basalts were affected by AFC processes (r?=?0.2) and were slightly contaminated by the upper crustal material.The high TiO₂ contents, enrichments in Ba and Nb, and depletions in Rb can likely be explained by the existence of amphibole in the mantle source, which might, in turn, indicate that the source mantle has been affected by metasomatic processes. The modeling based on relative abundances of trace elements suggests involvement of amphibole-bearing peridotite as the source material. ?skenderun Gulf alkaline rocks can thus be interpreted as the products of variable extent of mixing between melts from both amphibole-bearing peridotite and dry peridotite.     

南极普里兹湾海域铀系同位素的分布

本文报道了南极普里兹湾海域U、2 2 6Ra、2 1 0 Pb、2 1 0 Po的分布以及2 34U/2 38U和2 1 0 Po/2 1 0 Pb放射性比值。研究结果表明 ,该海域表层水中的铀同位素分布基本均匀 ,铀含量范围为1 3 2 8- 1 4 2 0 μmol·m- 3,平均值为 ( 1 3.82± 0 .2 9) μmol·m- 3,2 34U/2 38U平均放射性比值为1 1 4± 0 0 3。铀含量与盐度之间存在良好的相关性 ,其相关系数达 0 895。该海域溶解态2 2 6Ra比活度范围为 1 37- 1 78Bq·m- 3,平均值为 1 5 5Bq·m- 3;颗粒态 2 2 6Ra比活度范围为0 0 0 6- 0 0 35Bq·m- 3,平均值为 0 0 1 5Bq·m- 3;2 1 0 Po比活度 0 80- 1 5 2Bq·m- 3,平均 1 1 4Bq·m- 3;2 1 0 Pb比活度 1 34- 2 1 5Bq·m- 3,平均 1 66Bq·m- 3;2 1 0 Po/2 1 0 Pb的放射性比值0 5 5- 0 84,平均 0 69。并对2 1 0 Po和2 1 0 Pb的不平衡作了讨论。还研究了 1个站位溶解态和颗粒态2 2 6Ra、2 1 0 Pb的深度分布及2 1 0 Pb在两相中的分配