东川铜矿床同位素地球化学研究:I.地层年代与铅同位素化探应用

采用Ｐｂ－Ｐｂ等时线法测定了昆阳群中亚群落雪组白云岩、黑山组碳质板岩和上亚群大营盘组碳质板岩样品，获得了（１７１６±５６）Ｍａ、（１６０７±１２８）Ｍａ和（１２５８±７０）Ｍａ的年龄，确定了昆阳群中亚群时代约为１６００—１８００Ｍａ，属晚古元古代，上亚群大营盘组约为１２００—１３００Ｍａ，属中元古代。还应用铅同位素化探技术系统研究了汤丹铜矿１号硐中段西１４穿脉岩石－矿石的铅同位素组成，结果表明铅同位素Ｖ１值与铜含量呈反相关系。这是运用系统剖面方法开展铅同位素化探的首次尝试。     

Petrogenesis of plio-quaternary intra-plate continental alkaline lavas from the İskenderun Gulf (Southern Turkey): Evidence for metasomatized lithospheric mantle

The Quaternary alkaline volcanic field of Southern Turkey is characterized by intra-continental plate-type magmatic products, exposed to the north of the ?skenderun Gulf along a NE-SW trending East Anatolian Fault, to the west of its intersection with the N–S trending Dead Sea Fault zone. The ?skenderun Gulf alkaline rocks are mostly silica-undersaturated with normative nepheline and olivine and are mostly classified as basanites and alkaline basalts with their low-silica contents ranging between 43 and 48?wt.% SiO₂. They display Ocean Island Basalt (OIB)–type trace element patterns characterized by enrichments in large-ion-lithophile elements (LILE) and light rare earth element (LREE), and have (La/Yb)_N?=?8.8–17.7 and (Hf/Sm)_N?=?0.9–1.6 similar to those of basaltic rocks found in intraplate suites. The basanitic rocks have limited variations Sr-Nd isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.70307–0.70324, ¹⁴³Nd/¹⁴⁴Nd?=?0.512918–0.521947), whereas the alkali basalts display more evolved Sr-Nd isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.70346-0.70365, ¹⁴³Nd/¹⁴⁴Nd?=?0.512887–0.521896). The ?skenderun Gulf alkaline rocks also display limited Pb isotopic variations with ²⁰⁶Pb/²⁰⁴Pb?=?18.75–19.09 ²⁰⁷Pb/²⁰⁴Pb?=?15.61–15.66 and²⁰⁸Pb/²⁰⁴Pb?=?38.65–39.02, indicating that they originated from an enriched lithospheric mantle source. Calculated fractionation vectors indicate that clinopyroxene and olivine are the main fractionating mineral phases. Similarly, based on Sr-Nd isotopic ratios, the assimilation and fractional crystallization (AFC) modeling shows that the alkali basalts were affected by AFC processes (r?=?0.2) and were slightly contaminated by the upper crustal material.The high TiO₂ contents, enrichments in Ba and Nb, and depletions in Rb can likely be explained by the existence of amphibole in the mantle source, which might, in turn, indicate that the source mantle has been affected by metasomatic processes. The modeling based on relative abundances of trace elements suggests involvement of amphibole-bearing peridotite as the source material. ?skenderun Gulf alkaline rocks can thus be interpreted as the products of variable extent of mixing between melts from both amphibole-bearing peridotite and dry peridotite.     

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.     

陕西渭北东部岩溶水环境同位素

陕西渭北东部岩溶水系统是一个复杂的地下水系统，碳酸盐岩大面积隐伏与深埋。使用传统手段和方法勘查岩溶地下水和研究可持续开发利用方案遇到诸多困难，不仅费时，而且耗资大。本文通过系统分析研究陕西渭北东部地区岩溶地下水T、D、^180、^14C环境同位素特征，揭示岩溶水的补给迳流排泄条件、岩溶水系统边界性质以及岩溶水与黄河洛河地表水、黄河岩溶泉与洛河岩溶泉之间的补排关系。结果显示环境同位素方法简便有效，能够达到预期目的。     

粤东桃子窝锡矿区火山-次火山岩和花岗岩锆石U-Pb年龄、Hf同位素特征及其意义

桃子窝锡矿位于莲花山断裂带西段,是典型的火山-次火山岩型锡矿。本文以桃子窝锡矿赋矿火山-次火山岩及花岗岩为研究对象,首次开展LA-ICP-MS锆石U-Pb定年和Hf同位素特征研究。获得两个次火山岩样品的锆石206Pb/238 U加权平均年龄为172.1±1.1 Ma和171.8±0.9 Ma,一个花岗岩样品的锆石206 Pb/238 U加权平均年龄为168.9±1.5 Ma,表明桃子窝锡矿火山-侵入岩为中侏罗世同一岩浆事件不同阶段的产物。锆石εHf(t)值大多数为负值,只有3个点的值大于0,变化于-13.96~9.53之间,平均值为-7.92。在εHf(t)-t图解上,εHf(t)值大多落在球粒陨石演化线之下,有3个点落在球粒陨石与亏损地幔演化线之间。二阶段模式年龄除3个点介于609.6~795.5 Ma外,其余点年龄为1 450.8~2 102.5 Ma,Hf同位素特征指示成岩物质主要来源于早中元古代古老地壳的部分熔融,还有新元古代新生地壳物质的加入。结合区内已有的研究成果,认为桃子窝锡矿及有关的火山-次火山岩与中生代太平洋板块向欧亚大陆俯冲有关。     

S?o Francisco-Congo Craton break-up delimited by U-Pb-Hf isotopes and trace-elements of zircon from metasediments of the Ara?uaí Belt

Detrital zircon U-Pb geochronology combined with Hf isotopic and trace element data from metasedimentary rocks of the Aracuai Belt in southeastern Brazil provide evidence for break-up of the Congo-Sao Francisco Craton. The U-Pb age spectra of detrital zircons from metasediments of the Rio Doce Group(RDG) range from 900-650 Ma and define a maximum depositional age of ca. 650 Ma. Zircon trace element and whole rock data constrain an oceanic island arc as source for the deposition setting of the protoliths to the metasediments. Zircon ε_(Hf)(t) values from these rocks are positive between +1 and +15, supporting previous evidence of a Neoproterozoic extensional phase and oceanic crust formation in a precursor basin to the Aracuai Belt. Recrystallization of detrital zircon at ca. 630 Ma is compatible with a regional metamorphic event associated with terrane accretion to the Paleoproterozoic basement after transition from an extensional to a convergent regime. The juvenile nature, age spectra and trace element composition recorded in detrital zircons of metasediments from the Aracuai Belt correspond with zircons from metasedimentary rocks and oceanic crust remnants of other orogenic belts to its south. This suggests that rifting and oceanic crust formation of the entire orogenic system, the so-called Mantiqueira Province, was contemporaneous, most likely related to the opening of a large ocean. It further indicates that the cratonic blocks involved in the orogenic evolution of the Mantiqueira Province were spatially connected as early as 900 Ma.     

Low-pressure,water-assisted anatexis of basic dykes in a contact metamorphic aureole,Fuerteventura (Canary Islands): oxygen isotope evidence for a meteoric fluid origin

Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or negative δ¹⁸O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides, from within the aureole, show a similar evolution with lowest δ¹⁸O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts preserved in all dykes, retain typically magmatic δ¹⁸O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ¹⁸O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures promoting increasing exchange during recrystallisation. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

鄂尔多斯盆地能源矿产氯仿沥青Sm-Nd同位素研究

对鄂尔多斯盆地石油、煤、含铀砂岩及其围岩的氯仿沥青进行了Sm-Nd同位素研究。结果表明,盆地流体(包括深部流体)活动具有多期性,且后期的流体活动对铀矿床的形成具有重要作用;赋存于同一套地层中的含铀砂岩沥青、煤沥青及石油沥青,虽然均具有富集地幔特征,但并非同期活动的产物;东胜矿区侏罗系直罗组煤沥青和盆地西南部陈家山矿区侏罗系延安组的煤沥青,源区时代上存在较大差异,伴生沥青并非全部由煤的热演化形成,可能还存在外来流体的加入,且东胜直罗组煤的伴生沥青较延安组煤的伴生沥青来源深度更大;盆地内马岭油田的直罗组石油沥青、陈家山延安组煤层石油沥青及其煤沥青在源区特征上具有内在联系。     

湘中邵阳凹陷二叠系龙潭组页岩含气性特征与气体成因

针对湘中地区邵阳凹陷二叠系龙潭组页岩气资源评价,部署了页岩气调查井2015H-D3井,通过现场解析气等相关样品测试定量分析了页岩含气性特征及其影响因素,并借助气体稳定碳、氢同位素对气体成因进行了初步探讨.结果显示:钻深从150m处开始出现气显,随深度增加,解析气含量呈现先逐渐增大后减小的趋势,300～425m为最高含气层段,累计厚度达125m,现场解析气含量全部大于0.5m^3/t,最高为2.35m^3/t,平均1m^3/t,证实龙潭组具良好页岩气资源潜力.当埋深大于300m时,解析气含量受有机碳含量控制,而埋深小于300m时,解析气含量并不简单受控于有机碳含量,而是受到保存条件的严重制约.气体碳、氢同位素测试显示δ13C1介于-29.87‰～-36.82‰,平均为-34.52‰,δ¹³C_2介于-29.45‰～-31.02‰,平均为-30.09‰,δD1介于-131.20‰～-178.40‰,平均为-167.40‰.气体成因分析揭示龙潭组页岩气属热成因中的油型气类型.基于沉积现象判断龙潭组为海陆过渡相环境,与氢同位素判断结果基本吻合,但目前还无法确定具体判定区间.     

广西芒场锡多金属矿田稳定同位素组成对矿床成因探讨

笔者曾对广西芒场锡多金属矿田的稳定同位素进行研究。本文根据硫、铅、氢、氧、碳等稳定同位素组成和锶的初始值提供的信息.探讨了矿床成因。并结合矿田矿床地质特征、控矿条件及有关统计参数,参考前人对矿床认识的基础上,修正提出了该矿田混合热液成矿模式,可供类似矿床研究和找矿的参考。