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61.
新元古代晚期—寒武纪早期是地球历史演化的关键时期,整个生物圈、大气圈和水圈在此期间都发生了巨大的变化,海水成分在其间也发生了明显的变化。而石盐流体包裹体恰恰记录了该时段海水主要离子成分的转变:海水成分从新元古代晚期的“文石海”,快速转化为寒武纪的“方解石海”;同时海水中的碳、锶、硫同位素都发生了剧烈的改变,其中海水硫酸根的硫同位素从新元古代冰期前的20‰左右,迅速升高到新元古代冰期后的35‰左右,甚至可以到45‰,海相蒸发岩沉积中的硫酸盐沉积(主要是石膏、硬石膏)则直接记录了当时海水中硫酸根的硫同位素变化。现有研究表明,新元古代晚期——寒武纪时期的海相蒸发岩沉积记录了当时海洋中存在着地质历史时期最大的硫同位素异常,即“Yudomski事件”。塔里木盆地的寒武纪早期、中期蒸发岩记录了“Yudomski事件”的硫同位素异常高值(35‰左右,甚至更高),表明这一起源于新元古代晚期的同位素异常事件持续到了寒武纪的早期和中期;塔里木盆地奥陶纪早期的蒸发岩、鄂尔多斯盆地奥陶纪中期蒸发岩和美国Williston盆地奥陶纪晚期地层的蒸发岩的硫同位素数据相似,都在+25‰左右则记录了较低的海洋硫同位素值,表明起源于新元古代冰期之后的“Yudomski事件”的硫同位素异常,持续到了寒武纪的中期,而结束于寒武纪的晚期。 相似文献
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众多研究表明黄河源区受气候变化影响,土壤活动层逐渐下降。土壤温、湿度是陆面过程及地球系统中的重要物理量,它们通过影响地表能量和物质交换而影响大气环流和降水等。利用WRF(Weather Research and Forecasting)模式,选取2个典型年分别设计了2个控制试验和2个敏感性试验来探讨土壤初始状况变化对区域水循环的影响,通过再循环降水率定量描述不同气候背景下陆面对黄河源区水循环的影响,并尝试从环流角度进一步分析土壤初始状况改变对源区水循环影响的物理机制。结果表明:陆面对水循环的影响受大尺度环流背景场影响较大,较弱的环流背景下再循环降水率较强环流背景大5%左右。土壤初始状况对水循环要素有一定程度的影响。土壤初始温度升高/降低,水汽通量增多/减少,后期降水增大/减小。不同环流背景下,土壤记忆时间不同,在弱的环流背景下,土壤记忆时间要长,初始状况扰动可持续1~2个月。 相似文献
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Bo XIAO Kezhang QIN Guangming LI Jinxiang LI Daixiang XIA Lei CHEN Junxing ZHAO 《Resource Geology》2012,62(1):4-18
The Miocene Qulong porphyry Cu‐Mo deposit, which is located at the Gangdese orogenic belt of Southern Tibet, is the largest porphyry‐type deposit in China, with confirmed Cu ~10 Mt and Mo ~0.5 Mt. It is spatially and temporally associated with multiphase granitic intrusions, which is accompanied by large‐scale hydrothermal alteration and mineralization zones, including abundant hydrothermal anhydrite. In addition to hydrothermal anhydrite, magmatic anhydrite is present as inclusions in plagioclase, interstitial minerals between plagioclase and quartz, and phenocrysts in unaltered granodiorite porphyry, usually in association with clusters of sulfur‐rich apatite in the Qulong deposit. These observations indicate that the Qulong magma‐hydrothermal system was highly oxidized and sulfur‐rich. Three main types of fluid inclusions are observed in the quartz phenocrysts and veins in the porphyry: (i) liquid‐rich; (ii) polyphase high‐salinity; and (iii) vapor‐rich inclusions. Homogenization temperatures and salinities of all type inclusions decrease from the quartz phenocrysts in the porphyry to hydrothermal veins (A, B, D veins). Microthermometric study suggests copper‐bearing sulfides precipitated at about 320–400°C in A and B veins. Fluid boiling is assumed for the early stage of mineralization, and these fluids may have been trapped at about 35–60 Mpa at 460–510°C and 28–42 Mpa at 400–450°C, corresponding to trapping depths of 1.4–2.4 km and 1.1–1.7 km, respectively. 相似文献
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俯冲带是全球最大的物质循环系统,控制着硫(S)在地球内部圈层及表层的循环,影响着大气圈、水圈、生物圈、岩石圈的稳定性以及地球的宜居性。厘清S在俯冲带中的地球化学行为和循环特征对理解地球各储库的氧化还原状态、岩浆作用与演化、成矿物质聚集、以及地球大气成分等具有重要意义。本文首先总结了进入俯冲带之前的大洋岩石圈的S结构模型,对S在大洋板片中的分布状态和地球化学特征进行了系统归纳。随后,系统阐述了俯冲带高压-超高压变质岩记录的板片变质及脱水过程中硫的地球化学行为。岩石学研究表明俯冲板片中的S多以硫化物相存在,硫酸盐矿物在弧前深度就已被释放或分解。相较于熔体,俯冲带流体中S的溶解度更高,是运移硫的更有效方式。DEW模型计算结果显示,流体中S含量总体较低,但在俯冲板片~90km处其含量有一个峰值(浓度0.5%~1.0%)。岩相学证据、地球化学测试结果、磷灰石S近边吸收结构(S-XANES)特征以及模拟结果都显示俯冲深部流体中S多以HS^(-)及H_(2)S形式存在,不含大量的SO_(4)^(2-)及硫酸盐;中f_(S_(2))流体有利于S迁移出俯冲板片,从而促进俯冲带大规模S循环,而高f_(S_(2))流体在流-岩交换过程沿流体通道发生S的锁固作用而不利于俯冲带S循环。质量平衡计算显示全球俯冲带S输入通量为4.65×10^(13)g/yr,弧下深度板片S输出通量为2.91×10^(12)g/yr,板片-岛弧S循环效率仅6.3%。俯冲板片在弧下深度可能存在一个短暂高效的S释放窗口,释放流体的δ^(34)S值为-2.1±3.0‰。基于高压-超高压变质岩中硫化物的研究,初步厘清了俯冲板片中S的地球化学行为,首次从板片角度全面、定量地限定了俯冲带的脱硫通量、效率、种型和同位素特征,提出俯冲带循环的S不是岛弧岩浆的氧化剂,与岛弧环境的正δ^(34)S值也无直接因果联系,对解析俯冲带S循环和理解地球长期的S循环具有重要意义。最后,本文还展望了俯冲带S循环的未来发展方向,应在俯冲带流体氧化还原性质(硫酸盐的命运)、俯冲沉积物对S循环的制约、俯冲带环境下多硫同位素的分馏效应、S循环与其它挥发分(如C等)循环之间的耦合关系、地球历史上深部S循环等方向做出探索,更深入地理解俯冲带及全球S循环过程。 相似文献
66.
AbstractAdequate water resources management at the basin level needs quality downscaling of climate change scenarios for application to impact assessment and adaptation work. This study evaluates the ability of a regional climate model (RegCM3) to simulate the present-day climate and regional water balance over the Niger River Basin (NRB). RegCM3 gives a good simulation of the NRB hydroclimatic features. The mean bias error for monthly temperature is 1.5°C, 0.3 mm d-1 for rainfall, and 0.4 mm d-1 for runoff. Moderate to high correlations (0.66–0.95) were found between the modelled and the observed variables. RegCM3-based water cycling indices were not statistically different from the observation. Seasonal moistening efficiency (m) ranges between 19% and 37%; 66% of the available atmospheric moisture over NRB precipitates between June and September, of which 21% originates from local evaporation. The result suggests that the moisture sink period is July to October with very high precipitation efficiency over the basin. The model reproduces the hydroclimatology of the NRB and hence is a suitable tool for further studies relating to the assessment of climate change impacts on river basin water systems.
Editor Z. W. Kundzewicz; Associate editor D. Hughes 相似文献
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电子废物跨境转移近年来开始引起国际经济地理学者关注,其中折射了全球生产网络中污染控制与市场化再生利用之间的治理矛盾和价值冲突。中国在规范电子废物管理的过程中,采纳了生产者责任延伸制度,逐渐形成生产者缴纳政府基金,基金补贴正规处理厂,正规处理厂再通过市场采购方式从非正式的回收渠道收集电子废物的分工格局。这一格局杂合了巴塞尔公约的属地化管理机制和地区贸易的市场化机制,反映了政府在规制复杂产品环境问题中所面临的两难。本文在多年参与式调查的基础上,根据环保部公布的2014年全国109家正规处理厂实际回收废弃家电产品的数量,采用威尔逊空间相互作用模型,估算了全国非正式回收渠道内的废旧家电产品地区间流动格局,并结合处理厂问卷调查对比了实际流向与理论模型的差异。研究结果显示:由于非正式回收渠道的竞争性所导致的废旧家电跨省流动占到全国正规渠道电子废物回收总量的1/3以上,这与电子废物处理设施省级属地化管理,主要满足本省产生的电子废物处理需求的规划初衷有较大出入。为此本文探讨了这种规划目标与市场流动之间发生错位的内在原因,指出当前电子废物管理重点应该从围绕处理设施的管理控制转向逆向物流系统的优化和商业模式创新。 相似文献
70.
Yaofa Jiang Erika R. Elswick Maria Mastalerz 《International Journal of Coal Geology》2008,73(3-4):273-284
Sulfur occurs in multiple mineral forms in coals, and its fate in coal combustion is still not well understood. The sulfur isotopic composition of coal from two coal mines in Indiana and fly ash from two power plants that use these coals were studied using geological and geochemical methods. The two coal beds are Middle Pennsylvanian in age; one seam is the low-sulfur (< 1%) Danville Coal Member of the Dugger Formation and the other is the high-sulfur (> 5%) Springfield Coal Member of the Petersburg Formation. Both seams have ash contents of approximately 11%. Fly-ash samples were collected at various points in the ash-collection system in the two plants. The results show notable difference in δ34S for sulfur species within and between the low-sulfur and high-sulfur coal. The δ34S values for all sulfur species are exclusively positive in the low-sulfur Danville coal, whereas the δ34S values for sulfate, pyritic, and organic sulfur are both positive and negative in the high-sulfur Springfield coal. Each coal exhibits a distinct pattern of stratigraphic variation in sulfur isotopic composition. Overall, the δ34S for sulfur species values increase up the section in the low-sulfur Danville coal, whereas they show a decrease up the vertical section in the high-sulfur Springfield coal. Based on the evolution of δ34S for sulfur species, it is suggested that there was influence of seawater on peat swamp, with two marine incursions occurring during peat accumulation of the high-sulfur Springfield coal. Therefore, bacterial sulfate reduction played a key role in converting sulfate into hydrogen sulfide, sulfide minerals, and elemental sulfur. The differences in δ34S between sulfate sulfur and pyritic sulfur is very small between individual benches of both coals, implying that some oxidation occurred during deposition or postdeposition.The δ34S values for fly ash from the high-sulfur Springfield coal (averaging 9.7‰) are greatly enriched in 34S relative to those in the parent coal (averaging 2.2‰). This indicates a fractionation of sulfur isotopes during high-sulfur coal combustion. By contrast, the δ34S values for fly-ash samples from the low-sulfur Danville coal average 10.2‰, only slightly enriched in 34S relative to those from the parent coal (average 7.5‰). The δ34S values for bulk S determined directly from the fly-ash samples show close correspondence with the δ34S values for SO4− 2 leached from the fly ash in the low-sulfur coal, suggesting that the transition from pyrite to sulfate occurred via high-temperature oxidation during coal combustion. 相似文献