大别山北缘中生代火山—侵入岩锶—钕同位素组成特征及其物质来源

报道了大别山北缘中生代（早白垩世）不同成因系列火山－侵入岩的14个Rb-Sr,Sm-Nd同位素分析数据，其中正长岩类ISr值为0．70943－0．71014，εNd值为－14．7－15．8，亏损地幔两阶段模式年龄TDM为2．12－2．20Ga；高钾钙碱性系列岩石ISr值为0．70750－0．71054，εNd值为－17．2－－19．1，TDM为2．32－2．48Ga，橄榄安粗岩系列岩石ISr值为0．70873－0．70912，εNd值为－20．7－21．7，TDM为2．60－2．68Ga。通过与基底变质岩Sm-Nd同位素组成对比，认为高钾钙碱性系列主要由类似于大别群的地壳岩石衍生而成，正长岩类是由大别群和少量较年轻地壳岩石（卢镇关群和佛子岭群？）衍生而成的，而橄榄安粗岩系列则来源于富集地幔并可能混入少量更古老的类似于泰山群的地壳组分。     

Petrogenesis and tectonic implications of Early Cretaceous andesitic-dacitic rocks,western Qinling(Central China):Geochronological and geochemical constraints

~(40)Ar/~(39)Ar and zircon U-Pb geochronological and whole-rock geochemical analyses for the Laozanggou intermediate-acidic volcanic rocks from the western Qinling orogenic belt,Central China,constrain their petrogenesis and the nature of the Late Mesozoic lithospheric mantle.These volcanic rocks yield hornblende or whole-rock ~(40)Ar/~(39)Ar plateau ages of 128.3-129.7 Ma and zircon U-Pb age of131.3±1.3 Ma.They exhibit Si02 of 56.86-66.86 wt.%,K_2 O of 0.99-2.46 wt.% and MgO of 1.03-4.47 wt.%,with Mg# of 42-56.They are characterized by arc-like geochemical signatures with significant enrichment in LILE and LREE and depletion in HFSE.All the samples have enriched Sr-Nd isotopic compositions with initial ~(87)Sr/~(86)Sr ratios ranging from 0.7112 to 0.7149 and ε_(Nd)(t) values from 10.2 to 6.3.Such geochemical signatures suggest that these volcanic rocks were derived from enriched lithospherederived magma followed by the assimilation and fractional crystallization(AFC)process.The generation of the enriched lithospheric mantle is likely related to the modification of sediment-derived fluid in response to the Triassic subduction/collision event in Qinling orogenic belt.The early Cretaceous detachment of the lithospheric root provides a reasonable mechanism for understanding the petrogenesis of the Laozanggou volcanic sequence in the western Qinling orogenic belt.     

土壤和围岩地球化学组成及气候对洞穴滴水水化学的影响——以湖北清江和尚洞为例

大气降水渗入土壤,穿过围岩,将气候与地表环境信息导入洞穴滴水,最终被洞穴沉积物所记录,因而研究土壤、围岩与洞穴滴水的地球化学组成及3者之间的联系对了解气候和环境信号的传递以及石笋古环境信息的正确解译十分重要。通过对比清江地区和尚洞上覆土壤、围岩与滴水的元素及锶同位素N(87Sr)/N(86Sr)地球化学组成特征,进而调查土壤和围岩对洞穴滴水水化学的影响。结果表明:滴水的n(Mg)/n(Ca)、n(Ba)/n(Ca)、n(Sr)/n(Ca)及N87Sr)/N(86Sr)介于土壤和围岩之间,说明滴水物质组成来自土壤和围岩的混合;滴水的n(S)/n(Ca)大于土壤和围岩,说明有第三端元的混入,可能是大气硫沉降的结果。通过模型计算可知,土壤和围岩对和尚洞滴水各元素组成的贡献并不相同,贡献的相对大小不仅与元素本身的地球化学性质有关,而且随气候和环境而发生变化。     

三沙市美济礁滨珊瑚记录的近百年海面温度变化

利用南沙群岛美济礁滨珊瑚Sr/Ca建立与海面温度（SST）的关系式,后报近百年南沙群岛海区高分辨率的SST序列。结果显示：美济礁近百年SST的年平均值为28.4℃,最高值为29.2℃（1998 AD）,最低值为27.6℃（1917 AD）,相差1.6℃。近百年SST呈增暖趋势,升温速率为0.025℃/10 a,但存在年代际的温度波动,其中1906―1927 AD呈降温态势,1928―1938 AD呈增温态势,1939―1957 AD呈降温态势,1958年后SST呈波动上升趋势。近百年SST呈现3.5 a、33 a周期,显示受ENSO和太平洋年代际涛动（PDO）影响。     

内蒙古岱海地区小冰期气候演化特征的地球化学记录

通过对地处气候敏感带的岱海湖泊岩芯介形类壳体丰度、Sr/Ca和Mg/Ca摩尔比值，以及自生碳酸盐氧同位素组成等地球化学指标的综合分析，结合岩芯的岩性特征和^210Pb、^14C测年，重建了岱海小冰期以来气候环境演化过程，揭示小冰期前期本区以冷湿气候为主，在中后期，气候寒冷干旱，间有气候转温和的冷湿、湿干气候。本区小冰期气温变化与华北其他地区具有一致性，但降水与气温组合状况复杂，反映了明显的区域特征，其原因可能是气候转型期经向环流加强，气旋活动加强所致。     

Accurate Determination of Sr Isotopic Compositions in Clinopyroxene and Silicate Glasses by LA‐MC‐ICP‐MS

The low‐Sr content (generally < 100 μg g^?1) in clinopyroxene from peridotite makes accurate Sr isotopic determination by LA‐MC‐ICP‐MS a challenge. The effects of adding N₂ to the sample gas and using a guard electrode (GE) on instrumental sensitivity for Sr isotopic determination by LA‐MC‐ICP‐MS were investigated. Results revealed no significant sensitivity enhancement of Sr by adding N₂ to the ICP. Although using a GE led to a two‐fold sensitivity enhancement, it significantly increased the yield of polyatomic ion interferences of Ca‐related ions and TiAr⁺ on Sr isotopes. Applying the method established in this work, ⁸⁷Sr/⁸⁶Sr ratios (Rb/Sr < 0.14) of natural clinopyroxene from mantle and silicate glasses were accurately measured with similar measurement repeatability (0.0009–0.00006, 2SE) to previous studies but using a smaller spot size of 120 μm and low‐to‐moderate Sr content (30–518 μg g^?1). The measurement reproducibility was 0.0004 (2s, n = 33) for a sample with 100 μg g^?1 Sr. Destruction of the crystal structure by sample fusion showed no effect on Sr isotopic determination. Synthesised glasses with major element compositions similar to natural clinopyroxene have the potential to be adopted as reference materials for Sr isotopic determination by LA‐MC‐ICP‐MS.     

滇西洱海北部北衙地区富碱斑岩的地球化学、锆石SHRIMP U-Pb定年及成因

用SHRIMP锆石U-Pb测年法获得滇西北衙地区炭窑石英正长斑岩的年龄TY-1为31.5 Ma±1.1Ma,TY-3为31.34 Ma±0.73Ma,证明该斑岩形成于新生代。北衙富碱斑岩具有富碱、高钾的特点,总体属于钾玄岩系列的岩石。岩石富轻稀土和Rb、Ba等大离子亲石元素而亏损Nd、Ta等高场强元素。岩石的∑LREE/∑HREE比值和(La/Yb)N比值高,Eu异常不明显。综合北衙地区富碱侵入岩的常量、微量、稀土元素和同位素地球化学特征发现,富碱斑岩具有许多与埃达克岩（adakite）相似的岩石地球化学特征,但又与Defant等定义的典型埃达克岩有明显的差别,而与中国可可西里钾质埃达克岩更为接近。通过对北衙地区富碱斑岩的Sr、Nd、Pb同位素的系统研究发现,富碱斑岩的源区具有EMⅡ富集地幔的地球化学特征。     

海南省抱板群研究的新进展

根据对抱板群的最新研究，自下而上建立两个岩石地层单位，即戈枕村组、峨文岭组。戈枕村组由片麻岩类变粒岩组成，厚度大于２３８１ｍ，具混合岩化。该组测得锆石一致曲线上交点年龄（１８２４±７７）Ｍａ，混合岩脉体ＲｂＳｒ等时线年龄（１６３７±３１）Ｍａ，推测形成于１６００～１８００Ｍａ之间，相当于长城纪早期。峨文岭组以各类片岩为主，其次是石英岩和变粒岩，无混合岩化作用。侵入该组的变质花岗岩体，测定３个锆石ＵＰｂ一致曲线年龄分别为（１４５６±６６）、１４４１、（１３６４±２５．６７）Ｍａ；另一件锆石蒸发法２０７Ｐｂ／２０６Ｐｂ峰值年龄为（１４０７±２０）Ｍａ。以上数据表明其形成年龄为１６００～１４００Ｍａ，相当于长城纪晚期     

Chronology of Early to Mid-Pleistocene sediments in the northern North Sea: New evidence from amino acid and strontium isotope analyses

Sediments deposited during glacial-interglacial cycles through the Early to Mid-Pleistocene in the North Sea are chronologically poorly constrained. To contribute to the chronology of these units, amino acid racemization (AAR) and strontium (Sr) isotope analyses have been performed on samples from four shallow borings and one oil well along a transect in the northern North Sea. D/L Asp (aspartic acid) values obtained through reverse-phase liquid chromatography in the benthic foraminiferal species Elphidium excavatum is focused on because of consistent results and a good stratigraphic distribution of this benthic species. For the Early Pleistocene, an age model for the well 16/1–8, from the central part of the northern North Sea based on Sr ages allows for dating of the prograding wedges filling the pre-Quaternary central basin. A regional calibration curve for the racemization of Asp in Elphidium excavatum is developed using published ages of radiocarbon-dated samples and samples associated with the previously identified Bruhnes/Matuyama (B/M) paleomagnetic boundary and a Sr age from this study. Based on all the available geochronological evidence, samples were assigned to marine oxygen isotope stages (MIS) with uncertainties on the order of 10–70 ka.Sr ages suggest a hiatus of <2 million years (Ma) possibly due to non-deposition or low sedimentation between the Utsira Formation (Pliocene) and the Early Pleistocene. An increase in sedimentation rates around 1.5 ± 0.07 Ma (∼MIS 51) may partly be due to sediment supply from rivers from the south-east and partly due to the extension of ice sheet around 1.36 ± 0.07 Ma from the Norwegian coast to the central North Sea. A possible basin-wide glaciation occurred around 1.1 Ma (∼ MIS 32) (upper regional unconformity/top of unit Q4 in this study), resulting in erosion and regional unconformity. Two interglacials in the Norwegian Channel have been dated: the Radøy Interglacial to 1.07 ± 0.01 Ma (possibly MIS 31, the ‘super interglacial’), and the Norwegian Trench Interglacial to 0.50 ± 0.02 Ma (possibly MIS 13). A massive till unit identified at the same stratigraphic level in all shallow borings may partly represent an extensive MIS 12 glaciation. This study shows that the combined use of amino acid racemization data and Sr isotope chronology can refine the chronological ambiguities of Quaternary North Sea sediments related partly to the impact of glacial processes.