Geochemical and biological consequences of groundwater augmentation in lakes of west-central Florida (USA)

We studied sediment cores from four Florida (USA) lakes that have received groundwater hydrologic supplements (augmentation) for >30 years to maintain lake stage. Top samples (0–4 cm) from sediment cores taken in Lakes Charles, Saddleback, Little Hobbs, and Crystal had ²²⁶Ra activities of 44.9, 17.5, 7.6, and 8.5 dpm g⁻¹, respectively, about an order of magnitude greater than values in deeper, older deposits. The surface sample from Lake Charles yielded the highest ²²⁶Ra activity yet reported from a Florida lake core. Several lines of evidence suggest that groundwater augmentation is responsible for the high ²²⁶Ra activities in recent sediments: (1) ²²⁶Ra activity in cores increased recently, (2) the Charles, Crystal, and Saddleback cores display ²²⁶Ra/²¹⁰Pb disequilibrium at several shallow depths, suggesting ²²⁶Ra entered the lakes in dissolved form, (3) cores show recent increases in Ca, which, like ²²⁶Ra, is abundant in augmentation groundwater, and (4) greater Sr concentrations are associated with higher ²²⁶Ra activities in recent Charles and Saddleback sediments. Sr concentrations in Eocene limestones of the deep Floridan Aquifer are high relative to Sr concentrations in surficial quartz sands around the lakes. Historical water quality inferences for the lakes were based on diatom assemblages in sediments. Recent alkalization in Lakes Charles, Saddleback, Little Hobbs, and Crystal was inferred from weighted-averaging calibration (WACALIB). The lakes also show recent trophic state increases based on WACALIB-derived estimates for limnetic total P. Although residential and agricultural sources might contribute to increased P loading, P in augmentation waters probably has had significant influence on eutrophication. Dystrophic diatoms were abundant in the early history of Lakes Saddleback, Little Hobbs, and Crystal, which suggests that these lakes contained more tannic waters during the past than at present, perhaps as a consequence of greater inflows from surrounding wetlands. Ionic content of lake waters increased, as indicated by diatom autecological analysis. Recent geochemical and biological changes detected in cores from these lakes probably are a result of deliberate groundwater augmentation, although inputs of groundwater pumped for agricultural and residential development in the watersheds also might have contributed to limnological changes.     

前陆背景下的两种正断裂现象及其相互作用模式

许多前陆盆地同时存在着下部的裂陷正断裂和上部的造山期的挠曲正断裂。作用在均质不分层和非均质分层板块中的挠曲正断裂具有不同的外观形态和形变的空间协调机制，前者断面陡直、贯穿深远；后者则呈坡坪式形态。裂陷正断裂和挠曲正断裂具有3种相互作用方式、差异甚殊的断裂总体形态和中性面分布位置不同的应力体制。Ⅰ类，挠曲正断裂局限在陆缘期或坳陷期层序中；Ⅱ类，裂陷期正断裂断至断陷期层序，且以裂陷正断裂为基础而存在，二者构成完整而独特的断裂组合；Ⅲ类，挠曲正断裂亦断穿至断陷期层序，但和裂陷正断裂并不存在直接关系。这三类关系对孔隙—裂缝网络体具有不同的影响，并和应力体制一道，对流体尤其是烃类的作用过程有差异很大的影响。地层在跨越同生正断裂和挠曲正断裂时所发生的厚度的变化，起因于二者在物源方向上的完全不同。     

The devastating Muzaffarabad earthquake of 8 October 2005: New insights into Himalayan seismicity and tectonics

The recent earthquake of 8 October 2005 in the Muzaffarabad region in western Himalaya destroyed several parts of Pakistan and the north Indian state of Jammu and Kashmir. The earthquake of magnitude 7.6 claimed more than 80,000 lives, clearly exposing the poor standards of building construction — a major challenge facing the highly populated, earthquake prone, third world nations today. In this paper, we examine variations in the stress field, seismicity patterns, seismic source character, tectonic setting, plate motion velocities, GPS results, and the geodynamic factors relating to the geometry of the underlying subsurface structure and its role in generation of very large earthquakes. Focal mechanism solutions of the Muzaffarabad earthquake and its aftershocks are found to have steep dip angles comparable to the Indian intra-plate shield earthquakes rather than the typical Himalayan earthquakes that are characterized by shallow angle northward dips. A low p-value of 0.9 is obtained for this earthquake from the decay pattern of 110 aftershocks, which is comparable to that of the 1993 Latur earthquake in the Indian shield — the deadliest Stable Continental Region (SCR) earthquake till date. Inversion of focal mechanisms of the Harvard CMT catalogue indicates distinct stress patterns in the Muzaffarabad region, seemingly governed by an overturned Himalayan thrust belt configuration that envelops this region, adjoined by the Pamir and Hindukush regions. Recent developments in application of seismological tools like the receiver function technique have enabled accurate mapping of the dipping trends of the Moho and Lithosphere–Asthenosphere Boundary (LAB) of Indian lithosphere beneath southern Tibet. These have significantly improved our understanding of the collision process, the mechanism of Himalayan orogeny and uplift of the Tibetan plateau, besides providing vital constraints on the seismic hazard threat posed by the Himalaya. New ideas have also emerged through GPS, macroseismic investigations, paleoseismology and numerical modeling approaches. While many researchers suggest that the Himalayan front is already overdue for several 8.0 magnitude earthquakes, some opine that most of the front may not really be capable of sustaining the stress accumulation required for generation of great earthquakes. We propose that the occurrence of great earthquakes like those of 1897 in Shillong and 1950 in Assam have a strong correlation with their proximity to multiple plate junctions conducive for enormous stress build up, like the eastern Himalayan syntaxis comprising the junction of the India, Eurasia plates, and the Burma, Sunda micro-plates.     

Coulomb stress triggering of earthquakes along the Atalanti Fault, central Greece: Two April 1894 M6+ events and stress change patterns

Two M6+ events occurred 15–20 km apart in central Greece on April 20 and April 27, 1894. We identify the April 27, 1894 rupture (2nd in the sequence) with the Atalanti segment of the Atalanti Fault Zone because of unequivocal surface rupturing evidence reported by Skouphos [Skouphos, T., 1894. Die swei grossen Erdbeben in Lokris am 8/20 und 15/27 April 1894. Zeitschrift Ges. Erdkunde zu Berlin, vol. 24, pp. 409–474]. Coulomb stress transfer analysis and macroseismic evidence suggest that the April 20, 1894 event (1st in the sequence) may be associated with the Martinon segment of the same fault zone. Our stress modelling suggests that this segment may have ruptured in an M = 6.4 event producing a 15-km long rupture which transferred 1.14 bar in the epicentral area of the April 27th, 1894 event, thus triggering the second M = 6.6 earthquake along the Atalanti segment and producing a 19-km long rupture. We also examined three alternative fault sources for the first event; however, all these produce smaller stress stresses for triggering the second event. The proposed slip model for the second earthquake is capable of producing coastal subsidence of the order of centimetres to decimetres, which fits the geological data. The 1894 earthquake sequence was followed by a difference in the timing of subsequent M > 5 events in each of the “relaxed” areas (stress shadows; a negative change in Coulomb failure stress > − 0.6 bar), which terminated between 22–37 years (north) and 80 years (south).     

Speciation of Chromium in Artificially Contaminated Soil Reference Material GSJ JSO-2 Using XANES and Chemical Extraction Methods

The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g^-1 for JSO-2, 1352 μg g^-1 for mimic-JSO-2 and 69-113 μg g^-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future.     

Small-scale spatial variation of the stress field in the back-arc Aegean area: Results from the seismotectonic study of the broader area of Mygdonia basin (N. Greece)

In the present work a detailed seismotectonic study of the broader area of the Mygdonia basin (N. Greece) is performed. Digital data for earthquakes which occurred in the broader Mygdonia basin and were recorded by the permanent telemetric network of the Geophysical Laboratory of the Aristotle University of Thessaloniki during the period 1989–1999 were collected and fault plane solutions for 50 earthquakes which occurred in the study area were calculated with a modified first motions approach which incorporates amplitude and radiation pattern information. Fault plane solutions for the 3 main shocks of Volvi (23/05/78, M_W = 5.8 and 20/06/78, M_W = 6.5) and Arnaia (04/05/95, M_W = 5.8) events and the 1978 aftershock sequence were additionally used. Moreover, data from two local networks established in the Mygdonia basin were also incorporated in the final dataset.Determination of the stress field was realized by the use of the method of Gephart and Forsyth [Gephart, J.W., Forsyth, D.W., 1984. An improved method for determining the regional stress tensor using earthquake focal mechanism data: application to the San Fernando earthquake sequence: Jour. Geophys. Res., v.89, no. B11, p. 9305–9320] for the stress tensor inversion and the results were compared with independent estimates based on the calculation of the average moment tensor [Papazachos, C.B.,Kiratzi, A.A., 1992. A formulation for reliable estimation of active crustal deformation and its application to central Greece. Geophys. J. Int. 111, 424–432]. The obtained stress results show a relatively good agreement between the two approaches, with differences in the azimuth of the dominant extension axis of the order of 10°. Furthermore, comparison with independent information for the mean stress axes provided by the study of kinematics on neotectonic faults [Mountrakis, D., Kilias, A., Tranos, M., Thomaidou, E., Papazachos, C., Karakaisis, G., Scordilis, E., Chatzidimitriou, P., Papadimitriou, E., Vargemezis, G., Aidona, E., Karagianni, E., Vamvakaris, D. Skarlatoudis, A. 2003. Determination of the settings and the seismotectonic behavior of the main seismic-active faults of Northern Greece area using neotectonic and seismological data. Earthquake Planning and Protection Organisation (OASP) (in Greek)] shows a similar agreement with typical misfit of the order 10°. The stress inversion method was modified in order to select one or both nodal planes of the focal mechanism which corresponds to the “true” fault plane of the occurred earthquakes and was able to select a single fault plane in the majority of examined cases. Using this approach, the obtained fault plane rose diagrams are in agreement with results from various neotectonic studies. Moreover, several secondary active fault branches were identified, which are still not clearly observed in the field.     

Seismicity and stress evolution in heterogeneous faults with various degrees of roughness

We investigate the effects of the spatial distribution of stress drop ratios (SDRs) on the fault of an earthquake sequence as well as stress evolution. To achieve this, we test four fault models, each with its own SDRs which differ with regard to wavelength components (roughness) but which share first-order similarity and the same mean value. We assume rupture processes are quasi-static and fluid-controlled. The evidence clearly shows that the locations of large earthquakes are more sensitive to distribution than to the values of the SDRs. For this reason, it is expected that reducing fault roughness should increase the number of large earthquakes but decrease the number of small ones. It is also clearly apparent that a clustered distribution of large earthquakes should be more frequently observed on heterogeneous faults, especially in areas with small gradient values of the SDRs. These phenomena are consistent with our finding that long-wavelength components of stress usually develop in areas with low gradients of the SDRs. A fault with a smoother distribution of SDRs should, therefore, exhibit a greater likelihood to generate large earthquakes. By contrast, in that a rough fault covers a smaller area on which long-wavelengths can develop, it should result in fewer large earthquakes but a much more highly clustered distribution.     

一种全新的铀矿勘查方法--大地气态水铀测量

大地气态水是大地土壤的重要组分,借助于地球碳循环向上迁移的铀离子流积聚于大地土壤层,在松散的大地土壤空气中形成地球化学异常。铀离子流与下伏赋存的矿体相呼应,因此设法采集近大地土壤空气中离子流转化为新形成的固定相之前的组分并分析测试之,从而发现隐伏的深埋铀矿体。该方法已在内蒙某地浸砂岩铀矿床上进行的两年初步试验工作(包括剖面性测量与面积性测量),结果表明,异常幅度明显高于常规铀金属量测量方法,地球化学异常衬度也大大好于常规铀金属量测量方法。该项技术在油气矿藏的勘查及其他金属矿产资源的勘查中也有重要的应用潜力。