Speciation of Chromium in Artificially Contaminated Soil Reference Material GSJ JSO-2 Using XANES and Chemical Extraction Methods

The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g^-1 for JSO-2, 1352 μg g^-1 for mimic-JSO-2 and 69-113 μg g^-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future.     

Small-scale spatial variation of the stress field in the back-arc Aegean area: Results from the seismotectonic study of the broader area of Mygdonia basin (N. Greece)

In the present work a detailed seismotectonic study of the broader area of the Mygdonia basin (N. Greece) is performed. Digital data for earthquakes which occurred in the broader Mygdonia basin and were recorded by the permanent telemetric network of the Geophysical Laboratory of the Aristotle University of Thessaloniki during the period 1989–1999 were collected and fault plane solutions for 50 earthquakes which occurred in the study area were calculated with a modified first motions approach which incorporates amplitude and radiation pattern information. Fault plane solutions for the 3 main shocks of Volvi (23/05/78, M_W = 5.8 and 20/06/78, M_W = 6.5) and Arnaia (04/05/95, M_W = 5.8) events and the 1978 aftershock sequence were additionally used. Moreover, data from two local networks established in the Mygdonia basin were also incorporated in the final dataset.Determination of the stress field was realized by the use of the method of Gephart and Forsyth [Gephart, J.W., Forsyth, D.W., 1984. An improved method for determining the regional stress tensor using earthquake focal mechanism data: application to the San Fernando earthquake sequence: Jour. Geophys. Res., v.89, no. B11, p. 9305–9320] for the stress tensor inversion and the results were compared with independent estimates based on the calculation of the average moment tensor [Papazachos, C.B.,Kiratzi, A.A., 1992. A formulation for reliable estimation of active crustal deformation and its application to central Greece. Geophys. J. Int. 111, 424–432]. The obtained stress results show a relatively good agreement between the two approaches, with differences in the azimuth of the dominant extension axis of the order of 10°. Furthermore, comparison with independent information for the mean stress axes provided by the study of kinematics on neotectonic faults [Mountrakis, D., Kilias, A., Tranos, M., Thomaidou, E., Papazachos, C., Karakaisis, G., Scordilis, E., Chatzidimitriou, P., Papadimitriou, E., Vargemezis, G., Aidona, E., Karagianni, E., Vamvakaris, D. Skarlatoudis, A. 2003. Determination of the settings and the seismotectonic behavior of the main seismic-active faults of Northern Greece area using neotectonic and seismological data. Earthquake Planning and Protection Organisation (OASP) (in Greek)] shows a similar agreement with typical misfit of the order 10°. The stress inversion method was modified in order to select one or both nodal planes of the focal mechanism which corresponds to the “true” fault plane of the occurred earthquakes and was able to select a single fault plane in the majority of examined cases. Using this approach, the obtained fault plane rose diagrams are in agreement with results from various neotectonic studies. Moreover, several secondary active fault branches were identified, which are still not clearly observed in the field.     

Seismicity and stress evolution in heterogeneous faults with various degrees of roughness

We investigate the effects of the spatial distribution of stress drop ratios (SDRs) on the fault of an earthquake sequence as well as stress evolution. To achieve this, we test four fault models, each with its own SDRs which differ with regard to wavelength components (roughness) but which share first-order similarity and the same mean value. We assume rupture processes are quasi-static and fluid-controlled. The evidence clearly shows that the locations of large earthquakes are more sensitive to distribution than to the values of the SDRs. For this reason, it is expected that reducing fault roughness should increase the number of large earthquakes but decrease the number of small ones. It is also clearly apparent that a clustered distribution of large earthquakes should be more frequently observed on heterogeneous faults, especially in areas with small gradient values of the SDRs. These phenomena are consistent with our finding that long-wavelength components of stress usually develop in areas with low gradients of the SDRs. A fault with a smoother distribution of SDRs should, therefore, exhibit a greater likelihood to generate large earthquakes. By contrast, in that a rough fault covers a smaller area on which long-wavelengths can develop, it should result in fewer large earthquakes but a much more highly clustered distribution.     

青藏高原热状况和海温异常对亚洲季风季节转换年际变化的影响

本文根据季节转换前后副高脊面附近经向温度梯度变号的本质，利用相关分析和合成分析等方法研究了季节转换年际变化与外部影响因子的联系. 结果表明，冬春季青藏高原热状况和ENSO（El Nio/Southern Oscillation，厄尔尼诺/南方涛动）是决定亚洲季风区季节转换年际变化的主要因素. 当冬、春季海温呈现El Nio异常时，Walker环流减弱，于是西太平洋暖池区对流活动受到抑制，而赤道东太平洋对流活动加强则强迫赤道印度洋地区产生绝热下沉运动，使得印度洋地区大气偏暖，结果增大了南北向温度梯度，季节转换往往偏晚. 反之，季节转换偏早. 初春高原上空对流层中高层的气温异常对于判断季节转换迟早有很好的指示意义.     

一种全新的铀矿勘查方法--大地气态水铀测量

大地气态水是大地土壤的重要组分,借助于地球碳循环向上迁移的铀离子流积聚于大地土壤层,在松散的大地土壤空气中形成地球化学异常。铀离子流与下伏赋存的矿体相呼应,因此设法采集近大地土壤空气中离子流转化为新形成的固定相之前的组分并分析测试之,从而发现隐伏的深埋铀矿体。该方法已在内蒙某地浸砂岩铀矿床上进行的两年初步试验工作(包括剖面性测量与面积性测量),结果表明,异常幅度明显高于常规铀金属量测量方法,地球化学异常衬度也大大好于常规铀金属量测量方法。该项技术在油气矿藏的勘查及其他金属矿产资源的勘查中也有重要的应用潜力。     

不同初始饱水状态红砂岩冻融损伤差异性研究

借助于红砂岩冻融循环CT扫描试验，从扫描层面内不同的感兴趣区域内CT均值数大小及其变化以及CT图像，对4种典型的不同初始饱水状态红砂岩进行冻融循环条件下损伤扩展差异性研究。研究结果表明，对于初始损伤相同的岩石，初始饱水状态将决定冻融循环对其损伤扩展的影响程度。     

An Optimal Adaptive Kalman Filter

In a robustly adaptive Kalman filter, the key problem is to construct an adaptive factor to balance the contributions of the kinematic model information and the measurements on the state vector estimates, and the corresponding learning statistic for identifying the kinematic model biases. What we pursue in this paper are some optimal adaptive factors under the particular conditions that the state vector can or cannot be estimated by measurements. Two optimal adaptive factors are derived, one of which is deduced by requiring that the estimated covariance matrix of the predicted residual vector equals the corresponding theoretical one. The other is obtained by requiring that the estimated covariance matrix of the predicted state vector equals its theoretical one. The two related optimal adaptive factors are given. These are analyzed and compared in theory and in an actual example. This shows, through the actual computations, that the filtering results obtained by optimal adaptive factors are superior to those obtained by adaptive factors based on experience.     

A model of low-mass neutron stars with a quark core

We consider an equation of state that leads to a first-order phase transition from the nucleon state to the quark state with a transition parameter λ>3/2 (λ=ρ_Q/(ρ_N+P₀/c²)) in superdense nuclear matter. Our calculations of integrated parameters for superdense stars using this equation of state show that on the stable branch of the dependence of stellar mass on central pressure dM/dP_c>0) in the range of low masses, a new local maximum with M_max=0.082_⊙ and R=1251 km appears after the formation of a toothlike kink (M=0.08M_⊙, R=205 km) attributable to quark production. For such a star, the mass and radius of the quark core are M_core=0.005M_⊙ and R_core=1.73 km, respectively. In the model under consideration, mass accretion can result in two successive transitions to a quark-core neutron star with energy release similar to a supernova explosion: initially, a low-mass star with a quark core is formed; the subsequent accretion leads to configurations with a radius of ～1000 km; and, finally, the second catastrophic restructuring gives rise to a star with a radius of ～100 km.     

北票台吉地震与辽西地震相关分析

辽西地区被国家地震局列为“重点监测区”,该区区域构造复杂,近年来小震活动频繁,北票台吉地区处在辽西的中心部位,通过几年的观测研究,该区的小震活动与辽西地震活动有着很好的相关性。本文对北票台吉地震进行了各种分析研究,认为北票台吉地震与辽西地震有着很好的相关性,存在“窗口效应