2014年2月12日于田MS7.3地震前形变异常

The Yutian earthquake with Ms7. 3 happened on February 12, 2014. The precursor monitoring ability is weak in that area. We found tendency anomalies and middle- and short-term anomalies from metal pendulum tilt measurements in Hotan seismic station before the earthquake. And we also compared the anomalies with that of the Ms7. 3 Yutian earthquake on March 21, 2008. The tendency anomalies measured by the metal pendulum tiltmeter appeared since 2012 as tilting eastward. While the middle- and short-term anomalies were characterized by acceleration, pause and rapid change of tilt rate in two directions. The tendency anomalies of metal pendulum tilt records are the same before the two earthquakes. They both happened in the east direction. However, there are differences in duration, characteristic and earthquake intervals for the middle- and short-term anomalies.     

青海达日断裂中段构造活动与地貌发育的响应关系探讨

青海达日地区发育了多条晚第四纪活动断裂带,以NW—NNW向和近SN向为主。通过航卫片解译和野外实地调查发现,达日断裂中段晚第四纪新活动性尤为显著,其性质以左旋走滑为主,至今部分地段仍保存了清晰的1947年达日7级地震地表破裂带,其破裂样式具有分段性和多样性,反映了局部构造应力的差异。达日地区作为典型的活动构造区,是研究新构造运动与地貌响应的理想场所。因此,文中采用ASTER GDEM V2数据提取了该地区的水系网络和亚流域盆地参数,计算了亚流域盆地面积-高程积分曲线和积分值(HI值),讨论了其构造活动性及地貌响应的关系。区内黄河的6个亚流域盆地的面积-高程积分曲线形态分析结果表明,这6个亚流域盆地均处于地貌演化阶段的"壮年期",其演化过程表现出很好的同步性,反映了区域性构造隆升或沉降作用的总体结果。而且,区内亚流域盆地的面积-高程积分值(HI值)分布特征表明,HI低值分布与第四纪断陷盆地和河谷盆地范围相一致,反映了局部不同构造沉降和侵蚀作用的结果;HI高值则主要出现在达日地震地表破裂带由NWW向NW转向的部位,以及早侏罗世与晚三叠世花岗闪长岩体分布的地方,也很好地反映了局部构造作用的变化和地层岩性的差异。     

芦山地震、汶川地震与龙门山地区水汽异常

对龙门山地区水汽动态的分析研究表明,在2013年芦山MS7.0地震和2008年汶川MS8.0地震前,龙门山地区大气相对湿度异常频次都出现了先逐年下降,然后快速回升的过程;下降时间较长,10a以上,上升时间较短,1~2a;震中位于异常频次相对下降和上升幅度都是最大的中心或邻近区域。在地震孕育中期阶段发生水汽异常趋势变化的原因可能是由于岩层裂隙的张合、地下流体的运动和地热能的变化,影响地面温度和潜热交换的速度所致。在地震孕育的中长期阶段(10a~几a),地壳岩石受压缩变形,孔隙、裂隙不断闭合或减少,由地下释放的热水、热汽减少,潜热交换速度也随之降低,相对湿度异常频次表现为逐年下降的趋势。在地震孕育的中短期阶段,地壳岩石变形进一步加大,可能导致微破裂不断扩展,由地下释放的热水、热汽由减少转为增加,潜热交换速度由降低转为迅速增加,相对湿度异常频度也表现出由逐年下降转为突发的快速上升。     

新疆地区M≥7强震有序网络结构及其预测研究

自1800年以来,新疆及其邻区M≥7强震具有显著的可公度性和有序性,其主要有序值为30a×k(k=1,2,3)、11～12a、41～43a与18～19a等.根据翁文波信息预测理论和复杂网络技术,努力探索具有中国特色自主创新的强震预测方法,构建新疆地区M≥7强震信息有序网络结构,充分揭示了新疆地区近200a来M≥7强震链的活动规律,并据此较为成功地预测了2008年于田7.3级强震的发生.同时还提出新的预测意见:2014-2015年、2019-2020年以及2026年前后新疆地区仍有可能发生M≥7强震.研究结果表明强震是可以预测的.该方法对于强震的中长期跨越式预测具有独特效果.     

鄂尔多斯盆地南部长7暗色泥岩与黑色页岩生烃动力学特征对比分析

以往对鄂尔多斯盆地南部地区长7油层组(简称长7)中烃源岩生烃潜力的研究主要是采用静态地球化学指标进行的,目前尚无对生烃动态特征的系统评价,因而制约了对长7烃源岩生烃潜力和页岩油资源分布有利岩性的客观认识。为此,选取长7不同类型的烃源岩样品,通过开放和封闭热模拟实验,对比分析了不同类型烃源岩的动力学参数、生烃产物、产率特征及生烃演化规律。结果表明:(1)黑色页岩活化能分布范围比暗色泥岩更为集中,且主频活化能和频率因子均低于暗色泥岩,体现了快速生烃的特性;(2)在外推到地质条件下,黑色页岩主要生烃期对应的R_o值(0.70%~0.87%)低于暗色泥岩(1.06%~1.72%),且以生油为主;(3)R_o在0.9%~1.3%范围内,黑色页岩的总烃产率高于暗色泥岩,生油量高于暗色泥岩。结合研究区两类烃源岩的地球化学资料综合分析表明,黑色页岩是研究区页岩油资源形成与分布的有利烃源岩。     

Solutions of the linearized geodetic boundary value problem for an ellipsoidal boundary to order e 3

The geodetic boundary value problem (GBVP) was originally formulated for the topographic surface of the Earth. It degenerates to an ellipsoidal problem, for example when topographic and downward continuation reductions have been applied. Although these ellipsoidal GBVPs possess a simpler structure than the original ones, they cannot be solved analytically, since the boundary condition still contains disturbing terms due to anisotropy, ellipticity and centrifugal components in the reference potential. Solutions of the so-called scalar-free version of the GBVP, upon which most recent practical calculations of geoidal and quasigeoidal heights are based, are considered. Starting at the linearized boundary condition and presupposing a normal field of Somigliana–Pizzetti type, the boundary condition described in spherical coordinates is expanded into a series with respect to the flattening f of the Earth. This series is truncated after the linear terms in f, and first-order solutions of the corresponding GBVP are developed in closed form on the basis of spherical integral formulae, modified by suitable reduction terms. Three alternative representations of the solution are discussed, implying corrections by adding a first-order non-spherical term to the solution, by reducing the boundary data, or by modifying the integration kernel. A numerically efficient procedure for the evaluation of ellipsoidal effects, in the case of the linearized scalar-free version of the GBVP, involving first-order ellipsoidal terms in the boundary condition, is derived, utilizing geopotential models such as EGM96.     

On Helmert’s methods of condensation

Helmerts first and second method of condensation are reviewed and generalized in two respects: First, the point at which the effects of topographical and condensation masses are calculated may be situated on or outside the topographical surface; second, the depth of the condensation layer below the geoid is arbitrary. While the first extension permits the application of the generalized model to the evaluation of airborne and satellite data, the second one gives an additional degree of freedom which can be used to provide a smooth gravity field after reducing the observation data. The respective formulae are derived for the generalized condensation model in both planar and spherical approximation. A comparison of the planar and the spherical model shows some structural differences, which are primarily visible in the out-of-integral terms. Considering the respective formulae for the combined topographic–condensation reduction on the background of the density structure of the Earths lithosphere, the consequences for the residual gravity field are investigated; it is shown that the residual field after applying Helmerts second model of reduction is very rough, making this procedure unfavourable for downward continuation. Further considerations refer to the question of which sets of formulae should be used in geoid and quasigeoid determination. It is concluded that for high-precision applications the generalized spherical model, involving a depth of the condensation layer of between 20 and 30 km, should be superior to Helmerts second model of condensation, although it requires the direct calculation of the indirect effect, which is larger than in the case of Helmerts second method of condensation.     

Gas and Particle Products Distribution from the Reaction of β-Caryophyllene with Ozone

Gas and particulate reaction products from the ozonolysis of -caryophyllene (I) in the presence of atmospheric air were investigated using a combination of gas chromatography-mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC). A Scanning Mobility Particle Sizer system (3936, TSI) and a Condensation Particle Counter (3025A, TSI) were used to study secondary organic aerosol formation. The nighttime oxidation was carried out in a large outdoor smog chamber (190 m³). A wide range of ring retaining and ring opening products in the gas and particle phase are reported over the course of the reaction. On average, measured gas and particle phase products accounted for 64% of the reacted -caryophyllene (I) carbon. Measurements show that a number of reaction products with low vapor pressure (e.g., -caryophyllone aldehyde (IV), -norcaryophyllone aldehyde (V), -caryophyllonic acid (VIII), -14-hydroxycaryophyllonic acid (XIV)) were found in the sample taken during the first 20 min of the reaction and may play an important role in the early formation of secondary organic aerosol. A detailed mechanism is proposed to account for most products observed in this investigation.     

三溴偶氮胂—锇—溴酸钾催化光度法测定微量锇

在酸性介质中Ｏｓ（Ⅳ）对ＫＢｒＯ３氧化三溴偶氮胂的褪色反应有明显的催化作用，借此反应可在水相中直接测定微量锇。方法灵敏度高，锇的质量浓度为１０～２００μｇ／Ｌ时符合比尔定律，表观摩尔吸光系数为９１８×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。方法已用于贵金属精矿中锇的测定     

萃取色谱分离—原子发射光谱测定超高纯氧化铽和氧化镝中痕量稀土杂质

研究了２＿乙基己基膦酸单２＿乙基己酯萃取色谱分离＿原子发射光谱测定超高纯Ｔｂ４Ｏ７和Ｄｙ２Ｏ３中痕量稀土杂质，方法可用于纯度（质量分数ｗ）为９９９９９９％～９９９９９９９％Ｔｂ４Ｏ７和Ｄｙ２Ｏ３的分析。在铽和镝的样品中其它稀土杂质的回收率分别为７３％～１３３％和９５％～１２０％，６次测定平均值的相对标准偏差分别为５８％～２２％和７９％～２０％，分离周期为９ｈ和１２ｈ。