Vibrational spectroscopy of beta-eucryptite (LiAlSiO<Subscript>4</Subscript>): optical phonons and phase transition(s)

The structural behavior of -eucryptite (LiAlSiO₄) has been investigated using infrared (IR) spectroscopy over a temperature range of 20 to 900 K and FT-Raman spectroscopy at room temperature. IR reflectance measurements show that -eucryptite possesses high reflectivity in the far-IR region, as is consistent with its reported superionic conductivity along the c-axis. On heating, the Li-related IR bands near 246 and 300 cm^–1 (with A₂ symmetry) broadened and weakened dramatically, presumably as a result of Li⁺ positional disordering along the structural channels parallel to c. The disordering process appears to induce a framework distortion, as is evidenced by the broadening of some vibrations of Si(Al)–O with increasing temperature. A change in slope in the temperature dependence of the phonon frequency near 300 cm^–1 and the linewidth of the 760 cm^–1 band at 715 K indicates that Li becomes completely disordered above this temperature. In addition, the temperature dependence of the linewidth for the 760 cm^–1 band exhibits an additional change in slope at 780 K, implying the existence of an intermediate state within this temperature range. The detailed structure of this intermediate phase, however, needs further study. Our IR data provide no indication of structural changes between room temperature and 20 K.     

基于ETM影像数据融合的土地覆盖分类研究

在ERDAS软件支持下，对ETM遥感影像数据的TM1-TM5，TM7与其全色波段TM8进行融合，采用主成分、乘积法、Brovey转换三种融合方法，重采样方法分别为邻域法、立方卷积法及双线性内插法。采用相同的训练样本区及最大似然法分类方法，对融合产生的9幅影像及未融合影像进行土地覆盖分类，通过对分类影像的Producers Accuracy，Users Accuracy，Kappa三者的精度数据和地物波谱信息的对比分析，在总体上，上述的影像融合方法对提高土地覆盖分类的精度不明显，但就某些地物类型来说，还是值得采用的；三种融合方法和三种重采样方式它们之问相比较而言，乘积法融合法和立方卷积重采样法相对较为可取。     

Landsat 7图像快速几何校正方法研究

Landsat 7采用双向扫描的方式，由于扫描非线性及卫星姿态和轨道的波动，使得建立卫星视线的计算量增大。引入一种求视线的快速方法，将图像上的扭曲分解为标称扫描镜及卫星运动引起的和7个偏离标称运动的微扰量引起的两个部分，详细分析了各个微扰量造成的影响，建立了一个新的视线求解方程。最后用实际的数据验证了方法的速度和精度。     

High-altitude Plio–Quaternary fluvial deposits and their implication on the tilt of a horst, western Anatolia, Turkey

This study investigates the origin and regional tectonic implications of high-altitude Plio (?)–Quaternary fluvial deposits developed over the Bozdağ horst which is an important structural element within the horst–graben system of western Anatolia, Turkey.A total of 23 deposits occur near the modern drainage divide comprising fluvial to occasionally lacustrine deposits. The deposits are all elongated in N–S direction with a width / length ratio of 1 / 10. The largest of them is of 13 km in length with a maximum observable thickness of about 100–110 m. Morphological, lithological, deformational characteristics of these deposits and the drainage system of the area all suggest that the deposits were formed due to uplift and southward tilting of the Bozdağ horst. This tilting which is estimated as 1.2° to 2.2° caused accumulation of the stream load along channels flowing from south to north. All the deposits were later dissected by the same streams with the exception of one deposit which still preserves its original lake form. These deposits are of Quaternary age, which corresponds to the latest N–S directed extensional tectonic phase in the region.     

混合表面活性剂存在下锰的高灵敏显色反应研究

研究了碱性介质中,Ｍｎ（Ⅱ）被空气氧化生成Ｈ２ＭｎＯ３,然后在Ｈ３ＰＯ４介质中,Ｃｕ（Ⅱ）和阳离子型有机相／水相微乳液（ＣＴＭＡＢ／戊醇／正庚烷／水）的存在下,Ｍｎ（Ⅳ）与二安替比林对乙氧基苯基甲烷（ＤＡｐＥＭ）生成橙色产物,λｍａｘ为４５０ｎｍ,ε＝１．９５×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。Ｍｎ（Ⅱ）的质量浓度在０～３２０μｇ／Ｌ内符合比尔定律。方法用于合金中锰的测定,结果与标准值符合,５次测定结果的ＲＳＤ＜３％。     

丽江7.0级地震的余震震源参数研究

本从ＰＤＲ－２数字化近源（６．２ｋｍ≤△≤４２ｋｍ）台网记录的丽江余震中初选了７４个地震，初定了震中位置，震中方位角。用相应的台网数据处理技术，研究了丽江地震序列的体波谱。对震级２．５≤Ｍ≤５．７、地震矩２１．４０≤ｌｏｎｇＭ０≤２３．２８的地震，得出了丽江地区地震系列的震源参数；以及Ｐ波、Ｓ波的ｌｏｇＭ０与Ｍｄ的关系式分别为：ｌｏｇＭ０＾ｐ＝０．６２Ｍｄ＋１９．９３；ｌｏｇＭ０＾ｓ＝０．５９Ｍ     

丽江7.0级地震前地震波特征的时空演化过程

本论述了１９９６年２月３日丽江７．０级地震前洱源、腾冲两个地震台的多项地震波运动学和动力学异常及滇西北多台波速比异常的特征，探讨了其时空演化的动态变化过程。得出：在时间进程上，多项地震波突变特征均在震前一年左右的时间出现。其中，波速比在大震前的单点突变异常幅度为中强震的５倍之多；振幅比突变异常幅度约为中强震的３－５倍；尾波持续时间比则是在震前一年左右出现持续性的低值，时间尺度约为中强震异常时间的     

日本鹿屋台地磁转换函数的变化

1996年10月19日本九州宫崎发生7．1级大地震，震中离鹿屋地磁台约90km。分析了鹿屋台1989～2001年分钟值资料。周期等于60min和41min的地磁转换函数Au在1993年至1998年初呈现下降趋势。年变率达0．01α^-1。此变化有可能与宫崎地震相关。另外，从震前数年Parkinson矢量转向特征推测，震源区的电导率似乎是变小的。     

Certified Reference Materials of Copper, Lead and Zinc (Silver) Ore Rocks and Their Concentrates (GSO 1-7)

Sulfide mineral certified reference materials GSO 1-7, recently prepared by the Institute of Geophysical and Geochemical Exploration (IGGE), were analysed by twelve laboratories. Various reliable analytical methods based on different principles were adopted and classical chemical methods were taken as the primary analytical methods, by which 5729 determinations were carried out, 1425 average data were obtained, and twenty one to twenty seven elements and components were certified.     

The deformation evaluation of Kızlaç T3A Tunnel (Osmaniye, Turkey)

This study covers the graphical analysis of deformation values measured in the Kızlaç T3A tunnel (Osmaniye, Turkey), which was built as a part of the Tarsus–Adana–Gaziantep Motorway Project. Excavation was performed through a sequence which was composed of sandstone–shale alternation, sandstone and dolerite dyke. Horizontal, longitudinal and settlement deformation values were optically read and recorded daily on a computer. These data were evaluated according to New Austrian Tunneling Method. Total deformation measurement, risky area determination and forecast of transitions between weak and stiff rock, stiff and weak rock were assessed as a result of deformation evaluation for tunnel stability, safety and economy.

The largest resultant deformation value (13 mm) was measured in the sandstone–shale alternation between chainage 500 and 550 m, which was highly weathered by groundwater and affected by local tectonic disturbance. The smallest deformation value was observed in a stiff dolerite dyke between 370 and 430 m, where at times the deformation values decreased to zero. In the sandstone, small resultant deformation values (2–4 mm) were also recorded. The 500–550-m interval of tunnel alignment had the highest risk for tunnel instability in the studied section but the deformation values (maximum 13 mm) were within the tolerable deformation range (10 cm). Small negative longitudinal deformation values decreasing between chainage 320 and 370 m and small positive longitudinal deformation values decreasing between 420 and 480 m indicate the sandstone–shale alternation (weak rock) and the dyke (stiff rock) and sandstone (stiff rock), and the sandstone–shale alternation with a fault gauge zone (weak rock), respectively. These longitudinal deformations needed probable to predict the lithological transitions ahead of the face, which in timely were used to determination of the tunnel support system.