地质样品正构烷烃组分分离纯化的部分问题探究

用实验室自配的标准正构烷烃样品分别经硅胶或氧化铝柱层析后发现,等量溶剂洗脱的情况下硅胶对长链正构烷烃无吸附而氧化铝具有一定吸附性。进一步通过用植物样品测试4种层析柱填充方法,发现不论是只用氧化铝填充还是上部硅胶下部氧化铝和上部氧化铝下部硅胶,都会对长链正构烷烃产生一定的吸附,且这种吸附效果随着碳链的增长而增强。在实验条件下,当碳链加长到C36时,用硅胶加氧化铝填充层析柱的吸附量已达到20%左右,而只用氧化铝填充层析柱的吸附量则高达50%。故建议对研究高碳数正构烷烃的地质样品组分提取时用单一的硅胶柱层析方法。同时,实验显示对于一些杂质多的正构烷烃样品经过尿素络合后比络合前"干净"得多。18个黄土-古土壤和植物样品平均回收率为50%左右,经过尿素络合后的样品正构烷烃各组分相对含量基本不会发生改变,也不会产生明显的同位素分馏效应。因此在进行非正构组分干扰较大的正构烷烃各组分相对含量或同位素分析时,可以选择尿素络合的方法来将其纯化。     

Optimum design of stone column-improved soft soil using multiobjective optimization technique

A combined simulation–optimization-based methodology is proposed to identify the optimal design parameters for granular bed–stone column-improved soft soil. The methodology combines a finite difference-based simulation model and an evolutionary multiobjective optimization model. A combined simulation–optimization methodology is developed for two different formulations: (a) the minimization of maximum settlement and the minimization of differential settlement subject to stress constraints; (b) the minimization of maximum settlement, the minimization of differential settlement and the maximization of the degree of consolidation subject to stress constraints. The developed methodology is applied to an illustrative system. Different scenarios are evaluated to examine critical field conditions. The solution results show that the modular ratio and the ultimate stress carrying capacity of the stone column are the most important parameters for optimal design. The obtained results also show the potential applicability of the developed methodology.     

Frequency and variability of missing tree rings along the stems of Pinus halepensis and Pinus pinea from a semiarid site in SE Spain

We studied the occurrence of missing rings (MR) around and along the stems of three Pinus halepensis and three Pinus pinea trees growing in a semiarid Mediterranean site in SE Spain. Tree-ring analyses were performed along 8 radii on stem discs taken at 1 m distances from the base to the top of the trees. The tree rings analysed showed that 19% were missing in P. halepensis and 10% in P. pinea. MR were recorded in 61% of P. halepensis and 24% of P. pinea in the years analysed. Dry conditions from January to May and high late winter to spring temperatures seem to be the main climatic elements promoting MR in both species. In our research into P. halepensis, the frequency of MR gradually decreased from the bottom upward, but no such pattern was observed in P. pinea. Most tree rings were missing only locally (LMR), indicating that wood formation occurred every year in at least some part of a tree, and the tree rings were often discontinuous around and along the stem. Since the frequency of LMR greatly varies around and along the stem, our results suggest that serial sectioning along the stem provides more information on wood formation and responses of trees to environment than studying the samples at breast height only. The disadvantage of the technique is that, as in our study case, research is based on a limited sample size, since it requires destructive sampling with tree felling, which is not usually possible or desirable on highly vulnerable semiarid forest ecosystems.     

煤层工作面内陷落柱综合物探探查

煤层工作面内陷落柱与煤层之间具有显著的电阻率、波速和密度差异,适宜于采用无线电波透视法和震波透视CT法来探测煤层工作面内陷落柱的边界范围;陷落柱体通常裂隙发育,与围岩相比较,其富水陷落柱为相对低电阻率值范围,而不富水陷落柱则为相对高电阻率值范围,因此,可利用煤层底板三维电法来探查底板陷落柱富水性。谢桥矿13218工作面1^#陷落柱的探测表明,该陷落柱范围具有较高的电磁波吸收系数特征和相对较高的纵波波速特征;工作面底板陷落柱向下范围为相对高电阻率值特征,为不富水陷落柱。该综合物探探测结果与实际验证资料基本吻合,有效地指导了本煤层工作面开采及底板煤层工作面的开采设计与施工。     

重型动力触探在振冲施工质量控制及检测中的应用

振冲复合地基以其低成本、高效率等优势已经广泛的应用于水利水电、火电、工民建、石化、交通、市政、铁路等行业的地基处理中。振冲进行地基处理的规模和速度日新月异,使得施工过程中的质量控制变得非常重要。通过对重型动力触探在振冲碎石桩工程中的应用,论述了重型动力触探在振冲施工质量控制及检测中的重要性及适用性,并总结了其在工程中的应用经验。     

高低空位涡扰动、非绝热加热与气旋的发生发展

从湿位涡的扰动量出发，来分析气旋发展过程中高低空位涡的变化，结果表明：低层位涡扰动先于气旋并孤立于高层位涡扰动而存在，在气旋发生过程中，低层正值位涡扰动发展上伸，与高层下传的位涡相接，形成一条正值位涡扰动柱，而湿位涡扰动柱的形成正是气旋发生的重要标志。江南暴雨期的非绝热加热主要由降水产生的凝结潜热造成，最大加热层的出现，是低层位涡扰动产生和向上发展的一个重要原因，对气旋的发展起着促进作用。     

路南石林喀斯特的形态特征及地质演化

石林喀期特是喀斯特地貌中的一种极端形式，主要由表面溶良发育，高达３０￣５０ｍ的剑状石峰、石柱组成。同世界其他一些著名的剑状喀期特相比，路南石林喀斯特具有最为复杂的地质演化历史和最为多样的形态。研究表明：自２亿５千万年前早二叠世末期首次出现石牙以来，石林的发育经历了四大演化阶段；石林的形成是有利的地质、水文、气候条件综合作用的结果，而土下溶蚀是主要形成机理。剑状、峰状、塔状、蘑茹状及其他不规则状为石     

CSAMT法在四台矿402盘区陷落柱构造探测中的应用

可控源音频大地电磁法应用于寻找煤田落陷落柱构造，乃是个新课题。通过对大同矿务局四台矿４０２盘区的野外实际应用，发现了两个陷柱落构造，与实际资料基本吻合。     

矿井电法探测突水陷落柱在任楼煤矿的应用

井下工作面侧帮超前探测技术是矿井直流电阻率探测新技术之一。本文阐述了该技术基本探测原理及其在陷落柱突水前探测采煤工作面内部陷落柱的应用。结果表明,该技术能探测含水导水陷落柱位置及其富水性,从而预防陷落柱突水淹井事故的发生,为煤矿井下防治水起到了重要作用。      

Seasonal variation in water column conditions in the upper Gulf of Thailand

Seasonal variation in water column conditions in the upper Gulf of Thailand (UGoT) was analyzed by considering four major factors including surface heat flux, freshwater discharge, tidal and wind stirrings. The coincidence of surface heat loss, low river discharge and strong wind resulted in vertical well-mixing in December. Strong stratification developed in September and October due to large river discharge and moderate heat flux. Strong surface heating in April and May has a potential to generate strong stratification, although not as large as that in September and October due to low river discharge. Although no factors are prominent during January and March, and June and August, weak to moderate stratification results, because the influences of river discharge and surface heating are still larger than those of tidal and wind stirrings. The results of water column analysis based on monthly average data agree well with analyses derived from cruise data in the same months. Most analytical results correspond to the distributions of temperature and salinity from field observations. Disagreement, however, was found in December 2003 (cruise CU-2) when stratification in some small regions occurs in the distribution of water properties, but the water column analysis suggests vertical well-mixing. This phenomenon is triggered by non-uniform distribution of freshwater over UGoT, which is related to river discharge, monsoonal wind and current. Compared to a previous study regarding surface chlorophyll dynamics, water column conditions may be used to explain the occurrence of phytoplankton bloom in this region.