西湖茶园茶叶铅污染铅同位素示踪

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。     

粤西云浮镇安-阳春罗阳地区 地球化学特征与找矿方向

分析云浮镇安—阳春罗阳地区元素的分布、分配特征和区域地质背景后,指出该地区有找矿潜力,提出Au、Ag、Cu、Pb、Zn是重要的找矿元素,找构造蚀变岩型金矿、火山岩型金矿、岩浆热液型银—多金属矿前景好,主要的找矿标志是断裂和蚀变。     

黑龙江省中部森林沼泽区金在土壤A层中的富集规律

探讨了金在黑龙江省中部森林沼泽区A层土壤-10～+60目、-60～+100目、-100～+160目及-160目粒级中的含量分布特征和富集规律。经对比研究认为,-100目可以满足低密度深穿透地球化学详细测量采样要求,该粒级能够有效地发现异常。     

川西新场气田地气测量试验

通过对新场气田地气测量分析,发现地气测量的纳米微粒金属元素在新场气田上方有明显的异常显示。综合土壤地球化探结果对比分析,认为Ba、Cd、Cu、Mo、Zn、P、V、Ni等20多种纳米微粒金属元素在新场气田与相同的土壤微量元素都有着共同的响应。同时分析了有机地球化学指标在气田地表上方的表现模式,其特征和地气、土壤元素表现基本一致。地气测量方法在一定条件下对寻找天然气藏、确定气田范围具有一定的应用前景。     

Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong

Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model..     

Geochemistry and environmental effect of cadmium in the super-large Jinding Pb-Zn deposit,Yunnan Province,China

The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment.     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

胶东地区晚中生代岩浆活动及对大地构造的制约

应用近十几年来胶东地区及其周边岩浆岩体的同位素测年资料,结合几个岩体的新的SHRIMP测年数据(牙山岩体117.7Ma,院格庄岩体113.4Ma,正长斑岩脉115.7Ma),系统研究了该区晚中生代以来的岩浆活动规律,结果表明,该区可分为4个岩浆活动期;(1)晚侏罗世构造-岩浆热事件(150~160Ma),以玲珑-滦家河型岩体为代表,是在区域挤压构造应力作用下侵入的,属同构造或同造山时期的岩浆作用。(2)早白垩世早期构造-岩浆热事件(135~125Ma),以郭家岭岩体为典型,该时期的岩浆活动均具有双峰式岩浆作用特征,反映了伸展动力学背景。(3)早白垩世中晚期构造-岩浆热事件(125~105Ma),以崂山花岗岩为特征,该阶段对应于中国东部岩石圈大规模的减薄时期,是大陆裂谷作用的高峰期。(4)晚白垩世-古新世基性-超基性火山作用。本文还探讨了岩浆活动的地球动力学因素及其对大地构造的制约。     

福建建阳大金山铅锌矿床地球物理化学异常特征

大金山铅锌矿位于泰宁一政和北东东向铜多金属成矿带上,是该成矿带主要的矿种之一,也是闽北地区一个较有价值的矿床。矿床产于早元古代南山组上段,受燕山期北东东向构造控制,属中低温热液充填交代型矿床。     

河南桐柏围山城层控金银成矿带同位素地球化学

河南省桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,赋矿地层是新元古界歪头山组,矿体产状与地层产状一致,形态呈似层状、鞍状或透镜状,层控特征显著。氢-氧-碳同位素地球化学研究指示早、中阶段的成矿流体主要为变质水,晚阶段有大量大气降水加入成矿流体系统。碳-硫-铅同位素指示成矿物质来自于歪头山组地层;钾-氩同位素表明成矿作用(100~140Ma)发生在秦岭陆陆碰撞造山的高峰期之后碰撞挤压向伸展转变的背景下。综合考虑矿带的成矿流体来源、成矿物质来源以及矿床地质特征,认为围山城成矿带属典型的层控造山型金银成矿系统,形成于中生代扬子与华北板块的陆陆碰撞造山体制。