IAEA-S-1 参考物质及V-CDTS 同位素标准的32S/34S绝对比值

采用高纯S同位素物质和SF6的分析方法对IAEA-S-1参考物质及V-CDT S同位素标准的32S/34S绝对比值进行了实验标定，V-CDT的32S/34S比值为22.6496±0.060，IAEA-S-1的32S/34S比值为22.6564±0.0060.     

The origin and distribution of HAPs elements in relation to maceral composition of the A1 lignite bed (Paleocene, Calvert Bluff Formation, Wilcox Group), Calvert mine area, east-central Texas

The origin and distribution of twelve potentially Hazardous Air Pollutants (HAPs; As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, and U) identified in the 1990 Clean Air Act Amendments were examined in relation to the maceral composition of the A1 bed (Paleocene, Calvert Bluff Formation, Wilcox Group) of the Calvert mine in east-central Texas. The 3.2 m-thick A1 bed was divided into nine incremental channel samples (7 lignite samples and 2 shaley coal samples) on the basis of megascopic characteristics. Results indicate that As, Cd, Cr, Ni, Pb, Sb, and U are strongly correlated with ash yield and are enriched in the shaley coal samples. We infer that these elements are associated with inorganic constituents in the coal bed and may be derived from a penecontemporaneous stream channel located several kilometers southeast of the mining block. Of the HAPs elements studied, Mn and Hg are the most poorly correlated to ash yield. We infer an organic association for Mn; Hg may be associated with pyrite. The rest of the trace elements (Be, Co, and Se) are weakly correlated with ash yield. Further analytical work is necessary to determine the mode of occurrence for these elements. Overall, concentrations of the HAPs elements are generally similar to or less than those reported in previous studies of lignites of the Wilcox Group, east-central region, Texas. Petrographic analysis indicates the following ranges in composition for the seven lignite samples: liptinites (5–8%), huminites (88–95%), and inertinites (trace amounts to 7%). Samples from the middle portion of the A1 bed contain abundant crypto-eugelinite compared to the rest of the samples; this relationship suggests that the degradation of plant material was an important process during the development of the peat mire. With the exception of Hg and Mn, relatively low levels of the HAPs elements studied are found in the samples containing abundant crypto-eugelinite. We infer that the peat-forming environment for this portion of the coal bed was very wet with minimal detrital input. Relatively high concentrations of crypto-humotelinite were found in samples from the top and base of the coal bed. The presence of abundant crypto-humotefinite in this part of the coal bed suggests the accumulation of wood-rich peat under conditions conducive to a high degree of tissue preservation in the peat mire. Although several of the trace elements (Be, Co, Ni, and Sb) exhibit enrichment in these samples, they are not necessarily chemically associated with humotelinite. We infer that these elements, with the exception of Be, are possibly associated with deposition of the roof and floor rock of the coal bed; however, further analytical work would be necessary to confirm this hypothesis. Beryllium may have an organic origin.     

中子活化分析在铼—锇法年龄测定中的应用

同位素稀释中子活化分析铼与感耦等离子体质谱法测定锇相结合，应用于辉钼矿及铜＿镍硫化物矿物的铼＿锇年龄测定，取得了满意的结果，扩大了铼＿锇测年法的应用范围。     

The Origin of the Early Proterozoic Kuandian Complex: Evidence from Geochemistry

The Kuandian Complex is scarcely preserved Early Proterozoic volcanic suite, formed2.3-2.4 Ga ago. It is located in an Early Proterozoic mobile belt bounded by the ArchaeanRangrim and Ryonggang Blocks of the northeastern Sino-Korean Craton. The Complex ismainly made up of amphibolites, gneisses, leucoleptite, leptite and layered granite. Petrologicaland geochemical studies show that the protoliths of the Complex are mainly assoctations ofbimodal volcanics and anorogenic granites. The Kuandian amphibolites are depleted in Nb, Ta,P and Ti, and enriched in LILE, e.g. K, Rb and Cs, with pronounced depletion of Sr relative toNd and Pb; La/Nb ratios are higher than 1(1.75 to 5.18). The trace element patterns of theamphibolites are similar to continental flood basalts formed by the Gondwana break-up, suchas those in South Karoo and Tasmania, which shows continental contamination. ε_(Nd) valuesranging from 0.70 to 1.94 of the Kuandian amphibolites and the relationships between Nb/Yband La/Yb suggest that contamination of basaltic magma happened in the mantle, rather thanalong the conduit. Isotope ratios of ~(208)Pb/~(204)Pb, ~(207)Pb/ ~(204)Pb, ~(206)Pb/~(204)Pb, ~(143)Nd/~(144)Ndand ~(87)Sr/~(86)Sr indicate that the magma was derived from a contaminated mantle source likeDMM or a mixture of DMM and EM2. The Kuandian Complex has Dupal anomaly, as is thecase with some continental basalts in the south hemisphere, e.g. in South Karoo and Tasmania.Petrochemical modelling proposes that the Kuandian gneiss, granite, and amphibolite camefrom the same parental magma, being products of strong fractional crystallization. Protoliths ofthe Kuandian Complex were formed in extensional tectonic setting during the transition fromcontinental crust to oceanic crust. The formation of the Kuandian Complex indicates that 2.3or 2.4 Ga ago tectonic evolution of the Sino-Korean craton was different from that of otherwell-studied Precambrian cratons, e.g. the North American shield, European platform andAustralian continent in that strong volcanic eruption resulted in its accretion. Besides, the con-taminated magma source with a Dupal anomaly for the Complex indicates that crust-mantleconvection whose scale was similar to that of the present plate tectonics had occurred at leastbefore the formation of the Kuandian Complex (2.3-2.4 Ga B.P).     

云南老王寨金矿煌斑岩地球化学研究中的某些问题──与宋新宇等同志商榷

本文对“云南老王寨金矿煌斑岩地球化学研究”一文中的部分结论及其解释，提出一些不同意见与原文作者宋新宇等先生商榷     

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