赣北大湖塘地区昆山W-Mo-Cu矿床侵入岩锆石U-Pb、辉钼矿Re-Os年代学及地质意义

昆山W-Mo-Cu矿床地处赣北九岭矿集区南部,距大湖塘超大型钨矿床狮尾洞矿区仅3 km。矿床目前处于详查阶段,已探明钨达中型规模,同时伴生中型钼矿及小型铜矿,具有良好的找矿潜力。昆山矿床矿化样式较为单一,W-Mo-Cu矿体以石英脉形式产出,主要赋存在燕山期侵入岩顶部与新元古界双桥山群浅变质岩的外接触带,具有"上钨中钼下铜"的特点,明显区别于大湖塘矿床矿体主要产在燕山期侵入岩与晋宁期黑云母花岗闪长岩的内外接触带,具细脉浸染型白钨矿、热液爆破角砾岩型钨铜矿及石英脉型黑钨矿"三位一体"的矿化特征。本文在详细的野外地质调查基础上,对昆山W-Mo-Cu矿床的成岩成矿时代进行了详细研究,并探讨了其地质意义。利用LA-ICP-MS锆石U-Pb法获得矿区内呈岩株状产出的似斑状花岗岩的年龄为151.7±1.3 Ma,晚期花岗斑岩脉的年龄为136.6±2.5 Ma;利用辉钼矿Re-Os法,获得辉钼矿Re-Os等时线年龄和加权平均年龄分别为151.0±1.3 Ma和150.0±1.0 Ma,厘定矿床成矿时代为晚侏罗世,且与似斑状花岗岩有关。结合前人所得高精度成岩成矿年龄数据,认为赣北地区燕山期成岩成矿具多期性,可分为160~150 Ma(塔前、朱溪钨多金属矿床)、140 Ma(大湖塘钨多金属矿床)和125 Ma(香炉山钨矿),主要集中于150~140 Ma。晚侏罗世,华南地区全面进入岩石圈"伸展-减薄"的地球动力学背景,赣北地区燕山期成岩成矿可能与这一构造背景有关。昆山矿床具"上钨中钼下铜"的分带模式,其成因值得进一步研究。     

High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.     

河南卢氏八宝山花岗斑岩LA-ICP-MS锆石U-Pb年龄和Hf同位素组成特征

河南省卢氏县八宝山岩体位于华北克拉通南缘东秦岭西段,岩体呈筒状,可能为古火山机构岩颈相的超浅成侵入体,成矿组合上为独特的以铁为主的多金属矿化。八宝山岩体边缘相为钾长花岗斑岩、中心相为黑云母二长花岗斑岩。二者的LA-ICP-MS锆石U-Pb年龄非常一致,分别为146.6±1.6Ma和145.9±1.9Ma,说明他们可能是同期岩浆侵入作用分异的产物。钾长花岗斑岩和黑云母二长花岗斑岩锆石Hf同位素组成特征也非常相似,εHf(t)值分别为-27.55～-20.71和-27.30～-21.90,tDM2值分别为1.80～2.93Ga和2.03～2.92Ga,表明该岩体的源区物质以壳源物质为主。综合分析表明,八宝山岩体可能是扬子俯冲陆壳部分熔融的作物,并可能混入少量的太华群和熊耳群的物质,其形成的地球动力学背景可能为俯冲碰撞后的伸展环境。     

Geological and C–O–S–Pb–Sr isotopic constraints on the origin of the Qingshan carbonate-hosted Pb–Zn deposit,Southwest China

Located in the western Yangtze Block, the Qingshan Pb–Zn deposit, part of the Sichuan–Yunnan–Guizhou Pb–Zn metallogenic province, contains 0.3 million tonnes of 9.86 wt.% Pb and 22.27 wt.% Zn. Ore bodies are hosted in Carboniferous and Permian carbonate rocks, structurally controlled by the Weining–Shuicheng anticline and its intraformational faults. Ores composed of sphalerite, galena, pyrite, dolomite, and calcite occur as massive, brecciated, veinlets, and disseminations in dolomitic limestones.

The C–O isotope compositions of hydrothermal calcite and S–Pb–Sr isotope compositions of Qingshan sulphide minerals were analysed in order to trace the sources of reduced sulphur and metals for the Pb–Zn deposit. δ¹³C_PDB and δ¹⁸O_SMOW values of calcite range from –5.0‰ to –3.4‰ and +18.9‰ to +19.6‰, respectively, and fall in the field between mantle and marine carbonate rocks. They display a negative correlation, suggesting that CO₂ in the hydrothermal fluid had a mixed origin of mantle, marine carbonate rocks, and sedimentary organic matter. δ³⁴S values of sulphide minerals range from +10.7‰ to +19.6‰, similar to Devonian-to-Permian seawater sulphate (+20‰ to +35‰) and evaporite rocks (+23‰ to +28‰) in Carboniferous-to-Permian strata, suggesting that the reduced sulphur in hydrothermal fluids was derived from host-strata evaporites. Ores and sulphide minerals have homogeneous and low radiogenic Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.561 to 18.768, ²⁰⁷Pb/²⁰⁴Pb = 15.701 to 15.920, and ²⁰⁸Pb/²⁰⁴Pb = 38.831 to 39.641) that plot in the upper crust Pb evolution curve, and are similar to those of Devonian-to-Permian carbonate rocks. Pb isotope compositions suggest derivation of Pb metal from the host rocks. ⁸⁷Sr/⁸⁶Sr ratios of sphalerite range from 0.7107 to 0.7136 and (⁸⁷Sr/⁸⁶Sr)_200Ma ratios range from 0.7099 to 0.7126, higher than Sinian-to-Permian sedimentary rocks and Permian Emeishan flood basalts, but lower than Proterozoic basement rocks. This indicates that the ore strontium has a mixture source of the older basement rocks and the younger cover sequence. C–O–S–Pb–Sr isotope compositions of the Qingshan Pb–Zn deposit indicate a mixed origin of the ore-forming fluids and metals.     

长城系团山子组火山岩颗粒锆石U－Pb年龄及其地质意义

蓟县中－上元古界典型剖面之邻区平谷县境内，长城系团山子组连续发育两层厚度各为１ｍ左右的富钾粗面安山岩，发育气孔构造和绳状构造。其中存在三种不同成因类型锆石，应用颗粒锆石Ｕ－Ｐｂ测定年龄技术，得到：（１）自生锆石，其Ｕ－Ｐｂ不一致上交点年龄为１６８３±６７Ｍａ，代表该火山岩形成年龄；（２）捕获锆石，多为原碎屑锆石，较年轻的一种捕获锆石的２０７Ｐｂ／２０６Ｐｂ表面年龄为１８２３±６８Ｍａ，这限定了长城系底界年龄应新于１８２３Ｍａ；（３）后生热液锆石，其Ｕ－Ｐｂ年龄为４６０Ｍａ左右，反映后期热液事件发生的时代。     

新疆东准噶尔拉伊克勒克斑岩铜(钼)矿床成岩成矿年龄、地球化学特征及其意义

拉伊克勒克矿床是在第四系覆盖区新发现的隐伏斑岩铜(钼)矿床。采用LA-ICP-MS技术,对赋矿岩体英云闪长岩中的锆石和矿石中的辉钼矿分别进行锆石U-Pb同位素、Re-Os同位素和锆石Hf同位素测定及相应的研究。测得锆石U-Pb年龄为421.8±2.5Ma,辉钼矿Re-Os模式年龄为409.1±2.6Ma,表明拉伊克勒克斑岩铜(钼)矿床形成于晚志留世—早泥盆世,与琼河坝地区主要斑岩矿床大规模成矿时间一致。英云闪长岩属过铝质-钙碱性系列花岗岩类,岩体具有较高的铝钙含量,K_2O/Na_2O值普遍偏低,介于0.16~0.29之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显。在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集。同时岩体具有高的正ε_(Hf)(t)值(10.98~15.01)和年轻的模式年龄(451~708Ma),暗示英云闪长岩体是大陆边缘弧环境下大洋板片熔融的产物,对进一步明确琼河坝地区斑岩型矿床的成矿环境和找矿方向具有重要意义。     

新疆西准噶尔巴尔鲁克蛇绿岩形成时代及大地构造意义

新疆西准噶尔地区分布多条蛇绿岩带,通过对巴尔鲁克蛇绿岩中2个辉长岩LA-ICP-MS锆石U-Pb测年,获得比较准确的年龄数据512.3±7.2Ma、521.1±2.8Ma。确定了该蛇绿岩的形成时代为晚寒武世;结合混杂岩带内岩石组合特征及其与中—下泥盆统库鲁木迪组为不整合接触,推断该蛇绿混杂岩带与唐巴勒蛇绿岩带及玛依勒蛇绿岩为同一时代、同一构造带产物,就位时代不晚于早泥盆世。     

新疆卡拉麦里地区早泥盆世洋内弧：来自火山岩地球化学及锆石U-Pb 年龄的证据

新疆东准噶尔卡拉麦里地区早泥盆世火山岩由玄武岩和玄武安山岩组成,采用LA-ICP-MS锆石U-Pb定年方法,获得玄武安山岩锆石的U-Pb年龄为404.5±1.9 Ma,表明喷发时代为早泥盆世。岩石地球化学显示早泥盆世火山岩属岛弧拉斑系列,具相对较高的Mg^# 值(41.25～55.32)及较低的Nb(1.11×10^{- 6}～2.42×10^{- 6})、Zr(73.9×10^{- 6}～95×10^{- 6})和ΣREE(81.50×10^{- 6}～121.80×10^-6)含量。富集大离子亲石元素(LILE：K、Rb、Ba)和轻稀土元素(LREE),而亏损Ta、Nb和Ti高场强元素（HFSE：Ta、Nb、Ti）,并显示Eu弱的亏损,这些特征与岛弧火山岩类似,其原始岩浆可能起源于俯冲流体交代的亏损地幔楔的部分熔融。结合区域地质背景,认为早泥盆世火山形成于洋内弧的构造环境,为卡拉麦里古洋盆向北俯冲消减的产物。这是在卡拉麦里地区首次报道的洋内弧火山岩,这一新的发现和认识对研究东准噶尔古生代洋盆演化及区域构造格局均具有重要的意义。     

海南岛钼矿床Re-Os年龄及其成矿地球动力学背景探讨

海南岛已发现的钼矿床(点)在空间上或成因上多与北西向或近南北向构造以及燕山晚期侵入的花岗质岩石密切相关。利用辉钼矿Re-Os同位素方法,对海南岛罗葵洞、文且、石门山三个典型的斑岩型钼矿床进行了精确定年,分别获得了99.7±0.4 Ma、104±1.0 Ma、88.6±1.0-80.2±0.6 Ma的成矿年龄,显示海南岛钼矿具有多阶段或多次成矿作用的特点(一次发生于约100Ma,另一次发生于80~88Ma间),形成于大陆边缘岩石圈拉张减薄、软流圈地幔上涌的伸展构造体制。     

西藏达金砾岩的沉积时代、物源及构造背景

达金砾岩出露于西藏阿里地区冈仁波齐峰南麓,因其地层中发现深海有孔虫化石而受到广泛关注,然而由于达金砾岩的沉积时代不确定,对其沉积的大地构造背景也没有统一的认识。本文中,根据最年轻的碎屑锆石U-Pb年龄限定达金砾岩的最大沉积时代为渐新世末-中新世初(24~27Ma)。综合野外观察,砂岩碎屑统计和碎屑锆石U-Pb年龄分析,本文认为达金砾岩的底部和顶部地层中碎屑物质直接来源于北侧的冈底斯弧,而其中部地层中碎屑物质(包括有孔虫化石)应再旋回自西侧的弧前盆地错江顶群地层。达金砾岩与上覆的冈底斯砾岩连续沉积,且其沉积时代,源区分析结果都与冈底斯砾岩一致,因此本文认为达金砾岩应隶属于冈底斯砾岩。达金砾岩地层变形较弱,产状近乎水平,应沉积于拉张应力背景下,可能与渐新世末-中新世初俯冲的印度板片的"折返"和"断离"有关。