西藏波龙斑岩铜金矿床的Re-Os同位素年龄及其地质意义

波龙斑岩铜金矿紧邻多不杂矿床,是多龙矿集区内新发现的一个超大型矿床。波龙矿床早期有两次成矿花岗闪长斑岩侵位,随后较晚期花岗斑岩侵位;地表广泛分布绢英岩化蚀变,深部发育钾化。本文对采于波龙斑岩型铜金矿床内石英-辉钼矿脉中的4件辉钼矿样品进行了Re-Os同位素测试,获得等时线年龄为119.4±1.3Ma (MSWD=0.63, n=4)。此年龄代表了波龙矿床的成矿年龄,与多不杂斑岩型铜金矿床的成矿年龄一致。波龙和多不杂斑岩型铜金矿床紧邻,并具有一致的成矿年龄,可能表明两个矿床的成矿受控于相同的构造-岩浆-成矿事件;斑岩铜矿具有成群分布的特征,波龙和多不杂斑岩铜金矿床的发现也暗示多龙矿集区具有找到其他大型斑岩铜金矿的潜力。     

陕西省凤太矿集区二里河铅锌矿床的成矿时代: 来自闪锌矿Rb-Sr同位素年龄的证据

八方山-二里河铅锌矿床位于陕西凤县-太白(简称凤太)矿集区西北部,矿体主要产于中泥盆统古道岭组与上泥盆统星红铺组接触带中,受NWW向八方山-二里河背斜控制。本次工作对二里河铅锌矿床主成矿阶段的闪锌矿进行了Rb-Sr同位素测年研究,获得了等时线年龄为220.7±7.3Ma,表明矿床形成于晚三叠世,该年龄对于整个凤太矿集区的铅锌成矿时代具有同样约束意义。闪锌矿的⁸⁷Sr/⁸⁶Sr_i值为0.714145±0.000031,指示成矿物质可能主要来源于大陆壳。结合前人的研究成果分析认为,二里河铅锌矿床是凤太矿集区在印支期区域性强烈的构造-岩浆-成矿作用过程中的产物。     

辽西四合屯地区义县期火山作用对沉积环境的影响

辽西四合屯地区中生代火山活动发育,广泛分布着火山作用形成的爆发相、溢流相火山岩。在显生宙地球历史中,如此巨大且迅速的火山作用普遍被认为是巨大种群灭绝的原因。与火山作用相联系的沉积相是火山作用间歇期形成的冲积扇-河流相、滨湖相、半深湖-深湖相,这些沉积相提供了研究火山作用对沉积环境影响的依据。义县期火山作用对沉积环境影响包括:义县期各沉积环境火山作用产物及火山岩风化产物的充填;各沉积相被当地多期(次)火山岩控制并埋藏于其下的火山-沉积相组合由下至上“螺旋式”规律性变化;义县期火山作用引起地表抬升与构造地形的变化,从而影响排流模式的变化;经历火山作用影响的生物群提供了义县期气候变化证据。     

生烃动力学、同位素动力学方法在烃源岩研究中的应用

生烃动力学、同位素动力学常用于烃源岩评价、油气源对比研究中。生烃动力学参数结合盆地热史,可恢复烃源岩在任一时代的生烃史,对构造复杂盆地的二次生烃研究具有独特的优势。利用生烃动力学方法可以实现有机质总量的恢复,在此基础上对高—过成熟样品原始有机质丰度是否有必要恢复进行了讨论;而基于生烃动力学的油气源对比综合考虑热史、成藏期次、成藏过程等各种地质参数对烃源岩生烃的影响,是一种动态的研究方法。     

康古尔金矿区次火山岩同位素年龄学及其意义

康古尔金矿区分布着一系列的次火山岩 ,这些次火山岩与金矿体相伴产出。从次火山岩的Rb- Sr等时线年龄及单颗粒锆石表面蒸发法 2 0 7Pb/2 0 6Pb年龄资料看 ,次火山岩形成于 30 0～ 2 82 Ma。而石英正长斑岩单颗粒锆石 2 0 7Pb/2 0 6Pb年龄值 ( 593Ma)反映了岩体侵位过程中捕获了基底岩石中古锆石的年龄信息。进一步推测在阿齐山—雅满苏火山岛弧之下可能存在前寒武纪陆壳基底     

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.     

内蒙古黄旗海不同粒级湖泊沉积物Rb、Sr组成与环境变化

Based on the geochemical elements Rb and Sr in sediments with three different grain size fractions from profile H3 on the northern lacustrine bottomland 13 m above the Huangqihai Lake surface in 1986,the paper investigates the record of palaeolake stand state, sedimentary environmental evolution,and winter monsoon change.First,these samples are separated into three different grain size fractions,i.e.,total sediments,77-20μm and〈20μm. Second,the chemical elements-Rb and Sr-of the grain size separation were tested and analyzed systematically in this paper.Then the elements compositions of these samples are measured using VP-320 mode fluorescence spectrum instrument,respectively.The magnetic susceptibility of these samples is measured using Kappabridge KLY-3 mode instrument made in Czech AGICO Company.The results showed the elements and the ratios varied regularly with the grain size.But the ratio of Rb/Sr in the sediments〈20μm correlates positively with the magnetic susceptibility of these samples.Therefore,the ratio of Rb/Sr in the fraction〈20 μm from the lake sediments reflected the strengthening of the weathering in the deposition sites.It is a good indicator of the summer monsoon-induced weathering and pedogenesis fluctuations and can be used to reconstruct the conditions of the paleoclimate and paleoenvironment.     

黄旗海湖泊沉积记录的早中全新世大湖期环境的差异性

内蒙古黄旗海H6剖面揭示了最近间冰期古湖泊涨缩的一个完整旋回。基于OSL年代、粒度并结合沉积物地球化学等数据,分析了黄旗海在早、中全新世（约（11.4±1.1～6.7±0.7）ka）大湖期指标记录特点与环境意义。研究认为黄旗海全新世大湖期可分为三个阶段:1）（11.4±1.1～9.3±0.9） ka BP,半深水环境、湖水盐度低、流域存在有利于化学风化的湿润气候条件;2）（9.3±0.9～7.7±0.7） ka BP,湖水变浅、湖泊萎缩、湖泊盐度升高,流域可能存在不利于化学风化的干燥气候;3）（7.7±0.7～6.7±0.7） ka BP,大湖期结束,指标记录存在剧烈波动,揭示气候具有宽幅震荡特征。同时,研究初步认为Mn/Li比值可以作为流域化学风化的指标指示。     

新疆东准噶尔拉伊克勒克斑岩铜(钼)矿床成岩成矿年龄、地球化学特征及其意义

拉伊克勒克矿床是在第四系覆盖区新发现的隐伏斑岩铜(钼)矿床。采用LA-ICP-MS技术,对赋矿岩体英云闪长岩中的锆石和矿石中的辉钼矿分别进行锆石U-Pb同位素、Re-Os同位素和锆石Hf同位素测定及相应的研究。测得锆石U-Pb年龄为421.8±2.5Ma,辉钼矿Re-Os模式年龄为409.1±2.6Ma,表明拉伊克勒克斑岩铜(钼)矿床形成于晚志留世—早泥盆世,与琼河坝地区主要斑岩矿床大规模成矿时间一致。英云闪长岩属过铝质-钙碱性系列花岗岩类,岩体具有较高的铝钙含量,K_2O/Na_2O值普遍偏低,介于0.16~0.29之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显。在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集。同时岩体具有高的正ε_(Hf)(t)值(10.98~15.01)和年轻的模式年龄(451~708Ma),暗示英云闪长岩体是大陆边缘弧环境下大洋板片熔融的产物,对进一步明确琼河坝地区斑岩型矿床的成矿环境和找矿方向具有重要意义。     

内蒙古东乌旗宝力高庙组地层划分及其同位素年代学研究

在1/5万内蒙古东乌旗狠麦温都尔地区的矿产远景调查工作中,首次按照岩性组合的差异,将宝力高庙组划分出以安山岩、安山质火山碎屑岩夹砂砾岩为主和以酸性火山岩-火山碎屑岩、炭质板岩、河流相砂砾岩为主的上、下段.在其中分别采集地层中的流纹岩、英安质晶屑凝灰岩和安山岩夹层样品,挑选其中的锆石进行U-Pb SHRIMP同位素测年,分别获得了上段303.4±6.7 Ma,304.9±3.1 Ma和下段320.1±7.2 Ma的年龄信息,地层时代为晚石炭世.该成果对研究古亚洲洋的闭合和晚华力西期成矿地质背景均具有十分重要的意义.