南海北部深水盆地沉积-构造的差异性及其油气意义

南海北部深水区自西向东依次分布着琼东南盆地、珠江口盆地、台西南盆地等新生代被动陆缘盆地,这些盆地经历了大致相当的从裂陷到坳陷的构造演化史,但在张裂活动过程中存在着明显的沉积-构造的差异性。构造沉降特征分析显示:在同一构造带上自西向东有盆地主要构造沉降发生的时段逐步变晚的趋势;在不同构造带上自北向南有盆地主要构造沉降发生的时段逐步变晚的趋势。这种沉积-构造的差异性对烃源岩的发育类型、分布及生储盖组合等方面有明显的控制作用,表现为:裂谷期构造沉降幅度大的盆地,陆相烃源岩发育,以陆生陆储陆盖型成藏组合为主;裂后期构造沉降幅度大的盆地,海相烃源岩发育规模较大,海生海储海盖型成藏组合及混生海储海盖型生储盖组合所占分量逐渐增多。推测渐新统湖相-湖沼相及海陆过渡相源岩和中新统海相烃源岩应是南海北部深水区油气的主要来源,陆生海储海盖型、海生海储海盖型及混生海储海盖型生储盖组合应是深水区基本生储盖组合类型。     

Sequence stratigraphic framework and sedimentary model of Shanxi Formation in northeast Zhoukou Depression of the North China Plate

The sequence stratigraphic framework of Shanxi Formation in the northeast Zhoukou Depression was established based on detailed sequence stratigraphical and sedimentological analysis by utilizing the logging and core data of six wells drilled in the eastern tectonic unit of Zhoukou Depression. It was divided into three third-order sequences, namely SQs1, SQs2, and SQs3 from bottom to top. Each sequence can be divided into a transgressive system tract (TST) and a highstand system tract (HST). Furthermore, four sequence boundaries and three maximum flooding surfaces were identified, and they are the bottom interface SBs and maximum flooding surface mfss1 of SQs1, the bottom interface SBs1 and maximum flooding surface mfss2 of SQs2, the bottom interface SBs3 and maximum flooding surface mfss3 of SQs3, and the top interface SBx from bottom to top. Carbonate tidal flat –clastic tidal flat sedimentary system developed in Shanxi Formation in the northeast Zhoukou Depression (also referred to as the study area) under the control of regression. Meanwhile, four sedimentary microfacies were identified in the sedimentary system, which are lime-mud flats, sand flats, mixed flats, and mud flats. The transgression in the study area occurred from the southeast to the northwest. Therefore, the northwestern part is the seaward side, and the southeastern part is the landward side. As revealed by relevant drilling data, SQs1 of the Shanxi Formation is characterized by the development of limestone and carbonaceous mudstone, with limestone, dark mudstone, and carbonaceous mudstone mainly developing. Meanwhile, lime-mud flats were mainly deposited in it. During the periods of SQs2 and SQs3, the sedimentary environment of the study area changed from the carbonate tidal flats to clastic tidal flats as the coastline migrated towards the sea. In these periods, sand flats mainly developed near the maximum flooding surfaces and were relatively continuous in the eastern and southern parts of the transgressive system tract; mixed flats were relatively continuous in the western and northern parts of the transgressive system tract as well as the eastern and southern parts of the highstand system tract; mud flats widely developed in the highstand system tract. Peat flats mainly developed in the period of HSTs2, with coal seams relatively developing in the southeastern part of the study area as revealed by drilling data. The peat flats in SQs2 are favorable hydrocarbon source layers, the lime-mud flats in SQs1 and sand flats formed in the transgression periods of SQs2 and SQs3 constitute favorable hydrocarbon reservoirs, and the mud flats form in the transgressions periods serve as favorable cap rocks. Therefore, the study area features a reservoir-cap assemblage for self-generating and self-storing of hydrocarbon, and the southeastern part of the study area can be taken as a favorable exploration area.     

藏南昂仁县贡久布地区晚二叠世孢粉组合的特征及其意义

贡久布一带的敌布错组分布于隆格尔-南木林地层分区,含较丰富的孢子花粉化石,以华夏植物群孢子花粉为特征,同时采获大量的植物化石,其时代为晚二叠世早期。根据地层中孢子花粉的演化规律,可建立Vetreisporitessignatus-Limitisporitesrectus孢子花粉组合带。丰富了古生物学的研究内容,为研究该区晚二叠世的沉积环境、古生态、生物古地理分区和地质演化历史提供了基础资料。结合区域资料分析,认为植物组合由冈瓦纳植物群与华夏植物群混生到典型华夏植物群是逐渐演化的。     

藏南昂仁县贡久布地区晚二叠世孢粉组合的特征及其意义

贡久布一带的敌布错组分布于隆格尔-南木林地层分区,含较丰富的孢子花粉化石,以华夏植物群孢子花粉为特征,同时采获大量的植物化石,其时代为晚二叠世早期.根据地层中孢子花粉的演化规律,可建立Vetreisporites signatus-Limitisporitesrectus孢子花粉组合带.丰富了古生物学的研究内容,为研究该区晚二叠世的沉积环境、古生态、生物古地理分区和地质演化历史提供了基础资料.结合区域资料分析,认为植物组合由冈瓦纳植物群与华夏植物群混生到典型华夏植物群是逐渐演化的.     

Chloritoid–glaucophane schist in the north Qilian orogen, NW China: phase equilibria and P–T path from garnet zonation

Chloritoid–glaucophane‐bearing rocks are widespread in the high‐pressure belt of the north Qilian orogen, NW China. They are interbedded and cofacial with felsic schists originated from greywackes, mafic garnet blueschists and low‐T eclogites. Two representative chloritoid–glaucophane‐bearing assemblages are chloritoid + glaucophane + garnet + talc + quartz (sample Q5‐49) and chloritoid + glaucophane + garnet + phengite + epidote + quartz (sample Q5‐12). Garnet in sample Q5‐49 is coarse‐, medium‐ and fine‐grained and shows two types of zonation patterns. In pattern I, X_grs is constant as X_py rises, and in pattern II X_grs decreases as X_py rises. Phase equilibrium modelling in the NC(K)MnFMASH system with Thermocalc 3.25 indicates that pattern I can be formed during progressive metamorphism in lawsonite‐stable assemblages, while pattern II zonation can be formed with further heating after lawsonite has been consumed. Garnet growth in Q5‐49 is consistent with a continuous progressive metamorphic process from ～14.5 kbar at 470 °C to ～22.5 kbar at 560 °C. Garnet in sample Q5‐12 develops with pattern I zonation, which is consistent with a progressive metamorphic process from ～21 kbar at 540 °C to ～23.5 kbar at 580 °C with lawsonite present in the whole garnet growth. The latter sample shows the highest P–T conditions of the reported chloritoid–glaucophane‐bearing assemblages. Phase equilibrium calculation in the NCKFMASH system with a recent mixing model of amphibole indicates that chloritoid + glaucophane paragenesis does not have a low‐pressure limit of 18–19 kbar as previously suggested, but has a much larger pressure range from 7–8 to 27–30 kbar, with the low‐pressure part being within the stability field of albite.     

Probabilistic aspects of micropaleontologic assemblage zones

A micropaleontologic assemblage zone is defined by occurrence of some characteristic species among many coeval species. When number of assemblage-defining species and total number of species observed are designated as Aand N,respectively, the ratio, A/N,is strongly dependent on duration of the assemblage. Theoretical consideration on the basis of a micropaleontologic cohort model shows that, when origination rate and extinction rate of species are obtained, the most reasonable ratio (A/N) and duration of the assemblage can be determined. The probabilistic model described in this paper provides a theoretical relation between the ratio and the duration. Inaccuracy in correlating micropaleontologic data to certain assemblage zones established can not be avoided because of many natural sorting and artificial biases. Ambiguity arising when data with a small number of characteristic species are correlated with a certain assemblage is numerically estimated.     

广东乳源彩石的矿物学特征及颜色成因研究

乳源彩石是具有华丽色彩的一种观赏石.采用偏光显微镜、扫描电子显微镜、电子探针、红外光谱仪以及X射线粉末衍射仪等测试手段对4块乳源彩石标本的显微结构、矿物组成和化学成分等进行测试与分析.结果表明,这些乳源彩石具有变粉砂结构,主要由石英组成（占总体质量分数的90％以上）,含少量云母,其它矿物的质量分数低,是一种浅变质的变石英粉砂岩;另外,4块乳源彩石样品的结晶度指数相近,结晶度指数最高的绿色样品推测是由于其含有后期充填的鲕状矿物导致.最后对乳源彩石样品的颜色成因进行了分析与探讨,认为其颜色为次生色,是由次生矿物组合、交代蚀变和氧化程度的不同而形成的.     

赣南淘锡坑钨矿床流体包裹体特征及其地质意义

淘锡坑钨矿是赣南一个重要的大型石英脉型钨多金属矿床。矿床主要矿化阶段含矿石英脉中石英和黄玉中的流体包裹体类型有单一水溶液相H2O-NaCl(Ⅰa型)、富液L+V两相H2O-NaCl(Ⅰb型)、两相H2O-NaCl-CO2体系包裹体(Ⅱa型)和三相H2O-NaCl-CO2包裹体(Ⅱb型)。Ⅰb型包裹体均一温度范围为80~370℃,具有多峰态分布特征,可识别出140~190℃,200~250℃和340~360℃几个峰。成矿流体的盐度相对较低,一般<8w(NaCleq)%。用流体包裹体组合的方法获得四组包体的相关参数,结果表明同一包体组合内不同包体的盐度、均一温度及密度基本一致,而不同包体组合中包体的盐度、均一温度及密度则相差较大,显示出不同包体组合所捕获的流体存在较大的差异。Ⅰb型包裹体均一温度分别分布在329~355℃,214~240℃和141~189℃三个温度区间,经压力校正后的捕获温度分别为400~425℃,275~300℃,210~260℃。这些特征表明,淘锡坑钨矿至少存在三期热液流动,其中前两期为成矿期的热液活动,第三期(次生包体)为成矿后的热液活动。根据Ⅱ型包裹体的CO2部分均一温度与最终均一温度计算出成矿流体的捕获压力67.3~97.8 Mpa,平均压力74.8 Mpa,按静岩压力换算成成矿深度为2.59~3.77 km,平均为2.88 km。     

鄂尔多斯盆地西南缘早白垩世地层孢粉组合及地层意义

正鄂尔多斯盆地是中国大陆形成最早、演化历史最长的一个沉积盆地,也是我国重要的煤炭、石油、天然气矿产地。近年来,随着国家对清洁能源的需求,加大了对该盆地的砂岩型铀矿的找矿工作,但长期以来对鄂尔多斯盆地西南缘铀矿目的层白垩系志丹群的古生物化石、古环境研究相当缺乏,而对于白垩纪孢粉研究更为少见,仅在1988～1992年有过几例孢粉研究(张子福,1988,1989,1992),     

金矿自然重砂矿物组合规律及其找矿指示意义

对云南、海南、江西、湖北、河南、新疆、浙江、山东、辽宁等27个省185个典型金矿床的自然重砂矿物进行统计分析,发现自然重砂矿物对金矿具有良好的响应,自然金、黄铁矿、方铅矿、黄铜矿、白铅矿、辰砂等对寻找金矿具有指示意义。不同成因类型的金矿床反映出的自然重砂矿物组合不同,斑岩型金矿床的标型指示矿物组合为自然金+黄铁矿+方铅矿+重晶石+闪锌矿+白铅矿+金红石,卡林型—类卡林型金矿床的标型指示矿物组合为自然金+黄铁矿+方铅矿+辉锑矿+毒砂+雄(雌)黄,而造山型+矽卡岩型+热液型+构造蚀变岩型金矿床的标型指示矿物组合为自然金+黄铁矿+方铅矿+辰砂。不同区域的金矿床反映出的自然重砂矿物组合也各有差异,闪锌矿为南方各省金矿床的特征矿物,辰砂和白钨矿为北方地区金矿床的特征矿物,重晶石和白铅矿为西部地区金矿的特征矿物。综合研究认为,自然重砂具有直接找矿和指导找矿的作用,按照特定成因类型和区域金矿床所建立的自然重砂矿物组合对建立矿床找矿模型具有重要的意义。