Calculating actual crop evapotranspiration under soil water stress conditions with appropriate numerical methods and time step

Calculation of actual crop evapotranspiration under soil water stress conditions is crucial for hydrological modeling and irrigation water management. Results of actual evapotranspiration depend on the estimation of water stress coefficient from soil water storage in the root zone, which varies with numerical methods and time step used. During soil water depletion periods without irrigation or precipitation, the actual crop evapotranspiration can be calculated by an analytical method and various numerical methods. We compared the results from several commonly used numerical methods, including the explicit, implicit and modified Euler methods, the midpoint method, and the Heun's third‐order method, with results of the analytical method as the bench mark. Results indicate that relative errors of actual crop evapotranspiration calculated with numerical methods in one time step are independent of the initial soil water storage in the range of soil water stress. Absolute values of relative error decrease with the order of numerical methods. They also decrease with the number of time step, which can ensure the numerical stability of successive simulation of soil water balance. Considering the calculation complexity and calculation errors caused by numerical approximation for different time step and maximum crop evapotranspiration, the explicit Euler method is recommended for the time step of 1 day (d) or 2 d for maximum crop evapotranspiration less than 5 mm/d, the midpoint method or the modified Euler method for the time step of up to one week or 10 d for maximum crop evapotranspiration less than 5 mm/d, and the Heun's third‐order method for the time step of up to 15 d. Copyright © 2011 John Wiley & Sons, Ltd.     

锂离子选择电极的研究 Ⅲ.：开链聚醚三（二环己酰胺）锂电极的制备和应用

以合成的开链聚醚三(二环己酰胺)等中性载体制成了PVC膜Li~+电极,研究了载体结构、膜成分与电极性能的关系,在聚醚三酰胺的胺基中,以环己基取代直链的烷基,显著地改善了Li~+—载体的性能,以邻苯二甲酸二癸酯或其和二苄醚混合增塑的1,1,1—三[1′—(2′—氧杂—3′—二环己胺基羰基)丙基]丙烷Li~+—电极的线性响应范围为2×10~(-5)～10~(-1)mol/L LiCl,K_(Li+Na)~(pot)～8×10~(-3),以Mg(Ac)_2为离子强度调节缓冲剂,用标准比较法或样品加入法测定了LiCl—HCl—H_2O或LiCl—MgCl_2—HCl—H_2O体系中的Li~+,LiCl含量≥2％的样品,测定误差≤5％。     

Interpretation of gamma-ray logs: The distribution of uranium in carbonate platform

High gamma-radioactivity in carbonates is usually ascribed to uranium of detrital minerals and organic matter, and to thorium and potassium of clays. The present study based on Urgonian marls and marly limestones (France) shows that some of the most radioactive values correspond instead to some ‘pure’ limestones. These peaks are generally associated with a sequence boundary or a maximum flooding surface. Low-level γ-spectrometry and ICP–MS analyses show that although high radioactivities are mostly associated with uranium, there is no obvious correlation between uranium enrichment and lithology. Also, correlation between high radioactivity and argillaceous beds might not be systematic. To cite this article: M.C. Raddadi et al., C. R. Geoscience 337 (2005).     

Statistical characteristics of chlorophyll-a concentration in Hong Kong′s coastal waters

In this paper seven of the ten Water Control Zones (WCZs) in Hong Kong′s coastal waters with monthly or bi-weekly sampling data of 17 parameters collected at 37 monitoring stations from 1988 to 1999 were selected to analyze the spatial and temporal variations of chlorophyll-a and its influencing factors. Cluster analysis was employed to group the monitoring stations based on the structure of the data set. Multiple step regression was employed to determine the significant influencing factors of chlorophyll-a level. The results suggest that all the monitoring stations could be grouped into two clusters. Cluster I with frequent red tide incidents comprises two WCZs which aresemi-enclosed bays. Cluster II with less red tide occurrence comprises the other five WCZs in an estuarine environment in the west. For both clusters, the organic contents indicator, BOD5, was a common significant influencing factor of the chlorophyll-a level. Nitrogen and light penetration condition related to turbidity, total volatile solids and suspended solids had more influence on the cholophyll-a level in Cluster I than in Cluster II, while phosphorus and oceanographic conditions associated with salinity, temperature, dissolved oxygen and pH were more important in Cluster II than in Cluster 1. Generally, there was a higher average chlorophyll-a level in winter and autumn in a year.The chlorophyll-a level was much higher in Cluster I than in Cluster II among all seasons. Although the chlorophyll-a concentration had great variations from place to place in Hong Kong′s coastal waters, it seemed to have a common long term fluctuation period of 8-10 years with a high-low-high variation in the period in the whole region, which might be influenced by other factors of global scale.     

HUMBOLDT AND THE HABITABILITY OF CANADA'S GREAT NORTHWEST*

ABSTRACT. Alexander von Humboldt's influence in British North America during the nineteenth century was filtered mainly through British imperial applications of “Humboldtian” sciences, including geomagnetism and biogeography. The best‐known examples include Edward Sabine and John Henry Lefroy, Royal Artillery officers who, during the 1830s and 1840s, transformed British North American outposts and territories, including Rupert's Land, into Humboldtian sites and regions in Great Britain's imperial “magnetic crusade.” Important groundwork had already been laid by John Richardson, who applied data accrued during John Franklin's overland Arctic expeditions during the 1820s to systematize Humboldtian inquiries into the habitability of Canada's Great Northwest. Despite both the relative decline of Humboldtian sciences by midcentury and Humboldt's own reservations about the political ramifications of his science, his “cosmic” outlook circulated in Canada to refine territorial expansionists' scientistic arguments justifying annexation of Rupert's Land after the monopoly of the Hudson's Bay Company expired in 1869.     

Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin     

高围压高水压渗流条件下岩石的力学性质试验研究

对锦屏二级水电站引水隧洞大理岩、砂岩和板岩进行了高水压高围压渗流条件下的全应力应变过程三轴压缩实验,分析了高围压高水压对岩石强度及变形的影响,探讨了岩石强度与围压及孔隙水压力之间的关系。     

Ag-rich Tetrahedrite in the El Zancudo Deposit,Colombia: Occurrence,Chemical Compositions and Genetic Temperatures

Chemical compositions of tetrahedrite—Ag-rich tetrahedrite—freibergite solid solutions (Ag-rich tetrahedrite_ss) and homogenization temperatures of fluid inclusions in quartz and carbonates of seventeen samples from nine veins in the El Zancudo deposit, Antioquia, Colombia, were investigated to reveal the origin of silver in Ag-rich tetrahedrite_ss, to derive their crystallization temperatures and to examine the relationship between chemical compositions of Ag-rich tetrahedrite_ss and their crystallization temperatures. The ores consist of arsenopyrite, pyrite, sphalerite, Ag-rich tetrahedrite_ss, galena, boulangerite, andorite, owyheeite, diaphorite, jamesonite, miargyrite, bournonite, chalcopyrite, and electrum. Ag-rich tetrahedrite_ss forms about 10 volume % of the total ores and is one of the most common and widely distributed sulfosalts in this deposit. Ag-rich tetrahedrite_ss is rich in Ag (1.13 to 31.02 wt%) and Sb (22.93 to 29.82 wt%), and poor in As (0.06 to 2.43 wt%), consistent with the reported incompatibilities of Ag and As in Ag-rich tetrahedrite_ss. The Zn/(Zn + Fe)-, Ag/(Ag + Cu)- and Sb/(Sb + As + Bi)-atomic ratios exhibit some variations among the veins. Ag-rich tetrahedrite_ss with higher Ag/(Ag + Cu) ratios coexist with diaphorite, whereas those with lower ratios are not associated with this sulfosalt. Ag-rich tetrahedrite_ss in the assemblages of Ag-rich tetrahedrite_ss+ sphalerite and of Ag-rich tetrahedrite_ss+ bournonite + galena shows no Zn ↔ Fe and Cu ↔ Ag variations between core and rim, respectively, negating the possibility of solid state reaction during cooling. Ag-rich tetrahedrite_ss is thus regarded as primary phase. Homogenization temperatures of primary fluid inclusions in quartz and carbonates co-existing with Ag-rich tetrahedrite_ss define the mineralization temperatures of 134 to 263°C. Independent crystallization temperatures of Ag-rich tetrahedrite estimated based on Zn/(Zn + Fe) and Ag/(Ag + Cu) ratios of the Ag-rich tetrahedrite_ss associated with silver minerals such as miargyrite, andorite and diaphorite using Sack's thermochemical database lie in a range between 170 and ∼250°C. Both results are thus in good agreement.     

基于Poulos弹性理论的被动桩改进算法

传统的Poulos弹性理论仅适合于均质土中土体侧向位移时桩的性状分析,无法考虑土的层状特性。通过引入层状地基中作用一水平集中力的广义Mindlin解和地面作用有竖向荷载时的应力和位移通解,对Poulos方法进行了改进,使之扩展到多层土中,还用于研究堆载条件下的被动桩变形和受力响应。算例分析表明,改进弹性理论要比Poulos方法更为严密、合理,提高了计算精度,应用范围也更广。     

Correction on effect of Earth’s oblateness in inversion of GPS occultation data

By using observed CHAMP orbit ephemeredes and MSISE-90 dry air model and regarding the earth as a sphere and an ellipsoid respectively, phase delays are simulated and the simulated data are retrieved under different schemes. The comparison between the inverted temperature profiles and the model temperature profiles shows that by inverting observed data, we will get temperature results with large errors if the effect of Earth’s oblateness is omitted. The correction method is proved to be effective because the temperature errors decreased obviously with this method.