The U-Pb Geochronology and Lu-Hf Isotope Compositions of Detrital Zircons from the Nanhua Group of the Longsheng Region, South China and their Implications for Pan-African Events

It is unclear whether the South China blocks have an affinity with continental Gondwana due to a lack of direct Pan-African magmatic and metamorphic features. In this study, we conducted U-Pb geochronological and Lu-Hf isotopic analyses for detrital zircons from a sandstone of the Chang’an Formation of the Nanhua Group in the Longsheng region of northern Guangxi, with the aim of constraining the timing of sedimentation and information as to its source, as well as seeking evidence for Pan-African events in the South China blocks. The results show that the ages of detrital zircons peaked at 654.7 ± 6.2 Ma, 773.2 ± 4.1 Ma and 821.9 ± 6.5 Ma, with some at 920–870 Ma; the youngest age indicates the existence of the Pan-African thermal event. The εHf(t) and TDM2 values demonstrate that the study area has experienced three stages of crustal growth at 3.0–2.4 Ga, 2.1–1.5 Ga and 1.3–0.9 Ga. With intensively distributed Neoproterozoic mafic-ultramafic and granitic plutons emplaced at 830–810 Ma along the southwestern section of the Jiangnan Orogenic Belt and positive εHf(t) values from a large group of zircon grains, it is proposed that the sediments of the Chang’an Formation (of Nanhua Group) were largely sourced from the southeastern margin of the Yangtze block. Comparison with the zircon age spectra of the Cathaysian block shows that about 79% of the Pan-African aged detrital zircon grains that have TDM2 = 1352–1031 Ma and εHf(t) = 3.68–8.79, were sourced from the recycled Grenvillian crust of the Cathaysian block, suggesting that the Cathaysian block had a close connection with Gondwana.     

武当地块基性岩墙群的Sm-Nd定年及其相关问题讨论

武当地块是卷入南秦岭构造带的前震旦纪基底岩块,该基底岩块中广泛发育变形变质的基性岩墙群,获得岩墙群的ＳｍＮｄ全岩等时年龄为ｔ＝７８２±１６４（２σ）Ｍａ,ＩＮｄ＝０．５１１７１±１６（２σ）,εＮｄ（ｔ）＝＋１．５±１．０。据此并综合区域地质实际,对南秦岭元古代古陆块的存在及其裂解等相关问题进行了讨论。     

Petrogenesis of Dashenshan I-type granodiorite: implications for Triassic crust–mantle interaction,South China

Triassic granodiorites in South China (SC) provide an opportunity to examine crust–mantle interactions that may have been caused by a mantle plume. Here we present a combined study of chronological, geochemical, and Sr–Nd–Hf isotopic compositions for Dashenshan granodiorites. These are high-K, calc-alkaline, I-type granodiorites that yield a U–Pb zircon age of 211 ± 3 Ma. They are metaluminous to weakly peraluminous (A/CNK < 1.1), with 3.04–3.89 wt.% Na₂O and 3.24–3.86 wt.% K₂O, and Na₂O/K₂O ratio ranging from 0.79 to 1.11. These granodiorites contain 67.7–72.6 wt.% SiO₂ but show moderate Mg^# values (44.2–57.8) and variable contents of Ni (3.6–29.9 ppm) and Cr (7.6–53.5 ppm). They exhibit light rare earth element (REE) enrichment and flat, heavy REE patterns with negative Eu anomalies (Eu/Eu* = 0.52–0.87). They also display strongly negative Ba, Sr, Nb, Ta, P, and Ti anomalies and positive Rb, Th, K, and Pb anomalies. Dashenshan granodiorites have high whole-rock initial ⁸⁷Sr/⁸⁶Sr ratios (0.7121–0.7172), negative ε_Nd (t) values (–8.8 to –6.8), and negative zircon ε_Hf (t) values (–6.6 to –3.3). These results suggest that the Dashenshan granodiorites were generated by a mixing between crustal melt and mantle-derived magma in an extensional setting. We conclude that generation of the Dashenshan pluton may reflect an interaction between a mantle plume and the overlying SC crust.     

海洋钙离子非保守行为及海洋钙问题

钙离子是海洋11种常量离子之一,与钠、钾等离子的保守性不同,钙离子在海洋中的分布表现出微小但系统的变化。钙离子的变化往往与海洋碳酸钙的形成和溶解过程有关,所以,钙离子可直接指示海洋碳酸钙通量（深层海洋碳通量的主要组成部分）。同时,碳酸钙沉淀或溶解又会改变总碱度和溶解无机碳,通过钙离子变化也能间接探讨海洋碳酸盐系统和海洋吸收CO2的能力。介绍了以碳酸钙溶解形成超额钙为主的海洋钙离子多种非保守行为及其控制过程,讨论这些过程对海水组成和海洋碳酸盐系统的影响,探讨未来海洋酸化条件下钙离子可能的变化及其潜在的效应,最后展望在南海开展钙离子精细行为的研究意义。      

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

Palaeobotanical evidence of wildfires in the Late Palaeozoic of South America – Early Permian, Rio Bonito Formation, Paraná Basin, Rio Grande do Sul, Brazil

Fossil charcoal, as direct evidence of palaeowildfires, has repeatedly been reported from several plant-bearing deposits from the Late Palaeozoic of the Northern Hemisphere. In contrast charcoal reports from the Late Palaeozoic deposits of the Southern Hemisphere are relatively rare in comparison to the Northern Hemisphere. Although the presence of pyrogenic coal macerals has repeatedly been reported from Late Palaeozoic coals from South America, no detailed anatomical investigations of such material have been published so far. Here is presented an anatomical analysis of charcoal originating from Early Permian sediments of the Quitéria Outcrop, Rio Bonito Formation, Paraná Basin, located in the central-eastern portion of Rio Grande do Sul, Brazil. This charcoal comes from two different coaly facies, and it was possible to scrutinize between three types, based on anatomical characters of the charcoal. Two of these charcoal types can be correlated to gymnosperm woods, and the other type corresponds to strongly permineralized bark with characteristic features of lycopsids. The presence of charcoal in different facies, ranging from parautochtonous to allochtonous origin, indicates that different vegetation types, i.e. plants which grew under wet conditions in the lowland as well as in the more dry hinterland, have experienced wildfires. Taking into account previous petrographic and lithological analyses from the facies in which the charcoal occurs and from the conditions of the wood and bark fragments, it was possible to speculate that the intensity of such wildfires most probably corresponds to forest-crown fires. Moreover, it is possible to state that wildfires have been a more or less common element in distinct Late Palaeozoic terrestrial ecosystems in the South American part of Gondwana. The data support previous assumptions on the occurrence of wildfires in the Early Permian of the Paraná Basin which were based solely on coal-petrographic data.     

华南早寒武世黑色岩系重晶石矿床环带钡冰长石 新发现及其意义

华南早寒武世黑色岩系重晶石矿床是全球著名的沉积型层状矿床。本文报道了我们最近的一项新发现,在该区天柱大河边重晶石矿床中首次发现了环带钡冰长石,环带的外带BaO含量1653%～1786%,K2O含量777%～819%,相比而言,核部BaO含量1204%～1421%,K2O含量860%～979%。结合成矿地质背景和已有工作报道,讨论了这一新发现的地质意义。认为这种环带钡冰长石的出现,反映了重晶石成矿受到热水作用影响,且其形成过程中经历了不同期富钡流体的影响,成矿可能属于一种热水、断控、幕式、渐进的过程,这不仅进一步揭示了矿床的热水（液）喷流沉积成因,而且加深了对成矿过程的刻画。该认识还可供全球沉积型重晶石矿床成因研究时类比参考。     

Rugose corals from the Upper Ordovician Sholeshook Limestone of southwest Wales with an assessment of the coral affinities and biofacies

Limestone horizons of Upper Ordovician (Katian) age in southwest Wales contain diverse fossil faunas including rugose corals. The existence of Ordovician Rugosa in Wales was first reported by Murchison in the 1830s, but since then hardly any specimens have been documented systematically until this present study. Newly collected material from the area around Llanddowror (Carmarthenshire) has now confirmed the diversity of rugose corals in the Sholeshook Limestone (Katian age), an arenaceous limestone originating from the shelf edge of the palaeocontinent Avalonia. The majority of the specimens are preserved as moulds. This means that in many instances preservation of the fossils was insufficient for specific identification; nevertheless, it was possible to document a diverse rugose coral fauna, including Helicelasma, probable Grewingkia and Kenophyllum, and a potential early mucophyllid. While associated with considerable difficulties, as some diagnostic features of Rugosa are not visible in moulds, it is demonstrated here that the work with such specimens can result in faunal information which would otherwise be unobtainable. An assemblage of rugose and tabulate corals in the Sholeshook Limestone can be differentiated from a similar assemblage in the neighbouring Robeston Wathen Limestone which has a slightly different lithology. The fauna has strong similarities with other Avalonian (Irish, English, Belgian) as well as Baltic (Estonian and Norwegian) rugose coral faunas. Copyright © 2012 John Wiley & Sons, Ltd.     

南海海域新生代沉积盆地构造演化的动力学特征及其油气资源

通过对构造环境、地球物理场特征、盆地生储盖层发育等方面对比研究, 讨论南海南北部沉积盆地的油气资源分布特征, 为在南海进行油气勘查指明方向.目前油气勘探实践证明, 南海南部的油气资源比北部丰富, 究其原因, 南海北部为被动大陆边缘, 张性沉积盆地的烃源岩体积较小, 而南部挤压环境下形成的沉积盆地的烃源岩体积大; 北部的地热流较南部小, 因此地温梯度也较小, 如北部陆架上的珠江口盆地的热流值在5 3~ 87mW /m2之间, 平均6 7mW /m2, 而南海南部大曾母盆地平均热流值达97mW /m2, 最大值达130mW /m2, 故南部边缘烃源岩的成熟度比北部高; 由于南部边缘处于挤压构造环境, 因此在沉积盆地中形成了许多挤压构造, 而北部边缘一直处于张性构造环境, 形成的构造较少且较小; 同时, 南部边缘沉积盆地中, 烃源岩生烃与构造形成在时间上搭配较好.因此, 在南海南部边缘沉积盆地中形成了许多大型油气田, 而南海北部边缘沉积盆地中, 大型油气田较少, 中小型油气田较多.这就是为什么南海南部边缘的油气资源比北部丰富的地质原因.      

塔里木河南岸地下淡水资源分布特征及成因分析--以哈得4油田水源地为例

塔里木河南岸地下水资源，卡要为受塔里水河控制的具有高矿化背景的地下水，在塔里木河洪水的淡化影响下，形成了一定范围的地下水淡化带．这种淡化水对油田供水具有战略意义，在一定程度上制约着油田建设的发展．通过对塔埋木河南岸地下淡水资源的分布特征与成因分析．为塔河南岸地下淡水资源的合理开发与利用指明了方向．