磷灰石中磁黄铁矿出溶结构的发现

中国东部苏鲁地区(江苏赣榆)出露大理岩-榴辉岩块体,其菱镁矿大理岩中保存的白云石分解结构表明地壳物质俯冲深度达到-200公里。在与该大理岩共生的榴辉岩中,我们发现了磷灰石的磁黄铁矿出溶结构。磷灰石是该榴辉岩的主要副矿物,其自形程度较高,与石榴石共生。样品中几乎所有磷灰石均发育出溶结构,至少存在两组相互垂直的出溶棒,它们各自严格沿同一个方向分布。出溶棒形状规则,宽度相近(<1μm),但长度变化大(5-50μm)。利用高分辨能谱仪测定其能谱,结果表明,出溶棒主要由Fe和S两种元素组成,但不能准确地确定其Fe/S比值。我们把这种出溶棒初步确定为磁黄铁矿(Fe1-xS)。磷灰石由于含大量稀土元素和挥发性组分如OH、F、Cl等以及我们所观察到的S,它的深循环因此可能对地球的水、硫以及其它挥发性组分的全球平衡具有重要影响。本文报道的磷灰石中磁黄铁矿出溶结构为深入探讨这个基本科学问题提供了一个新的突破口。     

南苏鲁超高压变质地体中罗迪尼亚超大陆裂解事件的记录

通过苏鲁超高压变质地体南部不同类型超高压变质岩石的原岩重塑．揭示超高压变质岩的原岩形成于由大陆玄武质岩石、辉长岩、表壳岩和花岗岩组成的被动陆缘拉伸构造环境。中国大陆科学钻探主孔中不同类型超高压变质岩石的锆石SHRIMP U-Pb定年表明。花岗质片麻岩原岩年龄为780～680Ma；榴辉岩、石榴角闪岩的原岩年龄为765～730Ma，副片麻岩中包含了730Ma、680Ma、621Ma和较年轻的继承性碎屑锆石和结晶锆石年龄。结合前人的研究成果表明，苏鲁超高压变质地体南部正片麻岩类和榴辉岩的原岩所代表的花岗岩浆和基性岩浆活动为罗迪尼亚超大陆形成后的新元古代裂解事件的产物．而副片麻岩的原岩为新元古代．古生代时期形成的扬子被动陆缘的沉积-火山表壳盖层，它们与结晶基底一起在240～220Ma期间经历了超高压变质作用。     

青藏高原的构造分区及其边界的变形构造特征

宏观构造特征的确立对青藏高原隆升和“动力学建模”具有重要意义。青藏高原是由来自塔里木-中朝板块的北昆仑-阿尔金-祁连地体,华南-东南亚板块的南昆仑地体、可可西里-巴颜喀拉地体和冈瓦纳古陆的羌塘地体、冈底斯地体及喜马拉雅地体等3大板块(或古陆)的6个地体经多次裂解、会聚和陆内俯冲作用拼合而成的巨型“会聚-陆内俯冲型”岩石圈块体,它以青藏高原南缘结合带、青藏高原北缘结合带和青藏高原东缘结合带依次与印度岩石圈块体、塔里木-阿拉善-鄂尔多斯岩石圈块体和扬子岩石圈块体相隔。按现今动力学特征,这一巨型岩石圈块体(一级构造单元)又可进一步划分为喜马拉雅、藏北、青南和昆仑-阿尔金-祁连等4个二级构造单元(地块),它们依次以雅鲁藏布江结合带、西金乌拉-金沙江结合带、中昆仑结合带为界。4个地块又可进一步划分为若干以断裂为界的三级构造单元(地体)。组成青藏岩石圈块体的各构造单元处于统一的地球动力学系统,它总的表现为:在印度板块向欧亚板块持续、强烈俯冲和热的、具柔性流变学特征的青藏块体整体向北北东方向移动的区域构造背景上,其南、北两侧的喜马拉雅地块、昆仑-阿尔金-祁连地块分别向冷的、刚性的印度岩石圈块体和塔里木- 阿拉善-鄂尔多斯岩石圈块体不对称逆冲叠覆。位于青藏高原腹部的藏北地块和青南地块,在深部存在大量低速体向上涌动和整体自西向东扩展的区域构造背景上,前者叠置近南北向挤压,形成以南北向断陷带及北西和北东向共轭走滑为主的构造格局,而青南地块除松潘-甘孜地体显示自北而南的逆冲叠覆外,可可西里-巴颜喀拉地体以逐一向东挤出的左行走滑作用为主,以致整个青南地块呈现向扬子岩石圈块体逆冲扩展和向三江构造带平移扩展。因此,就现今动力学而言,青藏高原在随着时间推移、隆升速度不断加快的同时,还逐渐向外缘的刚性地块扩展,即高原面积在不断增大。因此青藏高原的边界具有扩展性质,按扩展机制可区分两类扩展型动力边界:走滑型扩展边界和逆冲型扩展边界。典型的走滑型扩展边界位于青藏高原北缘的阿尔金山和青藏高原东缘的三江地区,青藏高原南缘的动力边界属典型的逆冲型扩展边界,而位于祁连山和龙门山的动力边界兼有逆冲和走滑双重扩展性质。     

Petrofabrics and seismic properties of garnet peridotite from the UHP Sulu terrane (China): Implications for olivine deformation mechanism in a cold and dry subducting continental slab

Lattice-preferred orientations (LPO) of olivine, diopside, enstatite and garnet from the Zhimafang garnet peridotite body in the Sulu ultrahigh-pressure (UHP) metamorphic terrane (China) were measured using the electron backscatter diffraction (EBSD) technique. The peridotite was captured from a mantle wedge immediately adjacent the subducted Yangtze slab and then experienced the UHP metamorphism at 750–950 °C and 4–7 GPa. The olivine LPO is characterized by the [001] axis close to the stretching lineation and the (100) plane subparallel to the foliation, indicating the prevailing of (100) [001] slip. Enstatite LPO displays the dominance of (100) [001] slip. Diopside developed complex LPO patterns that are difficult to explain using a single slip system of (100) [001]. Garnet is almost randomly oriented due to its low volume fractions, cubic symmetry and the presence of numerous slip systems. Calculated seismic properties of the peridotite yield a maximum P-wave velocity normal to the foliation and a minimum along the foliation, with anisotropy up to 8% in strongly sheared samples. The S-wave velocity pattern is complex but the fast polarization plane generally normal to the foliation. The inferred shear sense from the olivine LPO is top-to-SE, in contrary to exhumation-induced top-to-NW thrusting recorded in the quartz LPO, implying that the olivine LPO formed at early UHP metamorphic conditions. The olivine crystals have relatively low water contents (141–475 H/10⁶ Si), indicating a fluid-deficient environment for the LPO formation. The present study suggests that a combination of low temperature and UHP plays a much more important role than the water content to promote the activation of (100) [001] slip in olivine.     

Petrology of marble and peridotite in the Seiad ultramafic complex, northern California, USA

Abstract Peridotite and infolded marble of the Seiad ultramafic complex were recrystallized in the upper amphibolite facies as part of the regional progressive metamorphism of the Rattlesnake Creek terrane. Field relations, including the occurrence of metarodingites, and metasomatic zones between dissimilar rock types, demonstrate that the metasediments and serpentinized ultramafic rocks were juxtaposed prior to regional, barrovian metamorphism. Temperatures are estimated to have reached 760–800°C at pressures of 7–8 kbar during the peak of metamorphism. Four low-variance parageneses have been identified within a small (3 km²) area of the complex, which may reasonably be assumed to have formed under the same P and T conditions. Isobaric T-X co₂ diagrams of appropriate equilibria are presented for three different internally consistent sets of thermodynamic data. Despite the seemingly small numerical differences between the standard state thermodynamic properties of the data sets, only one diagram allows the four observed assemblages to coexist within a reasonable temperature range. All three phase diagrams require differences in fluid composition on the scale of a thin section; strong evidence for effective control of pore fluid composition by local mineral reactions during metamorphism.     

羌塘北缘上新世恒梁湖火山岩内含石榴子石长英质捕虏体岩石学与矿物化学特征

本文以羌塘地体北缘出露面积最大的上新世恒梁湖火山岩为研究对象，对火山岩内含石榴子石长英质捕掳体的岩相学、显微结构及矿物化学综合研究，揭示出此类捕掳体系深部地壳超高温部分熔融残余，其中石榴子石以高Mg#值(41~46)为特征。传统地质压力计估算其发生部分熔融的压力为1. 18~1. 53 GPa，对应深度约39~50 km，火山岩与捕掳体相互作用的温压条件为950~1050 ℃，1. 30~1. 66 GPa，对应深度约43~55 km。火山岩熔体快速上升冷却过程中，熔体沿捕掳体裂隙或边缘与石榴子石发生反应形成斜方辉石和斜长石，而火山岩基质内辉石及长石表现出强烈的成分环带。此研究结果首次揭示了北羌塘北缘中 深地壳岩石部分熔融所产生的熔体及其岩相学和矿物化学特征，亦为此区域地壳深部面波低速异常及强各向异性提供了深部岩石学方面的限定。     

西藏仲巴微地体中新世马莜木富钾埃达克质岩及其内暗色微粒包体的成因

西藏南部的中新世含暗色微粒包体的富钾埃达克质岩被认为是之前的大陆地壳在石榴子石稳定压力下发生部分熔融的熔体与同时期的幔源超钾质火山岩发生岩浆混合或混杂的产物。为检验这一观点,本文对雅鲁藏布江缝合带西段仲巴微地体内的中新世马莜木富钾埃达克质岩及其内的暗色微粒包体开展了岩石学、锆石U-Pb定年、矿物电子探针分析以及全岩主微量元素和Sr-Nd同位素测试等方面的工作。结果显示暗色微粒包体和富钾埃达克质岩具有相似的结晶年龄(～17.5 Ma)、矿物组合(石英+长石+角闪石+黑云母)和矿物成分,但暗色微粒包体比富钾埃达克质岩含更多的角闪石和黑云母,且具有比富钾埃达克质岩低的K₂O和SiO₂以及高的MgO、TiO₂和P₂O₅含量。除此之外,富钾埃达克质岩和暗色微粒包体还表现出相似的全岩Sr-Nd同位素组成：富钾埃达克质岩的(⁸⁷Sr/⁸⁶Sr)_i和ε_Nd(t)值分别为0.70933～0.70950和-8....     

Interpretation of gravity profiles across the northern Oaxaca terrane,its boundaries and the Tehuacán Valley,southern Mexico

A gravity study was conducted across the northern Oaxaca terrane and its bounding faults: the Caltepec and Oaxaca Faults to the west and east, respectively. These faults juxtapose the Oaxaca terrane against the Mixteca and Juarez terranes, respectively. The Oaxaca Fault also forms the eastern boundary of the Cenozoic Tehuacán depression. On the west, at depth, the Tehuacán valley is limited by the normal buried Tehuacán Fault. This gravity study reveals that the Oaxaca Fault system gives rise to a series of east tilted basamental blocks (Oaxaca Complex). The tectonic depression is filled with Phanerozoic rocks and has a deeper depocenter to the west. The gravity data also indicate that on the west, the Oaxaca Complex, the Caltepec and Santa Lucia faults continue northwestwards beneath Phanerozoic rocks. A major E–W to NE–SW discontinuity is inferred to exist between profiles 1 and 2.     

Zedong terrane revisited: An intra-oceanic arc within Neo-Tethys or a part of the Asian active continental margin?

Precise timing of the India-Asia collision is important to constrain the evolution history of both the Himalayan orogen and the Tibetan Plateau. It has been proposed that the Indian plate first collided with an intra-oceanic arc at ∼55 Ma, and then the composite terrane collided with the Asian continent at ∼35 Ma. The Zedong terrane has been suggested to represent the vestige of such an intra-oceanic arc developed within the Neo-Tethys Ocean, as some volcanic rocks with high K₂O have been classified as shoshonites. In this study, we present detailed geochemical and geochronological data of various types of magmatic rocks (including volcanic, cumulate and granitic rocks) widely exposed in the Zedong terrane to constrain the formation age and tectonic setting of the Zedong terrane. We found that the Zedong volcanic rocks belong to calc-alkaline series rather than shoshonites and high K₂O contents in some volcanic rocks resulted from alteration. The basalts are highly enriched in LREE and LILE, but strongly depleted in HFSE, indicating they were derived from a metasomatized mantle. Presence of hornblende phenocryst in both gabbros and hornblendites indicates that the cumulates were produced from hydrous basalts through crystallization. The granitic rocks have adakite-like compositional characteristics, i.e., high Sr/Y ratios but low Y contents, which were formed by melting of a thickened lower crust. Zircons from six samples, including a volcanic rock (an andesite), three cumulates (a hornblendites, a hornblende-bearing gabbro and a gabbro) and two granitic (a tonalite and a granodiorite) rocks, have been dated to yield identical ages of ∼155–160 Ma. This suggests that the volcanic eruption and plutonic emplacement were coevally developed in the Zedong terrane. Zircons from both the andesite and the cumulates have similar positive ε_Hf(t) values (∼+11.6 to +16.7), indicating they were stemmed from similarly depleted mantle sources. Meanwhile, zircons from the granitic rocks also have positive ε_Hf(t) values of ∼+12.6 to +15.2, implying their derivation from a juvenile lower crust. Therefore, we proposed that the basalts in the Zedong terrane were formed through partial melting of the mantle wedge metasomatized by slab-released fluids/melts. A part of hydrous basalts were underplated in the thickened lower crust beneath the Zedong terrane, which gave rise to the cumulate and granitic rocks. By comparison, magmatic rocks in the Zedong terrane show compositional similarities with the Jurassic rocks exposed in the Gangdese arc. This suggests that the Zedong terrane represents a slice of the active continental margin developed on the southern margin of the Lhasa terrane as a result of the northward subduction of the Neo-Tethys Ocean during the Late Jurassic, rather than the vestige of an intra-oceanic arc.     

松潘—甘孜造山带容须卡岩浆-穹隆地质特征及构造演化

位于松潘—甘孜造山带雅江穹隆群北东部的容须卡岩浆底辟穹隆区,经历了多期构造演化,内部构造极其复杂。为厘清容须卡地区岩浆与穹隆的演化关系,通过野外地质调查及室内综合研究,探讨了容须卡穹隆的地质特征及构造演化。该穹隆中心发育无根或肠状褶皱,及“S”型、“Z”型褶皱和“A”型平卧褶皱; 穹隆外围发育叠加褶皱,反映造山带早期SN向和EW向收缩挤压。该穹隆主要经历了晚三叠世(印支末期)SN向与EW向的“双向挤压”作用; 成穹期岩浆向上侵位时限为(214.4±1.2) Ma; 成穹后经历了挤压推覆和应力松弛阶段; 早中新世(17~10 Ma),由于青藏高原东南缘快速抬升,松潘—甘孜造山带发育NW-SE向鲜水河左旋走滑断裂,使容须卡地区形成一系列NNW向韧脆性和脆性破碎带。