Kinetic simulation of hydrocarbon generation from lacustrine type I kerogen from the Songliao Basin: Model comparison and geological application

Eight lacustrine Type I kerogen samples from the Songliao Basin were pyrolyzed using the Rock-Eval equipment, and parallel first-order reaction models including the model with a single frequency factor and a discrete distribution of activation energies (SFF model) and the model with multiple frequency factors and a discrete distribution of activation energies (MFF model) were adopted to analyze kinetic characteristics of hydrocarbon generation of the Type I kerogen samples. The results show that the MFF and SFF models can satisfactory simulate hydrocarbon generation under laboratory conditions and the Type I kerogen shows relatively concentrated activation energy distributions (activation energies of MFF model range from 190 kJ/mol to 250 kJ/mol, activation energies of SFF model range from 220 kJ/mol to 240 kJ/mol), which indicates a homogeneous chemical bond structure of the Type I kerogen. The hydrocarbon generated curves from Type I kerogen were calculated by using the two models with a linear heating rate (3.3 K/Ma). It indicates that the hydrocarbon generation potentials (reaction fractions) are underestimated by using the SFF model during the kerogen thermal degradation for the components with chemical bond of lower and higher activation energies, while this problem can be avoided by using the MFF model. The calculated temperatures for 50% transformation ratio (TR) of all samples differ by as much as 20 °C. For the SFF model, the hydrocarbon generation curve obtained by using the weighted averaged kinetic parameters and the SFF model almost includes every curve calculated by using its own kinetic parameters. While the curve obtained by using the weighted averaged kinetic parameters and the MFF model cannot include every curve for all samples, it lies at the position of the averaged curve of all samples. The application of the MFF model in Songliao Basin shows that if TR 10% is taken as the onset of hydrocarbon generation, the threshold depth of hydrocarbon generation is about 1700 m, which is consistent with other geochemical parameters, such as S₁/TOC, S₁/(S₁ + S₂) and HC/TOC.     

地形、气候与湖面波动对浅水三角洲沉积环境的控制作用——以松辽盆地北部东区葡萄花油层为例

松辽盆地北部东区葡萄花油层沉积时期,基底整体一致下降,气候干旱,地形平缓,河流入湖发育浅水三角洲。三角洲平原上的分流河道通过填积和湖面的频繁波动向湖泊中心方向长距离推进,在三角洲前缘的浅水区发育很有特色的水下分流河道,发育了宽展的三角洲前缘相沉积。在平面上,三角洲平原与宽展的三角洲前缘、前三角洲平缓相接,不存在Gilbert型三角洲模式的顶积层、前积层、底积层三褶结构。     

城市化进程中平原河网地区河流结构特征及其分类方法探讨

平原河网地区河流结构发育受到自然条件和城市化的双重影响。依据遥感解译数据,围绕城市化水平、河流形态、河流结构和河流调蓄功能四个维度,就建成区面积比例、河流长宽分布、河系分维、河流调蓄能力等具体指标,分析了城市化水平和土地利用特征不同区域的河流空间形态、结构特征和功能状态,探讨了城市化进程中平原河网地区河流结构的可能演化轨迹,尝试建立了城市化影响下平原河网地区河流结构分类方法,提出了城市河流综合整治过程中应充分重视保护自然河流结构,注重发挥河流综合功能等观点。     

松辽盆地南缘基性岩脉中捕获锆石U-Pb年龄及其对基底岩浆事件的制约

团山子基性脉岩为松辽盆地南缘晚中生代最后一期岩浆活动,在其中获得了较多的捕获锆石。为了反映松辽盆地基底岩浆活动事件,对基性脉岩中捕获锆石进行了锆石LA-ICP-MS U-Pb定年。捕获锆石阴极发光(CL)图像和Th/U比值显示具有岩浆成因的特点。从锆石定年结果得到8组年龄,反映出早侏罗世晚期(176Ma)、海西期(291Ma)、加里东期(467Ma)、新元古代(942Ma)、中元古代(1368Ma)、古元古代(1886Ma和2165Ma)、新太古代(2458Ma)岩浆事件记录。松辽盆地南部基底组成以古生代和早中生代岩浆岩为主,并可能存在西保安群前寒武纪结晶基底(942Ma),并经历了复杂的岩浆演化。中元古代、古元古代、新太古代年龄的锆石具有磨圆和反应边,可能为与华北克拉通岩浆事件形成的锆石被搬运到松辽盆地南部,并被再次捕获的结果,反映松辽盆地南部与华北大陆具有一定的联系,但不确定存在该期的结晶基底。     

From foredeep to orogenic wedge-top: The Cretaceous Songliao retroforeland basin,China

Songliao Basin, the largest Mesozoic intracontinental nonmarine basin in eastern China, initiated during the latest Jurassic as a backarc extensional basin; rifting failed and thermal cooling controlled subsidence through the early Late Cretaceous. Integrating 2-D and 3D reflection seismic and borehole data with regional geological studies, we interpret sedimentary sequence and structural patterns of the Coniacian-Maastrichtian fill of Songliao Basin as defining a retroforeland basin system developed after 88 Ma (marked by the T11 unconformity in the basin), including (1) significant increase in the thickness of the Nenjiang Formation eastward towards orogenic highlands of the Zhangguangcai Range and the convergent continental margin; (2) a shift of detrital provenance in the basin from north to southeast; and (3) propagation of E-W shortened structures, increasing eastward in amplitude, frequency, and degree of inversion toward the orogen. During latest Cretaceous, foreland basin fill progressively deformed, as the foredeep evolved to a wedge-top tectonic setting, marked by the basin-wide T04 unconformity within the upper Nenjiang Formation at 81.6 Ma. Much of the basin was brought into the orogenic wedge and eroded by the end of the Cretaceous. Late Jurassic/Early Cretaceous backarc rifting of uncratonized basement comprised of accreted terranes likely facilitated and localized the foreland. Synrift normal faults reactivated and extensively inverted as thrust faults are prominent in the eastern 1/3 of the basin, whereas folds developed above detachments in shaley early post-rift strata dominate the western 2/3 of the basin. Songliao foreland development likely was driven by changing plate dynamics and collision along the Pacific margin after 88 Ma.     

松辽盆地北部上二叠统林西组地球化学特征及地质意义

为探讨松辽盆地北部林西组地球化学特征、沉积环境及构造背景,对该区黑富地1井所钻遇的上二叠统林西组暗色泥质板岩进行主量元素、微量元素和稀土元素测试分析,结果表明：样品主量元素平均质量分数SiO₂为65.05%、Al₂O₃为17.23%、CaO为2.58%、Na₂O为2.84%、K₂O为3.29%,K₂O/Na₂O值为0.20~3.48,A1₂O₃/（CaO+Na₂O）值为0.41~8.01;稀土元素w（∑REE）值介于80.68×10^-6~215.59×10^-6之间,平均值为173.41×10^-6,δEu值介于0.61~0.88之间,平均值为0.70,表现为Eu的负异常,δCe值介于0.91×10^-6~1.01×10^-6之间,为微弱的Ce负异常,LREE富集,HREE亏损;微量元素以亏损Nb、Ta、Sr,相对富集Rb、Ba、La、Ce、Pb、Nd、Sm为特征。样品元素分析和物源w（TiO₂）-w（Ni）、La/Th-w（Hf）等判别图解表明,林西组沉积物源具有多样性,主要来源于上地壳长英质物源,还有少量来自中、基性岩火成岩物源区。样品微量元素标准化蛛网图,稀土元素球粒陨石标准化配分模式图,K₂O/Na₂O-w（SiO₂）、Th-Co-Zr/10、F₂-F₁构造背景判别图及地球化学参数对比结果表明,松辽盆地北部林西组物源构造背景主要为活动大陆边缘和大陆岛弧,可能形成于靠近大陆岛弧的活动大陆边缘构造背景。林西组应形成于海陆过渡相到陆相环境,水体由半咸水逐渐转变为淡水。     

海拉尔盆地乌尔逊凹陷与松辽盆地孤店CO2气田含片钠铝石砂岩的岩石学特征

海拉尔盆地乌尔逊凹陷南屯组与松辽盆地孤店CO₂气田泉头组发育大量含片钠铝石砂岩。通过偏光显微镜、扫描电镜、茜素红-S染色、X射线衍射、电子探针与INCA能谱分析等,对含片钠铝石砂岩的骨架碎屑组分、胶结物与自生矿物、成岩共生序列等岩石学特征进行了系统研究。研究表明,含片钠铝石砂岩的岩石类型为长石砂岩和岩屑长石砂岩,粒度以细粒、细-中粒为主,分选差-中等。砂岩中胶结物主要为次生加大石英、自生石英、片钠铝石、铁白云石和粘土矿物。其中,片钠铝石最高可达砂岩总体积的22％在砂岩中或以放射状、束状、菊花状、杂乱毛发状、毛球状、板状等集合体充填孔隙,或呈束状和板状交代长石和岩屑。电子探针与INCA能谱综合分析表明,片钠铝石主要由Na、Al、O、C等组成。在含片钠铝石砂岩中,成岩共生序列依次为粘土矿物包壳-次生加大石英、自生石英、自生高岭石-油气充注-CO₂充注-片钠铝石-铁白云石。其中,CO₂注入前形成的自生矿物组合主要为次生加大石英、自生石英和自生高岭石,CO₂注入后形成的自生矿物组合主要为片钠铝石和铁白云石。     

Syn-rift to post-rift tectonic transition and drainage reorganization in continental rifting basins: Detrital zircon analysis from the Songliao Basin,NE China

Tectonic transition from a syn-rift stage to subsequent post-rift stage is an important mechanism in the evolution of extensional basins. The sedimentary infill records the crustal response to this process. We have obtained new detrital zircon U-Pb and Lu-Hf signatures from the Lower Cretaceous stratigraphic successions encompassing the commonly accepted syn- to post-rift transition boundary, the T4 unconformity, in the Songliao Basin, NE China. These constrain the Songliao Basin’s evolution from its center to distal margins, providing insights into the sediment provenance and dispersal pattern over the tectonic transition. Analysis of zircons from the syn-rift (the Shahezi and Yingcheng formations) and immediate post-rift (the Lower and Middle Denglouku Formation) stages reveals Phanerozoic age populations with positive ?_Hf(t) values, which were derived from the proximal juvenile mantle-derived melt origin bedrocks of the Songliao Block. In contrast, the overlying samples from the Upper Denglouku Formation deposited in the subsequent post-rift stage contain exotic and ancient zircon populations with ages of 2.5 Ga & 1.8 Ga and complex hafnium signatures, characteristic of a mixed origin. These are interpreted to be transported from distant cratonic terranes via larger drainage networks. It is obvious that the sediment dispersal pattern switched from being a local and hydrologically closed “intraregional” pattern to a “transcontinental” pattern during the transition. The time lag between the development of the T4 unconformity and the drainage reorganization also ensures a distinguishable ～3 Myr (106103 Ma, Late Albian) transition period of regional extent. During this transition stage, syn-rift faulting was replaced by post-rift thermal subsidence, exhibiting a uniform sag configuration. Our new findings are important for understanding other continental rift basins during syn- to post-rift transition, which often demonstrates a complex interaction between the linkage and integration of sub-basins, and the reorganization of fluvial drainages and catchment systems.     

天绘一号卫星影像的平原绿化提取方法

平原绿化是我国平原地区森林植被的主体,为生态环境建设提供了有力保障。但平原绿化分布零散,斑块面积小,不易被准确提取。本文以河南省封丘县为例,利用天绘一号卫星影像面向对象分类技术提取了平原绿化。在面向对象分类过程中,针对不同平原绿化信息选取不同的分割尺度和参数,建立影像对象的分割层次结构,确保农田林网、通道防护林、四旁防护林等平原绿化信息能够被准确分割。分类时通过构建隶属度函数,利用层与层之间的关系,子类继承父类的分类特征,在此基础上增加自己的特征,建立分类规则集,逐层提取绿化信息。本文共获取封丘县平原绿化面积152.51 km²,其中,农田林网36.09 km²,通道防护林21.29 km²,四旁防护林71.56 km²,片林23.57 km²。利用验证点数据,对分类结果进行精度评价,总体分类精度为93.50%,Kappa系数达到0.92。     

蒲江—新津—成都—德阳断裂带——成都平原内一条代表性弱活动地震带的地震地质特征

活断层是地震的潜在策源地。然而不同的活断层上地震潜在能力有极大的差别。客观地评价活断层上地震潜在能力不仅是地震预报研究的需要,对国民经济建设的布局和抗震决策也极为重要。在这个意义上,对弱活动性断裂的研究与对强活动性断裂的研究具有同样的重要性。本文以弱活动的蒲江—新津—成都—德阳断裂带为例,讨论了该断裂的晚第四纪活动性,断裂带的地质结构以及断裂的切割深度等因素对该断裂带地震潜在能力的可能影响。