Diagenesis and reservoir quality of sandstones with ancient “deep” incursion of meteoric freshwater——An example in the Nanpu Sag,Bohai Bay Basin,East China

An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (T_h) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high T_h (95∼115 °C) of AFI and low δ¹⁸O_(SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ¹⁸O_(SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds.     

毛乌素沙地西南缘灌丛沙丘沉积物的粒度和元素特征

对毛乌素沙地白刺(Nitraria tangutorum)灌丛沙丘沉积物粒度和元素特征进行了采样分析.结果表明:灌丛沙丘沉积物来源单一,几乎全部由丘间地物质组成,其粒度和元素特征与丘间地物质极其相似;相对而言,灌丛沙丘沉积物比丘间地物质含有更多粗颗粒物,主要因丘间地可做跃移运动的中沙和细沙更易被灌丛阻挡而堆积;灌丛沙丘沉积物中大部分元素含量比丘间地物质低,主要因这些元素易被淋溶迁移到丘间地富集;灌丛沙丘发育以来,虽然其沉积环境存在波动,但相对稳定,未发生过显著变化.     

永安地震台数字地震观测系统常见故障的分析及排除

论述了永安地震台数字地震观测系统的组成单元及各单元的作用与功能,总结、分析日常观测中常见的各类故障,并详细分析仪器运行过程中典型故障的产生原因及排除方法,可为其他相关地震台站提供借鉴。     

新04号泉溶解气氢气异常特征分析

选取乌鲁木齐周围100 km范围内MS4地震和300 km范围内MS≥5地震,分析新04号泉氢气资料。结果显示,新04号泉对乌鲁木齐周围100 km范围内4级地震无明显震兆异常,对300 km范围内MS≥5地震对应情况较好,对应率为80%。     

堆浸生产中高锑金矿样品金的测定

堆浸生产中,高锑金矿样品采用氢醌容量法测金,锑对测定有严重的正干扰,采用氯化铵培烧除锑或溴化氢挥发除锑,可消除锑对金的干扰,该方法快速、简单,效果明显。     

塔里木河下游地区滴灌沙枣防护林地土壤盐分分布特征

为了研究不同滴灌措施对极端干旱区防护林土壤盐分的淋洗作用,以沙枣（Elaeagnus angustifolia）防护林作为研究对象,对塔里木河下游喀拉米吉绿洲沙枣防护林开展了灌溉与不灌溉、不同滴头距离、不同滴灌年限处理的试验。结果表明：①不灌溉林地土壤盐分含量与流动沙丘相似,流动沙丘土壤盐分分布的空间异质性大于不灌溉林地。滴灌林地土壤含盐量低于不灌溉林地。②1.5 m滴头距离处理与其他处理相比压盐碱效果显著（P<0.01）。1.5 m与3 m滴头距离处理在50 cm土体中含盐量差异达极显著水平（P<0.01）,前者比流动沙丘低30.5%～32.7%、后者比流动沙丘高17.1%～13.3%。与3 m滴头距离处理相比,1.5 m滴头距离处理产生水盐运移的“互作”影响,盐峰下移。③滴灌后的第1、2、3年,林地的土壤盐分分别下降至30 cm、50 cm和70 cm以下,基本对沙枣根系生长没有影响。随着滴灌次数增加,根系生物量逐渐增大,根系附近土壤盐分逐渐减少。滴灌能使防护林的根系分布上移,大部分在10～65 cm土层内,土层越深,林木的根系越少。④灌水季节末期,不同林龄的防护林在120 cm土体的含盐量表现为：1 a林＞2 a林＞6 a林,说明滴灌对林龄大的防护林淋洗效果更为明显;非灌溉季节里,防护林的林龄越大,其土壤盐分表聚现象越明显。     

模拟不同气候条件下碳酸盐岩风化作用的淋溶实验研究

通过模拟干热、湿热与干冷3种气候条件,以饱和CO2水作为淋溶液,对黔中岩溶区3条碳酸盐岩风化壳岩-土界面的岩粉层试样进行了淋溶实验(其中干热、湿热条件下淋溶到残余酸不溶物阶段),对淋出液的pH值以及主要造岩元素的浓度进行了动态分析。结果表明,碳酸盐岩风化壳岩-土界面由岩到土的转变过程中,伴随碳酸盐的溶蚀,酸不溶物已表现出明显的风化倾向。碳酸盐的溶蚀强度表现为干冷>干热>湿热的变化趋势。温度低,碳酸盐的溶解速率大;排水条件好,碳酸盐溶解释放的Ca、Mg易随风化流体排出体系。对于酸不溶物组分,淋溶实验中有:(1)K、Na、Mg、Si、P的载体矿物风化强度在干热条件下最大(至于Ca,由于方解石与白云石均是其主要的载体矿物,酸不溶物相中的Ca难以在淋出液中有效识别)。在干冷与湿热之间,K、Na、Mg等盐基离子的溶出能力大多表现为湿热>干冷,指示了温度对盐基离子释放强度的重要制约作用;而Si和P未表现出一致的变化趋势,可能源于淋溶体系微环境的差异。(2)Fe与Mn表现出弱迁移性。其中,Fe在干冷环境下淋出强度最弱,说明温度是制约含Fe矿物分解速率的重要因素。而Fe在干热与湿热之间,以及Mn在3种淋溶条件下,未呈现出一致的变化趋势。(3)Al和Ti在碳酸盐岩风化过程中表现出强烈的惰性。      

野外电位溶出法测铜新探索

溶液中加入氧化剂（高锰酸钾）,氧化电极表面的金属铜形成铜离子进入溶液中,金属氧化溶出时间与溶液中的金属离子的浓度成正比,峰值与溶出时间成正比,因此峰高与溶液中金属离子浓度成正比,以此测定溶液中铜离子的浓度。     

基于空三模型实现非接触式实测地质剖面解决方案研究

本文提出的"基于空三模型实现非接触式实测地质剖面解决方案",是通过导出空间三维模型剖面多段线三维坐标,使用自主开发的辅助软件,在AutoCAD中快捷生成剖面图。通过实践,该方案能快速完成无需人工到实地进行实测的实测剖面工作,尤其危岩体勘查中能精确反映高陡崖区微地貌起伏形态和结构面特征,解决了人工实测无法完成的工作。     

陈家岭钒矿选矿工艺试验

采用钙法氧化焙烧——酸浸的方法从钒矿石中浸出钒,克服了钠化焙烧过程中产生的H2S、Cl2,实验了矿石物料粒度、氧化钙添加量、焙烧温度、焙烧时间、漫出温度、浸出时间、酸的浓度、浸出液固比对浸出率的影响,获得了88％的浸出率。实验表明,焙烧温度、酸的浓度、浸出温度、浸出时间、液固比是影响钒浸出率的重要因素。