Effect of widespread severely acidic soils on spatial features and abundance of trace elements in streams

In the coastal area of western Finland, a large number of streams are strongly acidic and contaminated with metals. The reason for this is not historical and present industrial, mining and urban activities, but a current high rate of weathering and leaching of widespread acid sulphate soils (pH 2.5–4.0) developed in artificially drained Holocene marine and lacustrine sulphide-bearing sediments. Evaluation of existing hydro- and geochemical field and experimental data revealed that: (1) cobalt, Ni and Zn are extensively leached from the acid sulphate soils and thus exist abundantly in streams affected by such soils, (2) copper and Tl are also leached abundantly from the acid sulphate soils, although not to the same extent as are Co, Ni and Zn, (3) vanadium is in general depleted and Cr only weakly enriched in streams draining ‘the average acid sulphate soil’, but they increase substantially in severely acidic streams in catchments underlain with particularly acidic soil, (4) arsenic and Pb are not leached more abundantly from the acid sulphate soils than from the common types of soils and sediments (till, glaciofluvial deposits, peat) resulting in aquatic abundance and distribution patterns unrelated to the acid sulphate soil occurrences.     

512可地浸砂岩型铀矿床地质特征和远景评价

本文介绍了５１２矿床区域地质背景、矿床基本特征、近期勘探成果、地浸效果和矿区远景评价。该矿床的成矿条件有利，属层间氧化带砂岩型，有可能发展成可地浸的、低品位的万吨级矿床，其矿田远景将更为可观。     

基于AHP-熵-TOPSIS对极轨气象卫星应用系统健康程度评价指标体系

以实现对极轨气象卫星应用系统健康程度进行综合评价为目的,提出结合主观分析的层次分析法(Analytic Hierarchy Process,AHP)和客观分析的熵权法(Entropy Weight,EW)确定待评价系统指标值的综合权重,再采用逼近理想解排序法(Technique for Order Preference by Similarity to an Ideal Solution,TOPSIS)对系统的指标进行多角度评价排序来作为最终评价结果。本文根据连续5个月3颗极轨气象卫星在实际业务系统运行中异常指标样本进行实证分析。结果表明该方法较为全面考虑了影响应用系统的多种因素,避免了单一判据的局限性,并对各指标的重要性进行综合对比分析,使得评价结果更科学准确,可以作为构建极轨气象卫星应用系统健康程度评价指标体系的一种方法。     

多组份电解质溶液热力学——活度系数和渗透系数与高次极限定律的关联

自1973年Pitzer电解质溶液理论问世以来,它在海洋学、地球科学、生物学乃至化工中获得了广泛的应用。本文介绍在实际应用中有重要意义的高次极限定律及与活度系数、渗透系数间的关联,它们是Pitzer理论发展的重要组成部份。     

山西省热矿水形成机制分析

本文以系统理论为指导，在深入研究地质北景的基础上，通过研究热矿水的含水介质，水动力场，水化学物和温度场的特征，划分了热矿水系统，探讨了热矿水的起源及形成机制，将山西热矿水的形成归纳为异常增温型和正常增温型两种基本模式，异常增温型又根据地质结构的不同，地下水径流条件的差异，列举了三种典型模式，最后指出了寻找热矿水的方向，开发利用热矿资源应注意的问题。     

北方地区酸雨对地下水硬度形成的影响机制分析

由酸雨对包气带土样的淋滤试验和浸泡试验资料表明，在岩－水相互作用的初期，硬度主要来自土中易溶盐的溶解和Ｈ￣＋、Ｎａ￣＋对上颗粒表面Ｃａ￣（２＋）、Ｍｇ￣（２＋）、Ｆｅ￣（２＋）等的交换；在后期，硬度主要来自土中碳酸盐、铝硅酸盐的风化水解。酸雨中的酸度与土壤溶液中的碱度的中和过程，即是水中硬度的形成过程；酸雨的ｐＨ值越低，在相同作用时间内形成的硬度值越高。是硬度组分自土中迁出的主要载体；岩水作用的时间越长，硬度值也越高。     

Experimental Study on the Leaching of Gold from Greenstone1

Abstract Experiments were conducted on the leaching of gold from greenstone by chloride solution under the temperature of 200-550°C and the pressure of 60 MPa. During part of the experiments, the oxygen fugacity was controlled. The results show that the leaching rate of gold is related to temperature, composition of the solution, pH and oxygen fugacity. In the experiment with oxidative acidic solution, the leaching rate was up to 50% or more. It is known that the leaching of gold is restricted by the reaction in which the gold is dissolved from the rock to form gold chloride complex. Therefore, the authors hold that the acidic chloride solution derived from granite magma has caused the remobilization-migration of gold from greenstone and its enrichment into ore.     

Limestone solution rates and processes in the Waitomo District,New Zealand

Karst solution processes are investigated on Oligocene limestones in the Waitomo district, west central North Island, New Zealand. Estimates of the inputs, throughputs and outputs of water and dissolved calcium and magnesium in two drainage basins were used to establish the rate of limestone solution by autogenic waters. The best estimate for solution loss from the basins during the study year is 69 m³/km². The potential measurement errors inherent in each parameter used in the erosion rate computations were assessed and the probable maximum and minimum erosion rates were estimated to be 88 and 61 m³/km². In both basins approximately 67 per cent of the annual solute load is transported by flows greater than the mean annual discharge, over 15 per cent being transported by flood flows that are exceeded only 5 per cent of the time. Almost half of the annual load is transported during the three winter months (June-August), but no one month accounts for more than 18 per cent or less than 2.7 per cent of the annual total. Approximately 37 per cent of solution takes place within the soil profile, and most of the remainder is concentrated in 5–10 m of weathered bedrock (the subcutaneous zone) beneath this. Thus, it is likely that at least 85 per cent of the total solutional erosion contributes to the surface lowering of soil and bedrock.     

紫金山铜矿原地破碎细菌浸出工艺的可行性分析

根据紫金山铜矿的实际情况，分析采用原地破碎细菌浸出工艺回收紫金山铜矿资源的工程技术可行性，在此基础上进行经济方面的讨论。     

地浸采铀矿山地下水污染碱性中和清洗法治理研究

地浸采矿方法可引起地下水环境的严重污染，文章对地下水污染过程及治理机理进行了阐明，针对地浸铀矿山的污染特点，提出了碱性中和清洗治理方法的设想，并对碱性中和清洗法治理地浸铀矿山的地下水环境污染的方法及治理效果进行了实验研究，采用水文地球化学模式PHREEQC1．6来模拟计算中和清洗液的最佳pH值，提出了对现场清洗治理具有重要意义的一个重要指标——清洗比，实验结果表明，碱性中和清洗法对治理地浸矿山的地下水污染治理效果明显．为我国地浸矿山地下水污染治理工作的开展进行了探索性研究。