Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.     

Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.     

湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据

为了查明湘中盆地中-低温梯（金）矿床的成矿物质来源，文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定，并结合作者以往分析数据和实验地球化学结果，对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明：Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量，在近似成矿条件下的水/岩反应实验中，成矿元素的淋出率达20%～90%，元古界基底碎屑岩中的金（锑、钨）矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床（化）及其蚀变围岩中；湘中锑（金）矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征，以上微量元素地球化学特征充分证明该区锑（金）矿床锑、金等成矿物质主要来源于元古界底碎屑岩。     

上扬子台地晚震旦世灯影组中葡萄状-雪花状白云岩的成因意义

葡萄状 -雪花状白云岩是白云岩形成之后经淡水淋滤作用而成 ,葡萄内或雪花周围的有机物质不是原生藻 ,而是蓝绿藻经细菌腐解后形成的细菌集合体。该套白云岩的形成与沉积环境关系密切 ,与藻类多少无关。葡萄状白云岩富含有机物质 ,而雪花状白云岩孔洞发育 ,因此葡萄状 -雪花状白云岩既是生油层 ,又是良好的储集层 ,对其重新认识和定位 ,必将为寻找深部油气资源提供极为重要场所     

Experimental Study on Mine Spoils During Superficial Geochemistry Processes

Based on the mineral and chemical compositions of spoils taken from the Shilu Cu-Mo deposit and Hetai gold deposit, the leaching and batch experiments were made on spoils taken from these two deposits using the leaching column designed by the authors. The experimental results showed that it is not always true that the mine drainage is acidic. Its acidity depends on acid-buffering capacity of gangue, host rock and its alteration mineral assemblage. The composition of the drainage water is related with the interaction between superficial or underground water and solid materials in the spoils, including minerals, hydroxides and amorphous substances. The leaching extent of the element is related with its occurrence form in the deposit. The preferential flow results in leaching-out of heavy metals in large amounts. So it is important to prevent the generating of preferential flow in the system. The results will provide very important grounds for the comprehensive management of land and ecological rehabilitation of the mine site.     

模拟酸雨对福建四种山地土壤的淋溶与风化作用

在不同pH值 (2 .0、3.5、5 .0、6 .0及蒸馏水 )的模拟酸雨作用下 ,对福建四种类型山地土壤进行了为期 12 0d的淋溶试验。结果表明 ,盐基离子的淋溶量随模拟酸雨pH值的降低而增加 ,尤其当pH≤ 3.5时 ,增加最明显。 4种类型土壤中各离子淋失量大小均为 :Ca2 >Mg2 >K >Na ,这与原土壤中交换性盐基含量一致。在pH≥ 3.5的酸雨作用下 ,土壤中铝的淋失较少 ,而当酸雨pH =2 .0时 ,铝的淋失骤然升高。pH2 .0的模拟酸雨不仅增加了土壤铝离子的释放 ,而且加速了矿物的风化。在pH2 .0的模拟酸雨淋溶下 ,红壤、黄壤、山地草甸土和紫色土中由矿物风化输入的 5种阳离子总量分别为 2 .94、4 .33、4 .35和 6 .0 4 (cmol kg)土 ,显著大于其它酸雨处理。土壤对酸沉降的缓冲作用由阳离子交换、氢氧化铝水解以及原生矿物风化缓冲作用三部分组成 ,其相对重要性不仅决定于土壤酸度、盐基饱和度和矿物组成 ,而且与酸雨的pH值密切相关     

不同浓度Li2SO4水溶液结构的X射线衍射研究

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。     

细菌浸铜技术在紫金山铜矿的应用

介绍了生物浸矿技术在紫金山铜矿的应用及在这一过程中发现的一些问题，并提出了有待进一步解决的一些问题。     

萃淋树脂吸附法测金

对萃淋树脂在酸性介质中吸附解脱金及相关体系的条件选择，以及萃淋树脂在生产方面的应用前景进行了实验研究。结果表明，萃淋树脂在稀王水介质中能较好地吸附金，用硫脲解脱金简便完全，检测限达0．002μg／g，吸附率达100％，解脱率99．8％。     

溶液结构的X射线衍射研究──4.用粉末衍射仪精确测定溶液结构的新方法

本文叙述了用θ—2θ型X射线衍射仪精确测定电解质溶液结构的新的实验技术，设计制作了具有恒温功能的超厚液体样品池，并建立了样品池窗口强度的校正方法。建立在Johansson和Yamaguchi工作基础上，发展了液体X射线衍射数据处理和结构参数精细化的计算机程序，获得了非常令人满意的实验结果。由θ－2θ型X射线衍射仪精确测定的径向分布函数与θ－θ型衍射自由表面散射比较，表明DRF分辩率有所提高。