基于混合聚类的岩体结构面优势分组方法

提出一种基于凝聚层次法和模糊C均值法的混合聚类法,用于对岩体结构面的优势组划分。该方法将结构面投放到在单位球面上,并使用欧式距离作为极点的相似性度量准则。先剔除结构面数据中的孤值产状,然后用凝聚层次法得到初步聚类结果,并将其作为FCM法的初始聚类中心,最后用FCM法划分优势组。通对人工生成产状样本的分组,验证了该法的正确性。将该方法应用于大藤峡坝址区实测的结构面数据的划分。在实测数据中寻找到两个孤值产状,成功将大藤峡D1y^1-3地层岩体结构面划分为两组,得到了符合实际的分组结果。     

三峡库区龙门寨危岩体崩塌产生涌浪研究

长江两岸高耸的危岩体对航道、沿岸居民带来巨大安全隐患。大宁河属于长江一级支流,龙门寨危岩体位于大宁河上,距离巫山县城仅1 km。利用FLOW-3D软件,模拟了145 m、175 m两种水位工况下龙门寨危岩体崩塌产生涌浪过程和涌浪传播过程。模拟结果表明,涌浪在145 m水位工况下最大浪高约为17.9 m,175 m水位工况下最大浪高约为11.6 m;在巫山县的五个码头处,两种水位工况最大涌浪爬高分别约为10.9 m、3.8 m;根据涌浪高度,对大宁河进行危险分区,145 m水位工况下极高危险区长度约4.4 km,很高危险区长度约1.9 km;175 m水位工况下极高危险区长度约3.0 km,很高危险区长度约1.0 km。研究结果有助于防控龙门寨危岩体潜在涌浪灾害危害,保障大宁河航道和巫山县码头安全,同时也为三峡库区滑坡涌浪灾害提供了预警依据。      

Middle Permian organic carbon isotope stratigraphy and the origin of the Kamura Event

Large carbon cycle perturbations associated with the Middle Permian (Capitanian) mass extinction have been widely reported, but their causes and timing are still in dispute. Low resolution carbon isotope records prior to this event also limit the construction of a Middle Permian chemostratigraphic framework and global or local stratigraphic correlation, and hence limit our understanding of carbon cycle and environmental changes. To investigate these issues, we analyzed the ¹³C_org values from the Middle Permian chert-mudstone sequence (Gufeng Formation) in the Lower Yangtze deep-water basin (South China) and compared them with published records to build a chemostratigraphic scheme and discuss the underlying environmental events. The records show increased δ¹³C_org values from late Kungurian to early Guadalupian, followed by a decrease to the late Wordian/early Capitanian. The early-mid Capitanian was characterized by elevated δ¹³C_org values suggesting the presence of the “Kamura Event”: an interval of heavy positive values seen in the δ¹³C_carb record. We propose that these heavy Capitanian δ¹³C values may be a response to a marked decline in chemical weathering rates on Pangea and associated reduction in carbonate burial, which we show using a biogeochemical model. The subsequent negative δ¹³C excursion seen in some carbonate records, especially in shallower-water sections (and in a muted expression in organic carbon) coincide with the Capitanian mass extinction may be caused by the input of isotopically-light carbon sourced from the terrestrial decomposition of organic matter.     

Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.     

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.     

Loading protocols for experimental seismic qualification of members in conventional and emerging steel frames

Quasi-static testing is one of the most commonly used experimental methods for examining the seismic performance of structural members. However, consistent loading protocols for experimental seismic qualification of members in emerging steel frames such as self-centering braced frames (SCBFs) as well as in some conventional ones including buckling-restrained braced frames (BRBFs) are still lacking. This paper aims to propose standardized loading protocols based on time-history dynamic analysis on a series of prototype building frames, including steel SCBFs, BRBFs, and moment-resisting frames (MRFs), where both far-field and near-fault earthquakes are considered. The methodology for the development of the loading protocols involves ground motion selection and scaling, design and analysis of prototype buildings, analysis results processing, and rainflow cycle counting, together with extra justification steps. The proposed loading protocols are consistently derived based on the MCE-level seismic hazard and 84^th percentile values of key seismic demand parameters. These parameters are number of damaging cycles N_t, maximum inter-story drift θ_max, inter-story drift range Δθ_i, sum of inter-story drift range ΣΔθ_i, and residual inter-story drift θ_r. The analysis confirms the variations in these seismic demands imposed on the different structural systems under different types of ground motions, highlighting the necessity of developing separate loading protocols for the different cases. The assumptions, decisions, and judgments made during the development of the loading protocols are elaborated, and the conditions and restrictions are outlined. The rationality of the proposed loading protocols is further justified through demonstrating the cumulative distribution function and energy dissipation demand of the systems.     

长江中下游典型浅水湖泊沉积物水界面磷与铁的耦合关系

目前普遍认为磷铁耦合关系是P迁移的主要机制,但大部分研究结果并未提供直接的原位证据.为了探索沉积物剖面磷(P)与铁(Fe)的耦合关系,利用Zr O-Chelex薄膜扩散梯度技术(ZrO-Chelex DGT),分别对太湖、巢湖、鄱阳湖和洞庭湖4个浅水湖泊沉积物有效态Fe和P进行高分辨采样和分析.结果表明,不同湖区有效态Fe和P浓度在沉积物-水界面处开始增加,之后波动变化,垂向异质性较强,但两者浓度变化同步.有效态P和Fe浓度的相关分析结果证明两者浓度具有显著的线性相关.室内厌氧培养实验进一步表明,Fe~(3+)的还原性促使Fe~(2+)与铁结合态磷的释放,促使DGT有效态P与Fe同步变化.该结果表明沉积物P的二次迁移和释放受Fe氧化还原过程的控制,为铁磷耦合关系提供了直接证据.     

球坐标系下三维大地电磁正演研究

大地电磁正演理论研究热点一直以来主要集中在如何提高计算效率和精度,但在剖面足够长、探测深度足够大的情况下,传统的笛卡尔坐标系数值模拟方式难以准确拟合地球曲率形态.本文研究了基于球坐标系的三维大地电磁正演,推导了交错网格有限差分三维正演公式,与一维解析解和三维标准模型测试对比,验证了正演算法的正确性.通过理论模型计算,对比分析球坐标和笛卡尔坐标系正演结果表明：球坐标系模拟更合理,避免了传统笛卡尔坐标拉伸投影所引入的误差,可代替目前的笛卡尔坐标模拟方法.基于球坐标和笛卡尔坐标系的三维大地电磁正演响应值随着频率变低差异越明显.球坐标和笛卡尔坐标计算结果差异度与频率、模型结构和电阻率有关.本文模型计算结果在数万秒周期处已出现接近10%的差异,对于较大尺度的长周期大地电磁,地球曲率的影响不能忽略.     

FluBiDi – a model to estimate flood based on runoff: validation using extreme and natural basin conditions

FluBiDi is a two-dimensional model created to simulate real events that can take days and months, as well as short events (minutes or hours) and inclusive laboratory tests. To verify the robustness of FluBiDi, it was tested using a previous study with both designed and real digital elevation models. The results highlight good agreement between the models (i.e. Mike Flood, SOBEK, ISIS 2D, and others) tested and FluBiDi (around 90% for a specific instant and 95% for the complete time simulation). In the simulated hydrographs, the discharge peak value, time to peak, and water level results were accurate, reproducing them with an error of less than 5%. The velocity differences observed in a couple of tests in FluBiDi were associated with very short periods of time (seconds). However, FluBiDi is highly accurate for simulating floods under real topographical conditions with differences of around 2 cm when water depth is around 150 cm. The average water depth and velocities are precise, and the model describes with high accuracy the pattern and extent of floods. FluBiDi has the capability to be adjusted to different types of events and only requires limited input data.