碱渣与粉煤灰拌合物的岩土工程及环境特性研究

碱渣是氨碱法生产纯碱时产生的工业废料,仅天津碱厂历年堆积的碱渣占地已达数平方公里。碱渣与其它材料（如粉煤灰等）拌和可制成工程土,代替一般工程土作为道路基础或大面积填垫材料的途经。对碱渣制工程土的化学成分,岩土工程性质和对环境的影响进行了研究,对碱渣土回填场地的地基承载能力和长期稳定性进行了测试。研究成果可以使这种工程土得到合理利用,从而减轻工业废料-碱渣的堆积和污染问题     

土石混合料剪切特性影响因素的离散元数值研究

土石混合料剪切特性控制着高填方边坡的稳定性。土石混合料特殊的结构、物质及粒径组成等极其复杂,为探究土石混合料剪切特性影响因素及其规律,在室内试验基础上,基于PFC2D构建了颗粒离散元数值模型,分析了颗粒级配、初始孔隙率、块石尺寸及块石形状等因素对土石混合料剪切特性的影响。结果表明:土石混合料的剪应力-剪切位移曲线主要包括4个阶段:弹性变形、局部剪切、剪切破坏以及残余变形;块石形状、颗粒级配及初始孔隙率对土石混合料的破坏模式无明显影响,破坏模式均为应变软化型;当土石混合料的颗粒级配较差时,剪应力随剪切位移的增加出现较大波动,曲线出现明显"跳跃"现象;当含石量一定时,相同法向应力条件下,块石尺寸越大,土石混合料的抗剪强度越大,且随着法向应力的增大,不同块石尺寸的试验组之间抗剪强度差值也越大,块石尺寸对土石混合料抗剪强度的影响越明显。     

模拟真实场景的混合像元分解

在总结混合像元分解方法的基础上, 提出了一种模拟真实场景的像元分解方法, 该方法首先通过真实场 景的模拟获得各分量的丰度, 结合遥感影像与场景模拟的丰度反演端元反射率(模拟端元), 最后用带约束条件的线 性模型进行混合像元分解。用浙江省安吉县毛竹林调查资料及Landsat TM 对该方法进行验证和对比分析表明, 基 于模拟端元的混合像元分解结果比基于影像端元和参考端元的精度高且具有良好的稳健性。模拟真实场景的混合 像元分解方法将样地调查数据的先验知识应用于端元提取, 并将三维模拟模型引入到二维的线性光谱分解中, 具 有一定的优势和应用推广前景。     

斜长石、辉石混合模型的电导率有限元数值计算研究

以岩石实验中矿物的几何形态及空间分布为建模依据,以实验条件及单矿物电导率的测量结果为约束条件,用有限元数值方法模拟了不同微观结构的斜长石、辉石混合物在施加电压后电势及电流的分布情况,并计算了混合模型在不同温度条件下的电导率.研究结果显示,数值模型网格数及矿物颗粒数的选取对电导率计算结果的精度有较大影响,在体导电情况下,模型电导率因矿物比例含量和排列结构而异.当斜长石及辉石随机分布时,随着辉石含量的增加,混合模型电导率在不同温度下均有所增加,且温度越高,增加幅度越大,电导率的有限元模拟计算结果接近于有效介质渗透理论模型,且位于并、串联模型之间以及HS模型的上、下边界范围内;在斜长石及辉石含量一定的情况下,各矿物的排列分布对电导率计算结果也有一定的影响,当矿物颗粒大小接近且分布均匀时,模型中电势沿电流传导方向变化较为均匀,模拟计算得出的电导率相对较高,当矿物颗粒大小差别较大及分布不均匀时,电势分布受到一定的扰动,电导率计算结果也较低.将混合模型电导率有限元计算结果与辉长岩、辉绿岩及玄武岩实验测量结果进行比较,显示这3种岩石样品电导率与温度变化关系的斜率均与混合模型计算结果的斜率相接近,表明这些岩石在所选温度段导电机制与斜长石、辉石混合模型相似,用斜长石、辉石混合模型的电导率研究玄武岩、辉长岩及辉绿岩的导电性具有适用性.将混合模型有限元计算结果与玄武岩、辉长岩、辉绿岩覆盖区地壳大地电磁实测结果对比,发现大地电磁电导率结果位于混合模型计算结果范围内,用斜长石、辉石混合模型模拟玄武岩、辉长岩等岩石地壳具有一定的可行性.     

遥感图像最大似然分类方法的EM改进算法

基于参数化密度分布模型的最大似然方法（MLC）是遥感影像分类最常用手段之一，与其他非参数方法（如神经网络）相比较，它具有清晰的参数解释能力、易于与先验知识融合和算法简单而易于实施等优点。但是由于遥感信息的统计分布具有高度的复杂性和随机性，当特征空间中类别的分布比较离散而导致不能服从预先假设的分布，或者样本的选取不具有代表性，往往得到的分类结果会偏离实际情况。首先介绍了用基于有限混合密度理论的期望最大（EM）算法来作为最大似然函数（MLC）参数估计的方法－EM－MLC。该模型首先假设总体混合密度分布可被分解为有限个参数化的高斯密度分布，然后把具有先验知识的样本与随机选取的未知样本混合在一起，通过EM迭代计算来估计出各密度分布的最大似然函数的参数集，从而一定程度上避免了参数估计可能出现的偏离。最后，本文提出了基于EM－MLC遥感影像分类的具体实施流程和应用示范，并与一般最大似然方法（MLC）得到的分类结果进行了定性和定量的综合比较，认为EM－MLC在精度上得到了提高。     

Modelling of internal erosion based on mixture theory: General framework and a case study of soil suffusion

A general thermo-hydro-mechanical framework for the modelling of internal erosion is proposed based on the theory of mixtures applied to two-phase porous media. The erodible soil is partitioned in two phases: one solid phase and one fluid phase. The solid phase is composed of nonerodible grains and erodible particles. The fluid phase is composed of water and fluidized particles. Within the fluid phase, species diffuse. Across phases, species transfer. The modelling of internal erosion is contributed directly by mass transfer from the solid phase towards the fluid phase. The constitutive relations governing the thermomechanical behaviour, generalised diffusion, and transfer are structured by the dissipation inequality. The particular case of soil suffusion is investigated with a focus on constitutive laws. A new constitutive law for suffusion is constructed based on thermodynamic conditions and experimental investigations. This erosion law is linearly related to the power of seepage flow and to the erosion resistance index. Owing to its simplicity, this law tackles the overall trend of the suffusion process and permits the formulation of an analytical solution. This new model is then applied to simulate laboratory experiments, by both analytical and numerical methods. The comparison shows that the newly developed model, which is theoretically consistent, can reproduce correctly the overall trend of the cumulated eroded mass when the permeability evolution is small. In addition, the results are provided for four different materials, two different specimen sizes, and various hydraulic loading paths to demonstrate the applicability of the new proposed law.     

Numerical modelling of internal erosion during hydrate dissociation based on multiphase mixture theory

It has been reported that sand production, which is a simultaneous production of soil particles along with gas and water into a production well, forced to terminate the operation during the world's first offshore methane production test from hydrate-bearing sediments in the Eastern Nankai Tough. The sand production is induced by internal erosion, which is the detachment and migration of soil particles from soil skeleton due to seepage flow. The inflow of the eroded soil particles into the production well leads to damage of the production devices. In the present study, a numerical model to predict the chemo-thermo-mechanically coupled behavior including internal erosion during hydrate dissociation has been formulated based on the multiphase mixture theory. In the proposed model, the internal erosion is expressed as mass transition of soil particles from soil skeleton to the fluidized soil particles. Since the internal erosion is considered to depend on the soil particle size, mass of soil particles are divided into several groups that have different representative particle diameters, and the constitutive equations for the onset condition and the mass transition rate of the internal erosion are formulated for each group. Also, transportation of soil particles in the liquid phase is formulated for each particle size group in the proposed model. Finally, a simulation of the methane gas production from the hydrate-bearing sediment by depressurization method is presented, and the internal erosion and the dissociation behavior are discussed.     

Quantification of the hydraulic diffusivity of a bentonite-sand mixture using the water head decrease measured upon sudden flow interruption

This paper presents a new modelling approach to quantify the hydraulic diffusivity of low-permeability unconsolidated porous media under confined saturated-flow conditions in the laboratory. The derived analytical solution for the transient variation of the hydraulic head after flow interruption was applied to experimental data obtained from continuous measurements of the water pressure at two locations in the soil column. Three soil samples made of a mixture of natural bentonite (at different mass fractions) and medium sand were studied during a series of stepwise constant flow rates of water. The numerical results well fit the experimentally measured decrease of the dimensionless hydraulic head. The study shows that the increase of the mass fraction of bentonite in the soil sample from 10 to 30% is accompanied by a strong decrease of the hydraulic diffusivity from 2.4 × 10⁻² to 1.1 × 10⁻³ m² s⁻¹, which is clearly due to the decrease of the hydraulic conductivity of the soil sample. The specific storages obtained for each of the three samples are in the same order of magnitude and seem to decrease with the increase of mass fraction of bentonite. However, they clearly reflect the predominant portion of the compressibility of the porous medium compared with that of water. Compared with reported literature values for clayey soils, the specific storage values in this study are slightly higher, varying within the range of 2 × 10⁻³ to 8.1 × 10⁻³ m⁻¹._. The experimental results also give insight into the limitations of the modelling approach. In the case of low-permeability soils (K < 2 × 10⁻⁶ ms⁻¹) and steady-flow conditions with low Reynolds numbers, for example, Re < 0.003, it is recommended to choose a time duration for flow interruption between subsequent flow rate steps of longer than 5 s. For high-permeability porous media, to increase the precision of the quantified hydraulic diffusivity, it might be useful to select a measuring frequency significantly higher than 1 Hz.     

海洋沉积物中氧化亚铁的分析测定

海洋沉积物试样用Ｈ２Ｏ２－ＨＡｃ浸取,用以除去干扰测定ＦｅＯ的锰化合物和硫化珠,并以Ｈ２ＳＯ３－Ｎａ２ＳＯ３混合溶液破坏过乘的Ｈ２Ｏ２,不需过滤分离,即可用ＨＦ－Ｈ２ＳＯ４分解试样,Ｋ２Ｃｒ２Ｏ７标准溶液滴定ＦｅＯ。方法经海洋沉积物国家标准物质分析验证,结果与参考值相符,ＲＳＤ为６．３３％。     

面向开采扰动的离子型稀土矿区地表温度降尺度方法

离子型稀土的开采活动会导致矿区地表极其剧烈的生态扰动,并且会造成当地的生态环境问题,而矿区地表热环境分异变化能较好地反映矿区的生态扰动特点,是一种辨识地表生态扰动的重要参数.离子型稀土矿区存在矿点分散且单个矿点面积较小的特征,因此获取实用性强且空间分辨率更高的地表温度数据对稀土矿区生态环境的监测具有重要价值.构建了一种...