重金属迁移转化模型研究

大量重金属污染物迁移转化的现象和研究成果都表明重金属以泥沙颗粒为载体迁移转化,描述重金属在天然水体中的迁移转化必须紧紧抓住泥沙颗粒运动及重金属与泥沙之间的转化关系进行.为此在对现有的重金属迁移转化数学模型进行概括分类的基础上,根据水沙运动与污染物相互作用关系,分析了泥沙颗粒运动及重金属吸附解吸不平衡过程,并结合水沙数学模型,建立了重金属迁移转化的耦合模型.同时在模型合理性分析的基础上,对模型进行了计算分析,分析表明模型能够合理地反映重金属污染物在水体中的迁移转化过程.     

Hydro-thermal performance of multilayer capillary barriers in arid lands

In this study, a capillary barrier system was designed and tested for an arid land environment. To simulate arid land conditions of high temperature and sub-irrigation systems, the barrier was subjected to thermal and hydraulic gradients in opposite directions; to test the barrier system under these severe conditions, an experimental apparatus was designed and fabricated. The multilayer capillary barrier consisted of three layers made of silica sand, a mixture of sand and bentonite in equal portions, and a mixture of clay (25%) and aggregate (75%). Several one dimensional coupled heat and moisture tests were performed. Temperature variations along the thickness of the barrier were recorded as a function of time, and at the end of each test, the barrier was sliced into small sections, for the determination of volumetric water content as a function of distance from the heat source. The experimental results were discussed in view of the barrier's intended purpose of its ability to store moisture for long time durations. Coupled heat and moisture flow equations were developed and solved numerically via a finite difference method. Diffusivity parameters were calculated by using experimental results, a numerical model, and Powell's conjugate directions method of nonlinear optimization. The model was calibrated and the results were discussed. Good agreement between calculated and experimental results was obtained. This revised version was published online in July 2006 with corrections to the Cover Date.     

Transport of dissolved methoxy-nonafluorobutane through a saturated column

Solute transport experiments were conducted in a one-dimensional saturated column using dissolved methoxy-nonafluorobutane (HFE-7100), a Novec engineered fluid developed by the 3M Corporation, as the solute. Novec engineered fluids are considered dense non-aqueous phase liquids (DNAPLs) because they are immiscible with water and have a specific gravity greater than one. The HFE-7100 fluid is safer and environmentally friendlier than common DNAPL contaminants such as tetrachloroethylene (PCE) or trichloroethylene (TCE); thus, it is an ideal substitute DNAPL for laboratory groundwater contamination research. Three sets of solute transport experiments were conducted. The first set of experiments was conducted in a glass-bead-packed column using dissolved HFE-7100 as the solute. The second set of experiments was conducted in a sand-packed column using dissolved HFE-7100 as the solute. The third set of experiments was conducted in a sand-packed column using dissolved PCE as the solute. The dissolved HFE-7100 column breakthrough concentrations were compared with dissolved PCE breakthrough concentrations. Results show that the one-dimensional solute transport equation was successful in describing the transport behavior of dissolved HFE-7100. This study demonstrates that the HFE-7100 fluid can be used as a safer substitute DNAPL for groundwater contaminant dissolution and transport research.     

Soil moisture potential and water content in the unsaturated zone within the arid Ejina Oasis in Northwest China

Three soil profiles were selected in the Ejina Oasis, northwest China, to determine water content profiles and evolution of soil moisture potentials in the unsaturated zone within the arid area. The total soil moisture potentials have been monitored for about 3 months in 2001 at different depths in the soil profiles. The occurrence and movement of water in the unsaturated zone was analyzed using the zero flux plane (ZFP) method. It is shown that convergent ZFPs and divergent ZFPs may occur at depths between 0.5 and 3.0 m, and that the depth of the ZFPs was controlled by the root zone of plants growing on the land surface. Profiles of the total soil moisture potentials were observed to be coincident with those of the water contents at the three experimental sites. The total soil moisture potential showed a slight increasing trend and the ZFPs tend to vanish from summer to winter as the water extraction by roots decreased. Evapotranspiration through vegetation has an important bearing on the water content and the total potential in the unsaturated zone.     

Effects of temperature and humidity upon the transport of sedimentary particles by wind

Wind tunnel simulations of aeolian transport carried out over a range in mean temperature between 32 °C and ?9 °C suggest that cold airflows support higher mass transport rates (Q) than very warm air. The magnitude of this increase is larger than expected, so that analytical and semi‐empirical models underestimate Q. Extrapolation of the results suggests that, at ?40 °C, as for example in the dry valleys of Antarctica in winter, Q may be as much as 70% higher than for the equivalent wind speed in hot deserts at air temperatures of 40 °C. Temperature‐dependent changes in air density and turbulence contribute to this result. The decreased tension of water adsorbed onto particle surfaces at low temperatures is postulated to reduce interparticle cohesion and, thus, to increase the elasticity of particle impacts on cold beds. Definition of the roles that temperature and humidity play in aeolian transport is relevant to studies of palaeoenvironmental reconstruction and extraterrestrial (or planetary) geology. Investigation of present‐day, cold climate features and of climate change effects also requires knowledge of these fundamental relations.     

Nuclear Waste Disposal Simulations: Couplex Test Cases

We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods.     

深层水泥土搅拦桩在软土地基处理中的应用

通过对深层水泥土搅拌桩的加固机理及复合地基承载力性状的简要分析,根据国家现行规范,结合具体地基处理工程实例,对深层水泥搅拌桩在软土地区地基加固处理中的方案选择、设计、施工及检测中的常见技术要点作初步探讨。     

Modélisation du transport réactif en milieux poreux non saturés avec une méthode ELLAM en maillage variable

Modelling contaminant transfer with biological/chemical/radioactive processes needs appropriate numerical methods able to reproduce sharp concentration fronts. In this work, we develop a new Eulerian–Lagrangian Localized Adjoint Method (ELLAM) for solving the reactive transport equation with non-constant coefficients. To avoid interpolation (leading to errors), we use a moving grid to define the solution and test functions. The method is used to simulate first the infiltration of solute into a column of unsaturated porous medium and second the multispecies transport. The developed ELLAM gives accurate results without non-physical oscillations or numerical diffusion, even when using large time steps. To cite this article: A. Younes, C. R. Geoscience 336 (2004).     

Vegetation dynamics during the late Pleistocene in the Barreirinhas region, Maranhão State, northeastern Brazil, based on carbon isotopes in soil organic matter

The study place is in the Barreirinhas region, Maranhão State, northeastern Brazil. A vegetation transect of 78 km was studied among four vegetation types: Restinga (coastal vegetation), Cerrado (woody savanna), Cerradão (dense woody savanna), and Forest, as well as three forested sites around Lagoa do Caçó, located approximately 10 km of the transect. Soil profiles in this transect were sampled for δ¹³C analysis, as well as buried charcoal fragments were used for ¹⁴C dating. The data interpretation indicated that approximately between 15,000 and ∼9000 ¹⁴C yr B.P., arboreal vegetation prevailed in the whole transect, probably due to the presence of a humid climate. Approximately between ∼9000 and 4000-3000 ¹⁴C yr B.P., there was the expansion of the savanna, probably related to the presence of drier climate. From ∼4000-3000 ¹⁴C yr B.P. to the present, the results indicated an increase in the arboreal density in the area, due to the return to a more humid and probably similar climate to the present. The presence of buried charcoal fragments in several soil depths suggested the occurrence of palaeofires during the Holocene. The vegetation dynamic inferred in this study for northeastern Brazil is in agreement with the results obtained in areas of Amazon region, based on pollen analysis of lake sediments and carbon isotope analysis of soil organic matter (SOM), implying than similar climatic conditions have affected these areas during the late Pleistocene until the present.     

茯苓种植用材代用品

比较攀西地区茯苓种植用材代用1品(简称新配方2)生长的茯苓的菌核、菌丝与商品茯苓的显微特征及多糖成分的含量差异。分别提取茯苓水溶性及碱溶性多糖,酚-硫酸法测定茯苓多糖的含量。结果表明:新配方2 生长的茯苓的菌核、菌丝与商品茯苓的显微特征相似,多糖含量相近,但提取率有较大差异。与商品茯苓比较,新配方2生长的茯苓菌核多糖提取率基本一致,菌丝的多糖提取率约低1/4。由于新配方2生长的茯苓菌丝培育成本远低于商品茯苓,提高了栽培茯苓的经济效益。可以考虑将茯苓菌丝作为茯苓替代品入药。