膜分离技术的应用及发展趋势

综述世界和中国膜分离技术的发展，并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍；并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用，并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素，膜分离技术将在人类社会的发展史上起到不可替代的作用。     

Semi-analytical solutions of a contaminant transport equation with nonlinear sorption in 1D

A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).     

Compressibility and swelling characteristics of Al-Khobar Palygorskite, eastern Saudi Arabia

Expansive soils are found in different locations in eastern Saudi Arabia. The area is arid with high temperatures, highly variable humidity and an excessive rate of evaporation compared to the low precipitation. This resulted in the formation of water sensitive soils. In the present investigation, line valve buildings for a sweet water feeder (1118 mm in diameter) were constructed on a highly expansive material consisting mainly of brown palygorskite and gray palygorskite with thin sheets of gypsum and limestone. Block samples from both palygorskites were brought to the laboratory and cores as well as remolded samples were obtained from the blocks. The two palygorskites were found to be highly plastic and have a very high swelling potential. The liquid limit (LL) and plastic limit (PL) values for the brown palygorskite are 261% and 140%, respectively. The gray palygorskite has a LL of a 285% and a PL of 123%. The oedometer free swell tests for the two palygorskites produced an expansion ranging between 31.8% and 42.5% for the remolded samples. However, the expansion for cores ranges between 8.3% and 19.3%. The constant volume pressure tests produced a stress in excess of 4240 kPa. The swell potential reached a steady state after four days while the swelling pressure reached a steady state in about 3 h. The paper addresses the geology of the area, the characterization of the geomaterial including mineralogical composition using X-ray diffraction and SEM techniques and the swelling characteristics of the material.     

Effect of polypropylene fibre and lime admixture on engineering properties of clayey soil

In order to reduce the brittleness of soil stabilized by lime only, a recent study of a newly proposed mixture of polypropylene fibre and lime for ground improvement is described and reported in the paper. To investigate and understand the influence of the mixture of polypropylene fibre and lime on the engineering properties of a clayey soil, nine groups of treated soil specimens were prepared and tested at three different percentages of fibre content (i.e. 0.05%, 0.15%, 0.25% by weight of the parent soil) and three different percentages of lime (i.e. 2%, 5%, 8% by weight of the parent soil). These treated specimens were subjected to unconfined compression, direct shear, swelling and shrinkage tests. Through scanning electron microscopy (SEM) analysis of the specimens after shearing, the improving mechanisms of polypropylene fibre and lime in the soil were discussed and the observed test results were explained. It was found that fibre content, lime content and curing duration had significant influence on the engineering properties of the fibre–lime treated soil. An increase in lime content resulted in an initial increase followed by a slight decrease in unconfined compressive strength, cohesion and angle of internal friction of the clayey soil. On the other hand, an increase in lime content led to a reduction of swelling and shrinkage potential. However, an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. An increase in curing duration improved the unconfined compressive strength and shear strength parameters of the stabilized soil significantly. Based on the SEM analysis, it was found that the presence of fibre contributed to physical interaction between fibre and soil whereas the use of lime produced chemical reaction between lime and soil and changed soil fabric significantly.     

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.     

Threshold velocity for wind erosion: the effects of porous fences

Porous fence is a kind of artificial windbreak that has many practical applications. The threshold wind velocities at different distances downwind from porous fences were measured and the corresponding characteristics of particle movement observed to assess their shelter effect. It is found that the fence’s porosity is the key factor that determines the resulting shelter effect. The area near a fence can be typically classified into five regions, each with a different mode of particle movement. Dense fences, and especially solid fences, favor the accumulation of sand upwind of the fences. Fences with porosities of 0.3–0.4 produce the maximum threshold wind velocity; those with porosities of 0.3–0.6 (depending on the fence height) provide the maximum effective shelter distance. It is confirmed that the fence porosities of 0.3–0.4 that have been proposed for practical application in previous research are the most effective for abating wind erosion.     

Risk assessment of groundwater pollution using sensitivity analysis and a worst-case scenario analysis

This paper illustrates how sensitivity analysis and a worst-case scenario analysis can be useful tools in risk assessment of groundwater pollution. The approach is applied to a study area in Hungary with several known groundwater pollution sources and nearby drinking water production wells. The main concern is whether the contamination sources threaten the drinking water wells of the area. A groundwater flow and transport model is set up to answer this question. Due to limited data availability, the results of this model are associated with large uncertainty. Sensitivity analysis and a worst-case scenario analysis are applied to estimate this uncertainty and build confidence in the model results.     

Short-term beach–dune sand budgets on the north sea coast of France: Sand supply from shoreface to dunes, and the role of wind and fetch

Three experimental plots, covering the transition from the upper beach to the dune, on the North Sea coast of France were monitored at various intervals over a period of 18–24 months via high resolution terrain surveys in order to determine inter-site sand budget variability, as well as patterns and processes involved in sand exchanges between the upper beach and dune. The wind regime consists of a fairly balanced mix of moderate (80% of winds are below 8 m/s) onshore, offshore and shore-parallel winds. Sustained dune accretion over several years depends on the periodic local onshore welding of shoreface tidal banks that have developed in the storm- and tide-dominated setting of the southern North Sea. The only site where this has occurred in the recent past is Calais, where bank welding has created a wide accreting upper beach sand flat. At this site, significant sand supply from the subtidal sand bank reservoir to the upper beach flat occurred only once over the 18-month survey following a major storm. The bulk of the sand deposited over this large flat is not directly integrated into the adjacent embryo dunes by onshore winds but is progressively reworked in situ into developing dunes or transported alongshore by the balanced wind regime, thus resulting in alongshore stretching of the embryo dune system. The Leffrinckoucke site near Belgium shows moderate beach–dune mobility and accretion, while the Wissant site exhibits significant upper beach bedform mobility controlled by strong longshore currents that result in large beach budget fluctuations with little net budget change, to the detriment of the adjacent dunes. Accretion at these two sites, which are representative of the rest of the North Sea coast of France, is presently constrained by the absence of a shore-attached sand bank supply reservoir, while upper beach–dune sand exchanges are further limited by the narrow wave-affected upper beach, the intertidal morphology of bars and troughs which segments the aeolian fetch, and the moderate wind energy conditions. The balanced wind regime limits net sand mobilisation in favour of either the beach or the dune, and may explain the relatively narrow longshore morphology of the dune ridges bounding this coast.