鄂尔多斯盆地CO2地质封存适宜性与潜力评价

针对目前利用层次分析法对CO₂地质封存进行适宜性评价过程中,极少结合研究区域实际计算低层次评价指标权重,对适宜性评价结果又缺少进一步的分析,结合鄂尔多斯盆地的地质特征,通过计算指标组成权重和适宜性得分对盆地开展了CO₂地质封存适宜性评价,并以适宜区杏子川油田长4+5盖层为例,开展了盖层封闭性评价实验研究。同时,采用相应的计算方法对鄂尔多斯盆地深部咸水层和油藏的CO₂地质封存潜力进行了计算。结果表明：鄂尔多斯盆地在三叠系开展CO₂地质封存的适宜性最好,石炭-二叠系和奥陶系则次之;杏子川油田三叠系延长组长4+5盖层对区域开展CO₂地质封存具备良好的封闭性;鄂尔多斯盆地深部咸水层和油藏的CO₂有效封存量分别为1.33×10 ¹⁰ t和1.91×10 ⁹ t,且在延长石油吴起、靖边及杏子川油田共有56个CO₂地质封存适宜区,其CO₂有效封存量可达1.77×10 ⁸ t。     

硫酸参与的长江流域岩石化学风化速率与大气CO2消耗

流域的岩石化学风化过程是全球碳循环中的重要环节。以往的流域水化学碳汇通量估算大多是基于碳酸的风化作用。而实际上,硫酸和碳酸一样,也参与了流域碳元素的地球化学循环,从而对全球碳循环过程产生影响。长江流域水体近几年出现酸化现象,大部分河段SO42-和Ca2+含量增高,其对应的岩石风化过程和大气CO2消耗速率也发生变化。文章对长江干流及主要支流2013年不同季节的离子组成进行监测,利用水化学平衡法和Galy估算模型,对长江流域岩石化学风化速率和CO2消耗通量进行了估算,对硫酸参与下的长江流域岩石风化和碳循环过程进行了分析。结果表明,长江流域水体离子主要来源于硅酸盐岩风化和碳酸盐岩风化。其中碳酸盐岩风化对河水离子贡献率为92%。在硅酸盐岩广泛分布的赣江流域,碳酸盐岩风化离子贡献也达85%。分析表明,硫酸参与了长江流域的岩石风化过程,对水体中离子产生一定影响。硫酸的参与加快了碳酸盐岩的化学风化速率,平均提高约30%,但是使流域大气CO2消耗速率降低。在不考虑蒸发岩溶蚀作用下,平均从516×103 mol/km2·a降至356×103 mol/km2·a,降低约31%。在各支流中,硫酸对乌江流域碳酸盐岩的风化和碳循环的影响最大,而对雅砻江的影响最小,这与乌江流域的含煤地层、矿床硫化物及大气酸沉降有关。     

Hazardous Heavy Metal Distribution in Dahuofang Catchment,Fushun, Liaoning,an Important Industry City in China: A Case Study

Located in Liaoning Province, one of the traditional heavy industrial areas in China, Dahuofang Reservoir provides drinking water for nearly 30 000 000 citizens, as well as industrial and agricultural water for dozens of several cities and rural areas. The distribution of hazardous heavy metals is described in several types of soil, crops, and in different industrial or mining areas and main sewage irrigation areas. Five possible reasons that may cause the pollution are analyzed and listed. Also we provide some pragmatic suggestions for the remediation of heavy metals in contaminated soils.     

ICP-MS测定土壤中的As、Cr、Pb、Se、Cu和Zn

本文用电感耦合等离子质谱法(ICP-MS)测定了土壤的As、Cr、Pb、Se、Cu和Zn6种微量元素的质量分数,以In作为内标进行基体效应的补偿,方法快速灵敏,回收率为92.4%～106.8%,相对标准偏差小于5.0%,结果达到国家标准要求。     

低渗透油藏CO2驱油开发方式与应用

CO₂驱是一种能大幅度提高原油采收率的三次采油技术,国内该项技术的研究和应用起步较晚,多以先导试验为主。苏北盆地溱潼凹陷经过10余年的探索,已经在5个低渗油田开展了CO₂驱先导试验和推广应用,针对这5个油藏利用一维细管模拟和油藏数值模拟方法开展了注气时机、段塞尺寸和注气部位的研究,并应用典型实例进行了分析,认为先期注入提高混相压力,可更有效地缩短两相区过渡带,增加油相中溶解的CO₂含量,降低油相粘度和油气界面张力,进而提高混相程度,更有利于驱油;采用大尺寸段塞可加大CO₂波及区域,较好地保持地层能量,从而提高油井见效率,增强驱替效果;高部位注气可有效地抑制重力超覆,减少CO₂气体过早地产出和突破的机会。就苏北盆地低渗油藏而言,采用先期注入、大尺寸段塞和高部位注气不失为一种成熟有效的提高采收率方法。     

河南省土壤湿度年变化规律

利用河南省土壤墒情预报模型中建立的河南省台站土壤墒情数据库资料，对不同类型土壤湿度进行分析，从而确定不同类型土壤湿度差异、地下水对土壤湿度的影响及河南省土壤湿度的年变化规律。     

Root structure,distribution and biomass in five multipurpose tree species of Western Himalayas

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The tree root distribution pattern and biomass of seventeen year old trees of Grewia optiva, Morus alba, Celtis australis, Bauhinia variegata and Robinia pseudoacacia were studied by excavation method. B. variegata roots penetrated to a maximum depth of 4.78 m, whereas, M. alba roots were found down to 1.48 m depth. Lateral spread was minimum in B. variegata （1.10 m）and maximum inR. pseudoacacia （7.33 m）. Maximum root biomass of 6.30 kg was found in R. pseudoacacia and minimum （2.43 kg） was found in M. alba. For four species viz.,G. optiva, M. alba, C. australis andR. pseudoacacia, 68%-87% root biomass occurred within top 0-30 cm soil depth, but forB. variegata this was only45%. The soil binding factor was maximum in G. optiva and minimum in B. variegata. Soil physico-chemical properties also showed wide variation. The study suggests thatB. variegata with a deep root system is the most suitable species for plantation under agroforestry systems. R. pseudoacacia and G. optiva with deep root systems, more lateral spread and high soil binding factor are suitable for plantation on degraded lands for soil conservation.     

The Energy Relationship between Ions and Soil Particles based on Wien Effect and Its Application in Soil Science

The interaction between ions and soil particles plays an important role in the mobilization and bioavailability of ions in soils, which is one of the main research areas of soil chemistry. The new method based on suspension Wien effect has been developed recently to determine the binding energy and adsorption energy between ions and soil particles. Compared with other methods on the basis of adsorption isotherm or ions activity, Wien effect method has more advantages including convenience and direct measurement. The term suspension Wien effect refers to the increase of electrical conductivity of suspension with increasing applied electrical field. In this review paper, we introduced the fundamentals of suspension Wien effect, the apparatus about the Wien effect measurement, and along with demonstrating their application to quantifying the particles-ions interactions for several systems of soils. Our studies indicated that divalent cations have larger binding energies and adsorption energies on soil particles than monovalent because of the electrostatic interaction. However, few studies about the interaction between Cr³⁺ and La³⁺ on soil particles showed that the binding energy and adsorption energy of trivalent cations are lower than those of divalent cations because of hydrolysis. Soil properties such as soil organic matter, soil pH, and iron oxides significantly affected the binding energy and adsorption energy of ions. Our results deepened our understanding about the non specific adsorption of ions in soil chemistry, and enlarged the research area of soil chemistry in fundamental and methodology.     

二维海陆风环流的数值研究

本文对Nickerson的中尺度模式作了一些修改,加入了地表热量平衡方程和一个13层的土壤层模式,并对Therry等的行星边界层参数化形式作了调整.使之较好地模拟出太阳辐射和地表温度的日变化.对不同地形、纬度和夏、冬季海陆风的模拟表明,本模式具有较强的海陆风模拟能力.     

地震作用下锚固边坡稳定性数值分析

地震诱发的边坡失稳是一种重要的地震地质灾害类型,本文结合工程实例,利用有限差分软件FLAC3D 建立了一个边坡的数值分析模型。对比分析了静力状态下锚固前后边坡的塑性区、水平位移和滑移面,地震作用下锚固前后边坡的塑性区、各个时刻的水平位移、锚杆轴力分布和塑性状态,然后分析了边坡的稳定性,并探讨了边坡破坏的机理。数值分析结果表明:锚杆对边坡的加固效果十分显著; 锚杆在发挥锚固作用时主要受拉,且随着锚杆位置高程的增加,锚杆的轴力减小; 有无锚杆支护的边坡在地震作用下的破坏方式不同。研究结果为锚固边坡的抗震设计提供了参考依据。