The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks

The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion pressure during the high evolution stage. Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”.     

铝对铬成矿地球化学的依存性和对抗性

基于岩浆铬矿床与超镁铁质岩石的关系，从元素亲合性和共生规律的角度揭示了铝对铬成矿制约的主导作用，分析了铝和铬亲石、亲氧的二重性及其晶体化学的依存关系。论证了超镁铁Ｓｉ－Ｏ体系中铝丰度过高或过低均不利于铬的成矿。揭示了制约元素分散富集的因素都是在一定条件下互为依存和转化的，是在动态中的矛盾的对立和统一。     

生物礁岩分类方案

本文系统地提出了一个生物礁岩分类的新方案。生物礁岩首先根据次生组分的有无分为原生礁岩和次生礁岩。次生礁岩根据次生组分来源分为骨源次生礁岩和礁源次生礁岩。次生礁岩的二级分类根据次生组分的含量进行。骨源次生礁岩分为骨屑岩和含骨屑礁（灰）岩、倒骨央和含倒骨礁（灰）岩；礁源次生礁岩分为礁屑岩和含礁屑礁（灰）岩。骨屑岩根据次生组分的粒度分为巨骨砾（屑灰）岩、骨砾（屑灰）岩、细骨砾（屑灰）岩、骨砂（屑灰）岩；     

福建沙县地区早白垩世火山岩成因及构造环境分析

本文着重阐述了沙县地区早白垩世火山岩地球化学特征，论证了中性与酸性火山岩的成因及物质来源，认为二者为不同源岩浆演化的产物，其岩浆物质来源于壳幔混源区，为省内双峰式火两端员岩石间成因关系的分析研究提供了新的例征。     

太白维山中生代火山岩特征及其与成矿的关系

晋北太白维山火山岩属钾质碱性玄武岩系列,产于板块内部活化带,来源于上地幔或下部地壳,被上部地壳物质混染,为壳幔源型或同熔型火山岩.火山岩与Ag(Pb、Zn)矿化关系密切,是成矿热液和矿质的主要来源之一.     

藏南特提斯喜马拉雅带中段二叠纪-白垩纪的火山活动(Ⅰ):分布特点及其意义

在野外实地考察和追索的基础上，详细厘定了特提斯喜马拉雅带中段晚古生代以来火山岩的分布特点和迁移规律。结果表明，在特提斯喜马拉雅带中段晚古生代以来的地层系统中，从二叠纪→三叠纪→侏罗纪→白垩纪，共有11个层位含规模不等的火山岩，它们以透镜体、薄夹层或以块状玄武岩、玄武质安山岩等形式产出于不同地层系统中；从二叠纪→早中三叠世→晚三叠世→侏罗纪和白垩纪，具有由西向东、从南→北→南→北的迁移规律。这些火山活动的发现和厘定，对填补特提斯喜马拉雅带火山岩研究的空白，了解陆下岩石圈地幔和软流圈地幔之间的相互作用和新特提斯洋盆的形成演化都具有一定的指示意义。     

辽西地区中侏罗世海房沟组火山岩地球化学特征及其地质意义

辽西地区中侏罗世海房沟组火山岩的岩石共生组合为粗安岩粗面岩安山岩英安岩 ,属于高钾钙碱性钙碱性火山岩系 ,全岩Rb_Sr等时线年龄为 177.2± 2 8.0Ma。岩石总体上反映出高Al高Na特点 ,SiO2 ≥ 5 6 .99% ,Al2 O3 ≥ 15 .4 5 % ,Na2 O/K2 O≥ 1.35。稀土元素分馏明显 ,(La/Yb) N≥ 14 .80 ,(Ho/Yb) N≥ 1.15 ,贫Yb、Y(Yb≤ 1.4 2× 10 -6,Y≤ 15 .18× 10 -6) ,基本无Eu负异常 (0 .86～ 1.0 3) ,明显亏损Rb、Nb、Zr、Ti,而Sr、Ba、K及LREE富集 ,Rb/Sr值均小于 0 .1,地球化学特征与埃达克岩十分类似 ,属埃达克质岩。Sr、Pb和Nd同位素资料反映出这套火山岩的源岩较深 ,可能为古老的下地壳中基性变质岩部分熔融产物。研究表明 :海房沟组火山岩形成于板内环境 ,与太平洋板块俯冲没有直接关系 ;辽西地区中生代构造应力场的重大转换、广泛的岩浆活动和大规模断陷盆地群的形成与岩石圈拆沉作用密切相关。海房沟组埃达克质岩的确认对探讨辽西地区火山岩浆起源、壳幔相互作用及大陆动力学背景具有重要意义。     

内蒙古镁铁质-超镁铁质岩型铜镍矿床成矿条件与找矿远景分析

按构造环境控岩控矿特点,划分区内铜镍型矿成矿(岩)带,分析成矿条件,研究了与该类矿床成矿有关的镁铁质岩、超镁铁质岩分布规律及铜镍硫化物成矿特征,提出了找矿方向和建议.     

扬子地台西南缘传统型铂族矿产地质特征

传统型铂族矿产，系指与镁铁质岩浆成矿作用有关的铂族矿产资源。华力西运动时期，扬子地台西南缘沿超壳深断裂带发生的大陆裂谷作用，为来自上地幔的镁铁质(拉斑玄武岩质)岩浆的上涌和侵位提供了极为有利的前提条件。含铂基性超基性岩的时空分布，受到大陆裂谷作用的主要发生发展时期和裂谷活动带的控制。通过对典型矿床特征及其成矿作用的探讨，论述了扬子地台西南缘主要的铂族矿床类型；并从四维成矿的角度，阐述了对区域成矿规律的一些基本认识。     

New geochemical data from the Nigerian sector of the Chad basin: implications on hydrocarbon prospectivity

Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and T_max indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output.