湖南金船塘矿区矽卡岩矿物及Sn元素在绿帘石中的分布特征

金船塘矿区位于千里山花岗岩岩体西侧, 与东侧柿竹园矿区均是湖南柿竹园特大型W-Sn-Mo-Bi矿床目前正在开采的重要矿区.该矿区块状矽卡岩的矿物特点是: 石榴子石以钙铝石榴子石为主, 辉石存在透辉石-钙铁辉石连续系列, 长石以钙长石大量产出为特点, 硅灰石出现了不常见的锰铁硅灰石; 绿帘石中普遍含Sn, SnO₂含量0.2%~2%.根据绿帘石中Sn元素的详细测定和计算, 查明Sn元素在绿帘石中含量与在矿物中位置具幂律函数关系, 计算的分形维为1.93, 从矿物微观的尺度确认Sn等成矿元素在运移和分布上具分形时-空结构, 从而证实自组织的临界状态是柿竹园特大型多金属矿床动力学的基本特点.      

Composition and formation of Mercury: Constraints from future electrical conductivity measurements

Among the terrestrial planets, Mercury's composition is characterized by two specific features: a high density and a low surface FeO content. Based on these two constraints, different geochemical models have been proposed, according to different formation scenarios. Here thermodynamical modeling is used to derive the mantle and crust mineralogy associated with these geochemical models. For each mineralogy, the electrical conductivity profile and associated electromagnetic data are computed. Due to the very different oxide/silicate ratios, most geochemical models proposed for Mercury's formation show very different electromagnetic signatures. As a result, future measurements with MESSENGER and BepiColombo missions will help differentiating between different interior models and different formation scenarios.     

普洱西盟五类锡矿特征及找矿前景

西盟锡矿群是云南锡矿主产区,存在五类锡矿床：“面型”云英岩型,大理岩型,矽卡岩型,断裂破碎带型及层间破碎带型。深入了解其不同成因空间、成矿规律、岩矿组合、赋矿条件,并结合隐伏花岗岩体特征,十分有利扩大找矿远景。     

电感耦合等离子体发射光谱法测定铅锑合金中锑砷铋锡锌铁

探讨了用电感耦合等离子体发射光谱法对铅锑合金中锑、砷、铋、锡、锌和铁元素分析的基本条件,确定了合适的谱线和背景校正方法,基本解决了基体干扰和待测元素之间的干扰。建立的方法用于铅锑合金成分的分析,方法检出限为锑0.02 mg/g、砷0.03 mg/g、铋0.03 mg/g、锡0.02 mg/g、锌0.002 mg/g、铁0.002 mg/g,相对标准偏差(RSD,n=12)2%,加标回收率为95.5%~105.0%。方法快速简捷,准确度高。     

100MPa、850℃和800℃条件下锡在流体与富磷过铝质熔体相间分配的实验研究

利用江西宜春414岩体中的钠长石花岗岩作为实验初始物,制备含不同1〉20s含量（0．27％－7．71％）的实验玻璃,本次实验研究了100MPa、850℃和800℃条件下Sn在流体与富磷过铝质熔体相间的分配。实验结果显示,Sn在流体与熔体相间的分配系数（Dsofluid/mclt）变化于2．10×10^-4－1．36×10^3之间,指示Sn强烈趋向于在富磷过铝质熔体中富集。随体系中P2Os含量从0．27％增至1．91％,Sn在流体与熔体相间的分配系数逐渐增加,当体系中R2O5含量进一步增加时,Sn在两相间的分配系数呈降低的趋势。本次实验结果表明,P可能不是Sn以流体相形式进行搬运的主要络合剂。     

湖南骑田岭花岗岩与锡成矿的关系

骑田岭花岗岩是燕山早期深源浅成的高钾钙碱性复式花岗岩岩体.最晚的细粒花岗岩Rb-Sr等时线年龄为(151±5) Ma,低温蚀变和矿化的时代约为136 Ma.锡矿化分布于外接触带矽卡岩和岩体内部隐爆角砾岩充填的断裂中,细粒花岗岩岩浆作用与蚀变和矿化作用在空间上紧密伴生,成因上密切相关.骑田岭花岗岩具有花岗岩岩浆作用与矿化作用密切相关的直接证据--岩浆-热液过渡阶段典型的地质地球化学特征:①结构构造变化大,出现许多不平衡的结构构造,如斑状结构、蠕虫结构、连续不等粒结构、文象结构、花斑结构、细晶结构、环带结构、伟晶岩壳和晶洞构造;②石英中含有熔体包裹体和熔体-流体包裹体,并与CO2流体包裹体和高盐度流体包裹体共存;③蚀变广泛,特别是存在高温自交代蚀变钠长石化和条纹长石的微斜长石化.这种高温蚀变的花岗岩具有四重效应,表现出惰性元素的活动性,w(K)/w(Rb)、w(Sr)/w(Eu)、w(Y)/w(Ho)和w(Zr)/w(Hf)等值大大偏离球粒陨石中的值.这些特征反映了富挥发分的晚期花岗岩岩浆由于高位减压"过冷"及淬火从而导致挥发分出溶、顶盖沿构造薄弱带隐爆垮塌以及出溶流体与正在结晶的花岗岩间的流-岩相互作用.岩体冷却及其高热产率驱动长期的热液循环,形成广泛的蚀变和成矿作用.     

云南西盟锡矿阿莫矿段控矿条件

锡矿体产于蚀变片岩中,矿床形成严格受有利地层岩性、构造和蚀变等地质条件的控制,矿床应属岩浆期后气成高温热液矿床。     

华南地球化学走廊带碎屑沉积岩W、Sn时空分布特征及其指示意义

通过系统的高密度采样,选取了470件来自华南走廊带的细粒碎屑沉积岩,涵盖了中元古到白垩系地层,对其主要元素、微量元素、稀土元素进行了精确分析。研究结果显示,所有样品都存在明显的稀土元素的分异和Eu的负异常,其中(La/Yb)N=10.0,Eu/Eu*=0.67。相对上地壳平均组成,样品明显亏损Ca、Na和Sr,并具有较高的化学风化指数,暗示样品受到了较为强烈的风化作用影响,并且经历了长距离的搬运过程;主要元素和微量元素图解暗示样品的源岩可能包括花岗质、安山质和长英质岩石。样品的地球化学特征显示,样品可以代表较大的源区,并且W、Sn的含量可以反映走廊带上W、Sn分布特征。在走廊带上,W、Sn的含量自东南向西北递减,在江山—绍兴断裂带附近突变,该分布特征与华南地区的钨锡成矿作用非常吻合。碎屑沉积岩中W、Sn的含量明显高于上地壳平均含量,其中W、Sn含量的峰值存在于中元古代—奥陶系地层,而华夏地块从中元古代开始便具有高钨锡含量,可能是该地区形成全世界最大的钨锡成矿省的重要原因。     

Tin-bearing minerals at the Furong tin deposit,South China: Implications for tin mineralization

It remains poorly constrained whether remobilization of Sn from granites and prograde skarns plays an essential role in forming economic (skarn-type) tin mineralization. Using both electron probe microanalysis and laser ablation–inductively coupled plasma–mass spectrometry methods, in-situ Sn contents, as well as major elements, were analyzed for numerous silicates and magnetite from fresh granite, altered granite, and skarn at the large Furong Sn deposit (530,000 t Sn @ 0.8% Sn) in the Nanling Range, South China. Hornblende and biotite in fresh granite are the main Sn-bearing phases (Sn = 44–321 ppm), while plagioclase and K-feldspar are poor in Sn (< 5 ppm). In altered granite, tin is hosted mainly by hydrothermal muscovite (299–583 ppm) replacing plagioclase, but rarely by chlorite (mostly <10 ppm) replacing hornblende and biotite. In contrast, most silicates (garnet, diopside, vesuvianite, pargasite and epidote) and magnetite from tin skarn are Sn-rich (47–44,241 ppm), except for Sn-poor phlogopite and scapolite (< 10 ppm). In particular, garnet, pargasite, and epidote reach tin concentrations in the percent range. Tin generally enters the stannous silicates and magnetite through substitutions for octahedral Al^vi and Fe³⁺. Comparisons of Sn contents between magmatic and hydrothermal minerals in granite, prograde and retrograde minerals related to tin skarn indicate that remobilization of Sn from granite and prograde skarn is not a pre-requisite to form tin mineralization.     

First-principles Study on Equilibrium Sn Isotope Fractionations in Hydrothermal Fluids

Tin (Sn) isotope geochemistry has great potential in tracing geological processes. However, lack of equilibrium Sn isotope fractionation factors of various Sn species limits the development of Sn isotope geochemistry. Equilibrium Sn isotope fractionation factors (124Sn/116Sn and 122Sn/116Sn) among various Sn(II, IV) complexes in aqueous solution were calculated using first-principles calculations. The results show that the oxidation states and the change of Sn(II, IV) species in hydrothermal fluids are the main factors leading to tin isotope fractionation in hydrothermal systems. For the Sn(IV) complexes, Sn isotope fractionation factors depend on the number of H2O molecules. For the Sn(II) complexes, the Sn isotope fractionation between Sn(II)?F, Sn(II)?Cl and Sn(II)?OH complexes is mainly affected by the bond length and the coordination number of anion, whereas the difference in 1000lnβ values of Sn(II)?SO4 and Sn(II)?CO3 complexes is insignificant with the change of anion coordination number. By comparing the 1000lnβ values of all Sn(II, IV) complexes, the enrichment trend in heavy Sn isotopes is Sn(IV) complexes > Sn(II) complexes. The equilibrium Sn isotopic fractionation factors enhance our understanding of the tin transportation and enrichment processes in hydrothermal systems.