High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

The 17 March 2005 Kuzulu landslide (Sivas, Turkey) and landslide-susceptibility map of its near vicinity

Landslides are common natural hazards in the seismically active North Anatolian Fault Zone of Turkey. Although seismic activity, heavy rainfall, channel incisions, and anthropogenic effects are commonly the main triggers of landslides, on March 17, 2005, a catastrophic large landslide in Sivas, northeastern of Turkey, the Kuzulu landslide, was triggered by snowmelt without any other precursor. The initial failure of the Kuzulu landslide was rotational. Following the rotational failure, the earth material in the zone of accumulation exhibited an extremely rapid flow caused by steep gradient and high water content. The Agnus Creek valley, where Kuzulu village is located, was filled by the earth-flow material and a landslide dam was formed on the upper part of Agnus Creek. The distance from the toe of the rotational failure down to the toe of the earth flow measured more than 1800 m, with about 12.5 million m³ of displaced earth material. The velocity of the Kuzulu landslide was extremely fast, approximately 6 m/s. The main purposes of this study are to describe the mechanism and the factors conditioning the Kuzulu landslide, to present its environmental impacts, and to produce landslide-susceptibility maps of the Kuzulu landslide area and its near vicinity. For this purpose, a detailed landslide inventory map was prepared and geology, slope, aspect, elevation, topographic-wetness index and stream-power index were considered as conditioning factors. During the susceptibility analyses, the conditional probability approach was used and a landslide-susceptibility map was produced. The landslide-susceptibility map will help decision makers in site selection and the site-planning process. The map may also be accepted as a basis for landslide risk-management studies to be applied in the study area.     

莱州湾南岸第三陆相层年龄的铀系等时线法(TSD)测定

于莱州湾南岸ZK32-1钻孔第三陆相层上下边界处选取自生钙质结核,采用样品全溶铀系等时线法(TSD法)测定钙质结核的年龄。测试结果表明,所有等时线上的数据都有很好的线性关系,表明所获得的年龄数据是合理的。通过对样品代表性的讨论,说明所选取的钙质结核的年龄确可代表其所在地层的年龄,从而得出莱州湾南岸第三陆相层的沉积起止时间为72.16ka B.P.±7.41ka B.P.到45.34ka B.P.±5.35ka B.P.的结论。本研究首次获得莱州湾南岸地层的铀系TSD年龄,为全面认识该地区晚更新世地层年代学提供了一个新视角。     

Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.     

不同手段和尺度下地面沉降时空变化特征分析 ——以深圳大空港区为例

本文利用不同手段和不同尺度的地面监测方法,分析城市填海区地面沉降的时空变化特征。通过深圳市大空港区的地面沉降监测工程实例分析,结合精密水准测量和遥感监测手段,实现了不同尺度地面沉降监测,获取该区域地面沉降时空变化特征。研究结果表明,精密水准测量方法与遥感监测方法均发现了会展中心周围道路产生的沉降,具有相同的变化特征。精密水准监测方法能较精确地获取局部地面沉降量,在石围路的建筑基坑周边产生最大为-303.6mm的地面沉降。结合不同手段和不同尺度的监测方法,可以较全面获取监测对象的形变特征。     

Homogenization of the Daily Land Surface Temperature over the Mainland of China from 1960 through 2017

Land surface temperature(LST) is one of the most important factors in the land-atmosphere interaction process. Raw measured LSTs may contain biases due to instrument replacement, changes in recording procedures, and other non-climatic factors. This study attempts to reduce the above biases in raw daily measurements and achieves a homogenized daily LST dataset over China using 2360 stations from 1960 through 2017. The high-quality land surface air temperature(LSAT)dataset is used to correct the LST warming biases especially evident during cold months in regions north of 40°N due to the replacement of observation instruments around 2004. Subsequently, the Multiple Analysis of Series for Homogenization(MASH) method is adopted to detect and then adjust the daily observed LST records. In total, 3.68 × 103 effective breakpoints in 1.65 × 106 monthly records(about 20%) are detected. A large number of these effective breakpoints are located over large parts of the Sichuan Basin and southern China. After the MASH procedure, LSTs at more than 80% of the breakpoints are adjusted within +/– 0.5°C, and of the remaining breakpoints, only 10% are adjusted over 1.5°C.Compared to the raw LST dataset over the whole domain, the homogenization significantly reduces the mean LST magnitude and its interannual variability as well as its linear trend at most stations. Finally, we perform preliminary analysis upon the homogenized LST and find that the annual mean LST averaged across China shows a significant warming trend [0.22°C(10 yr)–1]. The homogenized LST dataset can be further adapted for a variety of applications(e.g.,model evaluation and extreme event characterization).     

玻色-爱因斯坦凝聚和重力测量——2001年诺贝尔物理学奖评介

介绍了2001年诺贝尔物理学奖获得者康奈尔，韦曼，克特勒的科学研究成果，实验玻色－爱因斯坦凝聚（BEC）及其在理论上的意义和应用前景，讨论了BEC在研制高精度重力仪方面的应用问题，为此回顾了重力测量现状，朱棣文等研制的原子干涉重力仪和ClauserJ提出的物质波干涉重力仪，分析表明，如果利用BEC，则重力仪的测量精度在朱棣文等工作基础上将会有很大的提高。     

GM（1,1）模型在铁路路基冻胀监测中的应用

通过对季节性冻土区铁路路基冻胀量与地层温度的监测,可以了解监测段的冻胀变化过程,但无法对未来的发展趋势作出有效预测。本文采用GM（1,1）模型对监测段落路基的冻胀变形及冻结深度的变化情况进行预测。结果表明,此预测方法可以在现有监测数据的基础上有效预测短期内路基冻胀的发展趋势。根据模型预测结果,可以提前采取有效整治措施,便于决策者对轨道检验周期、维修周期、限速周期等作出合理调整。     

东川铜矿硅质角砾40Ar-39Ar定年探讨

为探索热液成因含微量钾矿物＾４０Ａｒ－＾３９Ａｒ定年的最佳实验方案,从而获得可信的成矿年龄,本文进行了东川落雪铜矿稀矿山段落雪组角砾状矿石硅质角砾流体包裹体及其固体粉末的＾４０Ａｒ－＾３９Ａｒ对比实验;先采用真空击碎技术提取硅质角砾（ＣＤ－５－２）的流体包裹体进行＾４０Ａｒ－＾３９Ａｒ分析,接着对击碎后的固体粉末样品进行常规的＾４０Ａｒ－＾３９Ａｒ阶段加热分析（１７０～１８０℃）。与以往样品的流体     

内蒙古固阳福顺店渣尔泰山群增隆昌组的风暴沉积特征

本文着重叙述了渣尔泰山群增隆昌组的沉积特征和沉积相序特征 ,并对其成因进行了分析 ,区内的增隆昌组白云岩为一风暴沉积相序 ,该相序的发现对进一步研究渣尔泰山群的沉积环境及古地理特征具有一定意义。