河北中关矽卡岩铁矿床钴元素分布规律与沉淀机制研究及意义

河北中关铁矿是“邯邢式”矽卡岩铁矿的代表矿床,本文将中关铁矿床成矿过程划分为5个阶段：干矽卡岩阶段、湿矽卡岩阶段、氧化物阶段、铁铜硫化物阶段和铅锌硫化物阶段。对湿矽卡岩阶段、氧化物阶段和铁铜硫化物阶段的金属矿物（包括黄铁矿、磁铁矿、赤铁矿等）开展电子探针测试,并且对这三个成矿阶段的代表性磁铁矿进行LA-ICP-MS微量元素测试,旨在查明中关铁矿床中Co的赋存状态以及在矿床不同成矿阶段的分布规律,探讨Co元素迁移演化-沉淀机制。研究结果表明,Co主要以类质同象的形式存在于黄铁矿中。不同成矿阶段的Co元素分布不均匀,氧化物阶段黄铁矿和磁铁矿中的Co含量最高,分别为0.12%~1.39%、41×10-6~76×10-6;铁铜硫化物阶段黄铁矿大量出现,且Co含量相对较高,为BDL~0.45%,同时期条带状磁铁矿为32×10-6~71×10-6,故此阶段为Co元素最主要的富集阶段。湿矽卡岩阶段为较高温、弱氧化条件,氧化物阶段温度逐渐降低,氧逸度增加,Co可能主要以CoCl42?形式络合迁移;铁铜硫化物阶段温度进一步降低,但还原性增加,Co可能主要以CoCl42?和Co(HS)+形式络合迁移。温度降低以及氧化还原条件的变化可能是控制Co沉淀的重要因素。     

基于克里格法刻画砂岩型铀矿U、Ra和U-Ra平衡系数垂向分布规律——以二连盆地芒来铀矿床为例

砂岩型铀矿是绿色经济可采的重要能源矿种,目前是世界上重要的铀矿勘探类型之一。二连盆地芒来铀矿床、鄂尔多斯盆地纳岭沟铀矿床铀矿体多呈板状产出,板状铀矿体成因备受关注。为研究砂岩型铀矿内部U、Ra和铀镭平衡系数（Kp）分布的垂向分布规律,本文以二连盆地芒来铀矿床为例,采用具有网格精度高优点的克里格插值法研究U、Ra和Kp垂向分布规律,分别利用放射性样品分析数据和定量伽马测井五点式反褶积法反演U含量数据,通过克里格法精细刻画砂岩型矿体中U、Ra和Kp分布的垂向分布规律。研究发现,该矿床板状矿体内部具有卷状的特征,Kp分布形态可以用来判断含氧含铀水的运移方向以及氧化强弱。该方法对研究铀矿体形态、铀矿成矿规律和后续地浸开采具有重要意义。     

广西来宾市北敢堆积型铝土矿地质特征及找矿标志

在分析研究区域成矿地质背景、矿床地质特征的基础上,对矿床成因进行了初步探讨,总结了找矿标志.认为矿源层来自上二叠统合山组底部与中二叠统茅口组顶部的古侵蚀间断面上的原生铁铝岩(铝土矿);成矿过程经历了原生铁铝岩的形成、初始堆积铝土矿的形成和改造富集成矿三个阶段后再次遭受风化、剥蚀、搬运和堆积,最终堆积型铝土矿在岩溶坡地和...     

Origin of ore-forming fluids in Qinggouzi stibnite deposit,NE China:Constraints from fluid inclusions and H-O-S isotopes

The Qinggouzi stibnite deposit is located in Huashan Town, Jilin Province, in the northeastern margin of North China Craton(NCC). It is controlled by fault structures, hosted within structurally controlled felsic dykes, predominantly surrounded by phyllite, schist and quartzite. This study presents the results of fluid inclusions studies, intending to determine the source of the fluid responsible for ore-formation, hence exploring its metallogenesis. The aqueous biphase inclusions are identified in the stibnite-bearing quartz veins of the deposit. Moreover, aqueous biphase inclusions are further classified into(1) biphase liquid-rich inclusions(1 a) and(2) biphase gas-rich inclusions(1 b) depending upon liquid to gas ratio trapped within the fluid inclusions. Homogenization temperatures for(1 a) and(1 b) range between 114.8℃ to 422℃ and 128.3℃ to 267.5℃, respectively. 1 a and 1 b have salinities of 0.18% to 16.14% NaCl_(eqv) and 1.22% to 12.88% NaCl_(eqv), and density range from 0.43 to 1.02 g/cm~3 and 0.81 to 0.98 g/cm~3, respectively. Sulfur isotopic analysis indicates δ~(34)S_(V-CDT) from 4.4×10~(-3) to 6.5×10~(-3), with an average of 5.2×10~(-3), whereas H isotopes values on δD_(V-SMOW) standard are-100.8×10~(-3) and-107.5×10~(-3), while O isotopes data on δ~(18)O_(V-SMOW) standard range between 20.1×10~(-3) and 20.4×10~(-3). Fluid inclusions study, combining with sulfur and H-O isotopic data reveal that the ore-forming fluids originated from deep source and were subsequently contaminated by meteoric water. Hydrostatic pressure calculation shows that the minimum and maximum pressures are 11.65 and 42.33 MPa, and relevant depths of deposit are estimated to be 1.16 and 4.23 km. Finally, we inferred that Qinggouzi stibnite deposit is a medium-low temperature, low salinity hydrothermal deposit, which is formed by deep source and later contaminated by meteoric water, and is classified as epizonal deposit in terms of orogenic series.     

中哈俄阿尔泰稀有金属矿床时空分布、成因及成矿规律

中哈俄阿尔泰发育许多大型—超大型稀有金属矿床,是世界著名的稀有金属成矿省.该成矿省可分为3个稀有金属成矿带,自西南向东北依次为哈萨克斯坦Kalba-Narym、中国阿尔泰和俄罗斯山区阿尔泰等.这3个成矿带稀有金属矿床以伟晶岩型为主,但伟晶岩与花岗岩关系及其伟晶岩成因不一致:在哈萨克斯坦Kalba-Narym成矿带和俄罗...     

Geometry and kinematics of brittle deformation in the Central Cameroon Shear Zone (Kékem area): Implication for gold exploration within the Central Africa Fold Belt in Cameroon

The Central Africa Fold Belt (CAFB) is a collision belt endowed with gold deposits in Eastern Cameroon area mined for about 50 years. However, favorable areas for gold exploration are poorly known. This paper presents (1) the kinematics of the brittle deformation in the Kékem area in the SW portion of the Central Cameroon Shear Zone and (2) constraints gold mineralization events with respect to the collisional evolution of the CAFB. The authors interpret that the conjugate ENE to E and NNW to NW trending lineament corresponds to the synthetic (R) and the antithetic (R’) shears, which accompanied the dextral slip along the NE to ENE striking shear. The latter coincides with the last 570–552 Ma D₃ dextral simple shear-dominated transpression, which is parallel to the Bétaré Oya shear zone hosting gold deposits. Gold mineralizations, which mainly occurred during the last dextral shearing, are disseminated within quartz veins associated to Riedel’s previous structures reactivated due to late collisional activities of the CAFB as brittle deformation. Gold mineralizations occurred mainly during the 570–552 Ma D₃ event. The reactivation, which might be due to dextral simple shear during mylonitzation, plausibly remobilized the early gold deposits hosted in syn-compressional rocks and/or possibly focused deep-sourced fluid mixed with those released by dehydration. Therefore, the Central Cameroon Shear Zone where Kékem is located, and which shows similar petrographical and structural features to those controling Batouri gold district, is a target area for gold exploration in Cameroon.     

贵州三都排正金矿床成矿元素赋存规律及成矿潜力评价

贵州三都—丹寨Hg-Au-Sb成矿带大地构造位于扬子克拉通黔南台陷与华南褶皱带西缘交界处,成矿带内断裂构造极其复杂,矿体延伸、展布明显受构造控制.排正金矿床位于该成矿带中南段,对其成矿有利靶区进行成矿元素地球化学样品分析,探讨成矿元素相关性和赋存状态,反演成矿机制.分析结果显示:①矿石中Au元素与As、Pb+Zn、Hg...     

东川式铜矿的成矿作用及后期叠加改造:来自硫化物原位硫同位素的制约

沉积岩型层状铜矿床(SSC型)的成因争论聚焦在成矿作用主要集中在沉积成岩期并可能叠加有后期成矿作用,还是形成于成岩后盆地闭合过程和造山作用有关.产于扬子板块西缘的东川式铜矿是中国SSC型矿床的典型代表,这些矿床赋存在晚古元古界东川群岩石中,主要呈层状矿体产出,但也存在少量脉状矿体.文章选择东川铜矿田内因民、汤丹和滥泥坪...     

新探明的玻利维亚银沙(Silver Sand)超大型银矿床地质特征和找矿评价

银沙银矿(Silver Sand silver deposit)是玻利维亚锡矿带内新探明的一个超大型中硫型浅成低温热液银矿床,已探明银金属资源量约1万t,平均银品位约120 g/t,并伴有少量铅、锌、铟、镓.银矿化与中新世中酸性侵入岩和次火山岩有关.矿体赋存于白垩系蚀变褪色石英砂岩中的密集构造裂隙带内.成矿作用可以划分...     

西藏洛巴堆矽卡岩型铁多金属矿床石榴子石和锆石U-Pb测年及地质意义

石榴子石是矽卡岩型矿床中最常见的蚀变矿物之一,因此,对石榴子石进行年代学研究能够准确限定矽卡岩型矿床的成矿时代.青藏高原冈底斯成矿带中部发育众多矽卡岩型多金属矿床,由于缺乏精确的成矿年代学数据,制约着对这些矿床成因和动力学背景的深入认识.因此,文章以该成矿带具有代表性的洛巴堆矽卡岩型铁多金属矿床为研究对象,通过对赋矿矽...