The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

幔源岩浆活动过程中的去气作用 ——以云南老王寨金矿煌斑岩为例

本文以云南老王寨金矿煌斑岩为例，从岩石产出的构造环境、源区地幔交代富集作用、岩浆演化中硅酸盐熔体-碳酸盐熔体液态不混熔作用、岩石中CO     

内蒙武川后石花金矿床辉钼矿Re-Os同位素年龄及其地质意义

后石花金矿是华北克拉通北缘一小型石英脉型金矿床。对矿体5件辉钼矿样品的ReOs同位素分析,获得了介于280.3±3.8~283.0±3.9Ma,加权平均为282.0±1.8Ma(MSWD=0.28)的同位素模式年龄,以及一个相关性很好的等时线年龄281.9±1.8Ma(MSWD=0.57),表明矿床形成于早二叠世,推测是海西晚期古亚洲洋俯冲体制下陆缘弧背景中构造-热液成矿事件产物。综合区域资料认为,华北北缘中段在海西晚期曾发生过重要成矿作用,但多在后期被剥蚀破坏。华北北缘中段大陆弧范围内,叠加在前寒武纪结晶基底韧性剪切带之上的脆性断裂构造带,以及华北北缘早古生代增生带内部,是形成海西晚期金、钼矿床的有利部位。     

广西金牙金矿床百逢组沉积特征及其与金矿的关系

广西金牙金矿产于中三叠统百逢组中 ,矿区的百逢组为一套陆源碎屑浊积岩 ,既有阵发性高密度浊流引起的浊积扇体系 ,又有稳定低密度浊流引起的鲍马序列。百逢组下段为浊积扇体系 ,中段及上段为鲍马序列 ,一般不全 ,其中d、e段最发育 ,其次为c、b段。金矿化出现在砂泥混积的百逢组中段。矿体位于鲍马序列段 ,尤其是de和cde组合段 ,岩石为富含有机质的泥质与粉砂的混积岩 ,属远端浊积岩。其中 ,钙质泥岩和粉砂质泥岩是最有利的矿化围岩。主要载金矿物毒砂和黄铁矿呈自形晶出现。矿体的有机碳含量高于相邻围岩的有机碳含量 ,与运移烃类的叠加有关。金品位随有机碳含量的增加而增加 ,有机质也是有用的金的载体。富含有机质的浊积岩是浊积岩型金矿床形成的有利条件。     

东秦岭上宫金矿流体成矿作用:矿物学研究

通过对上宫金矿矿物学资料的研究，确定其成矿过程具有3阶段演化特征。早阶段以粗粒乳白色石英脉为标志，矿物破碎、变形明显，金和杂质成分含量低，形成于挤压构造背景下静岩压力的变质流体。中阶段发育细粒多金属硫化物-碲化物-自然元素组合，呈微细网脉浸染于共轭节理或裂隙，没有遭受变形，金和杂质成分含量高，自然金与其他矿物属共沉淀关系，由变质流体沸腾导致，而流体沸腾则由造山过程的地壳快速隆升剥蚀引起。晚阶段发育具梳状构造的石英-碳酸盐网脉，含金性较低，由静水压力的大气降水热液在伸展构造背景下贯入张性裂隙形成。矿床地质地球化学特征与造山型金矿一致，成矿过程同步于陆陆碰撞造山作用，属于典型的断控脉状造山型金矿，成因适合于CMF模式。     

黑龙江平顶山金矿石英天然热发光特征

对平顶山金矿中52件石英样品的天然热发光曲线特征研究表明,含金或富含金石英的热发光曲线以双峰或多峰为其主要特征,不含金的石英以单峰为其特征,石英热发光曲线特征可作为指示金矿化的一个重要标志.     

K-Ar Ages of Granitic Magmatism and Related Pegmatite Formation at the Umanotani-Shiroyama Mine, Shimane Prefecture, SW Japan and Their Bearings on Cooling History

Abstract. The Umanotani-Shiroyama pegmatite deposits, the largest producer of K-feldspar and quartz in Japan, are of typical granitic pegmatite. Ilmenite-series biotite granite and granite porphyry, hosting the ore deposits, and biotites separated from these rocks yielded K-Ar ages ranging from 89.0 to 81.4 Ma and 95.2 to 93.7 Ma, respectively. Muscovite and K-feldspar separated from the ore zone yielded K-Ar ages with the range of 96.2 to 93.1 Ma and 87.3 to 80.7 Ma, respectively. Muscovites from quartz-muscovite veins in the ore zone and in the granite porphyry yielded K-Ar ages of 90.4 and 76.3 Ma, respectively. K-feldspar is much younger in age than coexisting muscovite. It is noted that the K-Ar ages of biotite separates and the whole-rock ages are identical to those of muscovite and K-feldspar in the ore zone, respectively. These time relations, as well as field occurrence, indicate that the formation of the pegmatite deposits at the Umanotani-Shiroyama mine is closely related in space and time to a series of granitic magmatism of ilmenite-series nature. Using closure temperatures of the K-Ar system for biotite and K-feldspar (microcline), cooling rate of the pegmatite deposits is estimated to be about 82C/m.y. at the beginning, but slowed down to about 15C/m.y. in the later period.     

矿物标型六性及其在胶东金矿中的应用

目前矿物标型研究和应用已进入一个新的阶段。作者从哲学的高度,把国内外矿物标型特征的分散研究加以集中概括和总结,提出了“矿物标型六性”的普遍规律,即普遍性、特殊性、变化性、相应性、继承性和分带性,对矿物标型特征研究具重要的指导意义。这些规律在胶东金矿中得到广泛应用,并已取得良好效果。     

辽南上达子堡金矿化区黄铁矿标型特征及意义

上达子堡金矿化区主要出露古元古界辽河群盖县岩组二岩段,是金成矿物质的矿源层。黄铁矿标型特征指示目前区内的剥蚀水平相当于中上部,按黄铁矿垂直分带规律,{210}+{100}、{210}习性晶体向深部有可能逐渐增加,因此,本金矿化区深部含金量可能高于浅部。     

李坝式金矿床成矿作用及矿床类型探讨

李坝式金矿床成矿作用过程分为成矿元素初始富集期和构造叠加热液改造成矿期，岩浆活动主号是通过改变矿床地质体物化条件而促进矿化体的形成，并有部分岩浆物质参与成矿。该矿床与国内外经典卡林型金矿床具有较大的可比性，但是由于缺乏低温矿物组合以及与岩浆活动的亲密性证据，该矿床应属广义上的卡林型金矿床。