电吸附找矿方法

电吸附找矿方法是找隐伏矿的新方法.它是指通过物理化学手段来发现后生地球化学异常的找矿方法.它是建立在异常元素地球化学理论和野外地电提取法的理论基础之上.利用电吸附找矿方法在一些已知矿床进行找矿效果试验,获得了很好的效果,说明了该方法找矿的有效性.     

青藏高原热融湖塘动态监测中高分辨率遥感数据处理方法研究

遥感技术由于能够快速、 宏观的获得研究区域的数据, 已成为青藏高原热融湖塘动态监测的重要技术手段. 基于野外现场调查和SPOT-5、 QuickBird两种高分辨率遥感卫星数据的特性分析, 结合影响青藏高原热融湖塘发育的一系列特征因素, 探讨了最适合于青藏高原热融湖塘动态监测的高分辨率遥感数据的纠正、 融合和信息提取方法. 应用该方法对2006-2009年间北麓河盆地北侧的红梁河至秀水河段公路沿线局部63 km²范围的热融湖塘进行了变化特征分析, 结果表明该区的热融湖塘个数和总面积在研究时段都有所增加, 其中湖塘由70个增加到75个, 湖塘总面积增量19.65%.     

尾砂库重金属元素表生地球化学行为的初探

通过重金属含量分析,分级提取化学形态分析,结合矿物成分和化学成分分析,对黄龙铺矿区1号尾矿库重金属元素在风化过程中的地球化学行为进行了研究。研究结果表明在横向上,尾矿库中心排水口处地势低洼,铜、铁因相对活泼易于迁移而流失,铅、锌、铬、镉在尾矿库四周的地表浅部淋失,在尾矿库中心则相对富集。化学形态分析表明尾砂中各重金属元素赋存状态各有不同,一般以T6原生硫化物态和T7残渣态为主,铜、锌、铁迁移性较强;其他则较弱,表明对环境威胁不是很大。重金属的迁移明显的分为氧化带和次氧化带,研究结果显示尾矿覆盖方法也不一定能够有效地阻滞污染元素的迁移。     

基于RAGA的PPC模型在化探异常分析中的应用——以凤太矿集区为例

化探数据处理的核心内容是地球化学背景与地球化学异常的合理区分,找矿信息提取将直接影响到成矿预测的结果.文章采用基于RAGA的PPC模型对凤太矿集区1:5万水系沉积物化探数据进行处理,初步探讨了投影寻踪聚类方法在地球化学异常识别与元素共生组合方面的应用,以及投影方向值所代表的地质意义.结果表明,PPC模型的化探异常识别效...     

松潘两岔河高砷高锑金矿石氰化提金工业试验

高砷高锑金矿石属难处理矿石之一，通过对两岔河高砷高锑金矿石采用碱浸预处理后进行堆浸和池浸氰化提金试验，获得了金浸出率76．80％和86．76％的较好指标，为该矿床的开发利用提供了一个工艺简单、经济上可行的途径。     

Numerical simulation of fracture path and nonlinear closure for simultaneous and sequential fracturing in a horizontal well

Reservoir stimulation requires a model to evaluate the fracture path and closure for the simultaneous or sequential propagation of the hydraulic fracture (HF). This paper presents a fluid-solid coupled model to simulate multi-stage HF propagation. A non-linear joint model is proposed to evaluate the fracture closure when the created fractures are elastically propped. HF closure continues until the balance of external stress matches the proppant's resistance. The reservoir along the horizontal wellbore is not stimulated equally by the multi-stage fracturing. The HFs in the subsequent stage are ‘repelled’ and restrained by the HFs in the previous stage.     

Distribution and partitioning of major and trace elements in pyrite-bearing sediments of a Mediterranean coastal lagoon

The formation of iron sulphide minerals exerts significant control on the behaviour of trace elements in sediments. In this study, three short sediment cores, retrieved from the remote Antinioti lagoon (N. Kerkyra Island, NW Greece), are investigated concerning the solid phase composition, distribution, and partitioning of major (Al, Fe) and trace elements (Cd, Cu, Mn, Pb, and Zn). According to ²¹⁰Pb, the sediments sampled correspond to depositions of the last 120 years. The high amounts of organic carbon (4.1–27.5%) result in the formation of Fe sulphides, predominantly pyrite, already at the surface sediment layers. Pyrite morphologies include monocrystals, polyframboids, and complex FeS–FeS₂ aggregates. According to synchrotron-generated micro X-ray fluorescence and X-ray absorption near-edge structure spectra, authigenically formed, Mn-containing, Fe(III) oxyhydroxides (goethite type) co-exist with pyrite in the sediments studied. Microscopic techniques evidence the formation of galena, sphalerite and CuS, whereas sequential extractions show that carbonates are important hosts for Mn, Cd, and Zn. However, significant percentages of non-lattice held elements are bound to Fe/Mn oxyhydroxides that resist reductive dissolution (on average 60% of Pb, 46% of Cd, 43% of Zn and 9% of Cu). The partitioning pattern changes drastically in the deeper part of the core that is influenced by freshwater inputs. In these sediments, the post-depositional pyritization mechanism, illustrated by overgrowths of Fe monosulphides on pre-existing pyrite grains, results in relatively high degree of pyritization that reaches 49% for Cd, 66% for Cu, 32% for Zn and 7% for Pb.     

土壤重金属连续提取方法的优化

重金属在污染土壤中的形态分布决定着重金属的迁移性和危害的程度。土壤重金属形态分析应用最多的是Tessier和BCR连续提取法。Tessier和BCR连续提取法没有考虑土壤样品的特征。美国环保署危险废物浸出毒性鉴别标准法虽然考虑土壤pH值,但没有划分形态。采集不同pH土样,结合Tessier、BCR和毒性浸出鉴别方法的特征,优化出针对不同pH值土壤的连续提取方法,将土壤中重金属划分为活性态、次生碳酸盐结合态、次稳定态和稳定态。用优化的连续提取方法对土样进行连续提取,重金属回收率为85%~115%。优化连续提取方法的结果与Tessier和BCR结果对比显示优化连续提取方法克服了Tessier连续提取法对非石灰质土壤提取过量BCR连续提取法对石灰质土壤提取不足的缺点。优化后的连续提取方法数据稳定可靠,可作为重金属形态分析方法使用。     

Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.     

云南个旧多金属矿石门坎—保和地区Sn、Sb元素的成矿信息识别与提取

石门坎—保和地区位于云南个旧多金属成矿区西南部,成矿背景复杂,成矿作用具有多期性和多样性。利用研究区1∶1万土壤化探数据,采用泛克里格法和因子分析相结合的方法,提取不同层次的成矿异常信息。结果表明:主因子F_3包含Mo-Au-Sb等元素,反映成矿过程中的岩体和热液相关信息;主因子F_4包含Sn-Bi-W元素,指示中低温热液矿化环境; Sb沿杨家田断裂呈串珠状分布,反映了由北东向构造控制的空间变化特征,与已知矿点对应良好; Sn元素异常在研究区北部呈双峰状环形分布,推测受隐伏岩体或者断层控制。根据元素组合异常F_3和F_4的分布规律,结合地质资料圈定出2个找矿靶区,为进一步找矿工作提供了方向。