Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins,Southern India

The Palar and Cheyyar River Basins in Tamil Nadu state of Southern India are characterised by different geological formations, and groundwater is the major source for domestic, agricultural and other water-related activities. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes and their relation to groundwater quality. Groundwater samples were collected once a month from 43 groundwater wells in this area from January 1998 to July 1999. Sampling procedures and chemical analysis were carried out as per the standard methods. Chemical data are used for mathematical calculations and graphical plots to understand the chemical process and its relation to the groundwater quality. The chemical composition of groundwater in the central part of the study area mainly depends on the recharge from lakes and the river, which is explained by a mixing mechanism. In addition, weathering of silicate minerals controls the concentration of major ions such as sodium, calcium, magnesium and potassium in the groundwater of this area. Further, the activity ratios indicate that the groundwater is in equilibrium with kaolinite, smectite and montmorrillonite. The reverse ion exchange process controls the concentration of calcium, magnesium and sodium in hard rock formations, and dissolution of carbonate minerals and accessory minerals is the source of Ca and Mg, in addition to cation exchange in the sedimentary formations. In general, the chemical composition of the groundwater in this area is influenced by rock–water interaction, dissolution and deposition of carbonate and silicate minerals, ion exchange, and surface water interactions.     

Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, ?Li 2Mg 3Fe 3+ 2Si 8O 22(OH) 2

This work reports the synthesis of ferri-clinoholmquistite, nominally _Li2(Mg₃Fe³⁺₂)Si₈O₂₂(OH)₂, at varying f_O2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions ( NNO+1, where NNO = Nickel–Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe₂O₃ ratio, departs significantly from the nominal one. Under oxidizing conditions ( NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is ^M2(Mg,Fe²⁺) ^M4(Mg,Fe²⁺) ^M2Fe³⁺_–1 ^M4Li_–1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å, b = 17.878(3) Å, c = 5.282(1) Å, = 102.06(2)°, V = 870.8(3) ų. Mössbauer spectra show that Fe³⁺ is strongly ordered at M2 in all samples, whereas Fe²⁺ is disordered over the B and C sites. FTIR analysis shows that the amount of ^CFe²⁺ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites.     

建筑结构抗震研究若干基本问题概述及讨论

本文介绍和讨论了结构抗震研究中的一些基本问题,包括地震反应分析选择地面运动输入应注意的问题,高层结构地震模拟试验问题和结构地震反应分析中的主要分析方法和存在的问题,最后简要介绍了目前常用结构反应分析程序。     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

kSZ from patchy reionization: The view from the simulations

We present the first calculation of the kinetic Sunyaev–Zel’dovich (kSZ) effect due to the inhomogeneus reionization of the universe based on detailed large-scale radiative transfer simulations of reionization. The resulting sky power spectra peak at ℓ = 2000–8000 with maximum values of [ℓ(ℓ + 1)C_ℓ/(2π)]_max  4–7 × 10 ⁻¹³. The scale roughly corresponds to the typical ionized bubble sizes observed in our simulations, of 5–20 Mpc. The kSZ anisotropy signal from reionization dominates the primary CMB signal above ℓ = 3000. At large-scales the patchy kSZ signal depends only on the source efficiencies. It is higher when sources are more efficient at producing ionizing photons, since such sources produce larger ionized regions, on average, than less efficient sources. The introduction of sub-grid gas clumping in the radiative transfer simulations produce significantly more power at small-scales, but has little effect at large-scales. The patchy reionization kSZ signal is dominated by the post-reionization signal from fully-ionized gas, but the two contributions are of similar order at scales ℓ  3000 − 10⁴, indicating that the kSZ anisotropies from reionization are an important component of the total kSZ signal at these scales.     

碳酸锶废渣酸浸液的钙锶分离研究

对碳酸锶废渣酸浸液进行蒸发、结晶、过滤,得到初步纯化的氯化锶,再对其进行水溶、除钙等处理,以达到精制氯化锶的效果。在得到高纯氯化锶溶液的同时,回收了氯化钙。该方法通过简单的操作实现了碳酸锶废渣酸浸液的钙锶分离。     

孟加拉湾风暴Mala结构及对云南强降水的影响

利用实时观测资料和NCEP(1°×1°)的6 h再分析资料,对2006年春季发生在孟加拉湾的超强风暴Mala的移动路径、强度变化、环流背景以及风暴温湿场、动力场特征等进行分析。结果表明:Mala在阿拉伯副热带高压和西太平洋副热带高压两高间辐合区生成、加强,并沿西太平洋副热带高压西侧西南或偏南气流移动。风暴发展、成熟到消亡,湿度对风暴的作用比温度明显;动力场结构除具有台风结构的一般特征外,在风暴发展期,中心附近散度场从低层到高层为辐合和辐散交替结构,表明风暴内部高空辐散抽吸作用对于风暴发展起到重要作用。登陆后风暴低压内自身能量和水汽与冷空气共同作用下,在冷暖交汇处出现强烈的上升运动和激发出中尺度辐合线是造成云南强降水主要原因。     

Spatial and short-term temporal variations in Uranus’ near-infrared spectrum

We obtained near-infrared spectra of Uranus at NASA’s Infrared Telescope Facility during the planet’s September 2006 and September 2007 oppositions. Ratios between the spectra indicate that in 2006, Uranus’ methane windows appeared much brighter in the south than in the north, and that between 2006 and 2007 they grew dimmer in the south and brighter in the north; we interpret these variations to be primarily caused by changing brightness in Uranus’ upper cloud layer near 2 bars.     

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.     

北京西山煤田滑脱构造的遥感研究

本文利用多种遥感资料提供的大量的新的构造信息,对北京西山煤田已有的地质认识和成果进行了重要补充和修改,划分出推覆型和滑型两种基本类型的滑脱构造,并详细研究了各个滑脱构造系统的影像特征、展布规律、几何形态、成因机制、演化历史以及控煤作用。