水稻土中重金属元素Cd、Pb的竞争吸附——以长株潭地区水稻土为例

对中国南方的3个水稻土样品进行了Cd、Pb单一离子和混合离子吸附特点的研究。结果表明,3个水稻土样品中Cd、Pb的吸附特点都相似,Langmuir等温方程可很好地描述Cd、Pb的吸附等温线。3个土壤样品中,有较高pH值和较低有机物、CEC浓度、粘土含量、高岭石含量的2个土壤样品对Cd、Pb有较大的吸附量,且其等温吸附拟合的最大吸附量（B）也较大。在两组分混合溶液中,尽管共存离子的存在影响了土壤对单一离子的吸附,同时土壤对Cd的吸附在一定程度上受影响的程度大,但3个土壤样品都表现出对Pb有强的吸附能力。在3个土壤样品中,Langmuir等温方程中Pb的健合能常数（K）都大于Cd的健合能常数（K）,混合溶液中的K值高于单一溶液的K值,表明2种金属离子对吸附位点的竞争提高了特定吸附位点的保持力,使金属离子在土壤中特定位点的吸附更加坚固。     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

昆仑山北坡岛状冻土区西大滩大型饮用矿泉群成因分析

在对昆仑山北坡岛状冻土区西大滩大型饮用矿泉群水文地质、导水与控水断裂、水化学等方面实地调查和EH-4高频、电测深勘探的基础上,认为矿泉群的补给源为昆仑山玉珠峰一带的现代冰川底部冰雪覆盖融区水、冰雪消融水、大气降水和地表水.补给源水通过具多期活动性的F3和F4正断层组破碎带补给深层地下水.深层地下水在西倾近南北向正断层组F2及F2-1,2的导水断层破碎带富集并继续向北径流,径流至F1南倾活动性逆断层上盘时,形成富水"三角区",并沿F1断层破碎带排泄出地表,是西大滩大型饮用矿泉群形成的主因.     

土地利用变化对土地生产力的影响研究进展

土地利用变化对土地生产力的影响是土地利用/覆被变化(LUCC)效应研究的重要内容之一。本文基于对土地利用变化和土地生产力概念的辨析, 着重从土地利用变化对土地生产潜力、粮食生产能力和土壤质量3 个方面的影响, 总结梳理了当前的主要研究内容和方法, 探讨了研究的影响尺度特征。最后指出今后的研究应加强土地利用结构、方式和强度变化对小尺度范围内耕地生产力的影响, 强化不同尺度的综合以及空间分析和动态评估方法的应用。     

端头扩大型土锚的新发展 ——船锚式注浆张开型土锚

作为提高锚固性能的一种有效手段，端头扩大型土锚被广泛应用于实际工程。介绍了端头扩大型锚杆的各种扩孔方法，重点阐述一种新型的船锚式注浆张开型土锚。带有锚抓的新型土锚，不需要专门的扩孔机械，在注浆作用下能连续完成端头扩张与灌浆，具有施工方便、锚固面大、效果好等优点。通过对土锚进行张开试验，证明了在上海等软土地区通过灌浆压力使锚抓张开并形成扩大头是能够实现的。     

火山岩坡残积土地区暴雨滑坡泥石流的形成机理

暴雨条件诱发的浅层坡残积土质斜坡破坏的机理受控于土体在低有效围压条件下的应力应变特性。1993年11月4～5日,香港大屿山地区特大局部性暴雨导致在120km2范围内产生自然滑坡泥石流800余处,且绝大多数发生于火山岩风化坡残积土地区。本文对火山岩风化坡残积土开展了室内偏压固结不排水剪和偏压固结常剪应力排水剪试验,揭示了该类土的应力应变特性;在此基础上,分析了暴雨滑坡泥石流的形成机理和过程。     

粉状煤系土的物理力学特性

采用不同天气下的原位及室内试验方法,对广东云浮地区粉状煤系土的工程地质性质进行了测试,系统研究了煤系土的物理力学特性,重点论述了粉状煤系土不同干密度、不同含水率下抗剪强度和现场静力触探比贯入阻力的变化规律,提出了粉状煤系土的多项强度指标,建立了具有实用参考价值的经验性公式。研究结果为合理评价粉状煤系土的特性、路基处理和边坡处治提供理论依据,具有一定的实际意义。     

水平推力桩在大位移情况下m值的确定

根据《港口工程桩基规范局部修订》关于m法的新解释,结合某码头2根大直径钢管嵌岩桩的试桩资料总结了m值与泥面处位移 的指数关系以及m值对桩受力特性的影响,发现规范建议的m值难以适应大位移情况下的取值要求。建议通过收集大量有关大位移情况下的试桩资料,根据m值和泥面处位移 的指数关系,统计分析出在各种土质条件下相应于某一大位移时m值的取值范围,为工程设计提供依据。     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

宽级配砂土基料-滤层系统的室内模型试验研究

基料一滤层利用数码可视化跟踪技术、计算机信息实时处理技术和土体变形无标点量测技术,对宽级配基料一滤层系统进行了渗透室内模型试验。探讨了滤层准则的适用性,研究了不同滤层厚度和加压速率对管涌发生发展的影响。结果表明：传统太沙基滤层准则不适用于宽级配砂土,建议采用可移动颗粒中的d85s进行滤层准则设计;增加滤层厚度可提高系统的抗渗透破坏能力,但提高滤层厚度对提高整个系统抵抗渗透能力作用不大;水力梯度增加较快不利于系统的稳定。