贵州海相沉积汞矿特征及汞的迁移转化规律研究

采用X射线衍射(XRD)和电子探针显微分析技术(EPMA)对海相沉积汞矿特征进行了研究,分析了汞的迁移转化规律。表征结果表明,矿石类型包括白云石、方解石、钼钨钙矿、朱砂矿、钙钼矿和少量的钋矿;矿石结构致密,呈包裹和裂隙状态;汞主要以氧化矿为主,还有微量的单质汞,含量约为0.15%(以Hg计)。水和土壤环境中的汞易被各种配位体、有机质、无机颗粒物以及粘土矿等吸附形成有机汞(如甲基汞),一部分汞以气态形式进入大气。     

东准造山带原泥盆系的形成时代及源区：碎屑锆石U-Pb年代学证据

新疆东准地区晚古生代地层出露广泛,其沉积时限的精确限定对理解中亚造山带的增生和拼贴过程、确立该地区构造框架及油气开发具有深远意义。然而,目前的研究主要集中于岩浆岩方面,对于晚古生代地层时代及其空间展布的研究则相对缺乏,特别是石炭系和泥盆系沉积地层标定较为模糊。为此,本文选取了3个原泥盆系砂岩进行了细致的野外剖面测制、岩石学观测和碎屑锆石U-Pb年代学分析。研究显示：原泥盆纪砂岩的最年轻碎屑锆石年龄为346～312 Ma,碎屑锆石年龄谱图分为：380～310 Ma（晚泥盆世-早石炭世,71.8%）、445～385 Ma（志留纪-早-中泥盆世,11.7%）、480～450 Ma（奥陶纪,3.9%）、540～485 Ma（寒武纪,4.5%）和前寒武纪年龄段（8.1%）,碎屑锆石年龄谱图区域上具有由南向北、由西向东呈简单化趋势且晚古生代年龄比重增加。结合该区岩浆岩年代学研究成果,将研究区原泥盆系沉积时代重新厘定到晚石炭系早-中期,认为东准地区的碰撞拼贴时间应发生于晚石炭世,并非是不同期次碰撞拼贴之产物。     

Research on Paleoecology of Middle Permian-Middle Triassic in the Western Sichuan Basin

The research area is located in the western part of Sichuan basin as a Yangtze ecotope of Cathaysian Tethyan area. It is dominated by benthic fauna, including brachiopods, Fusulinids, corals, bivalves, foraminifers, ammonites, bryozoans,Crinoids and pleopods which are less common with traces of trilobites, stromatoporas, nautilus and sporopollens seen in one or two areas,which are obviously controlled by sedimentary environments and in accordance with sedimentary facies.Through the analysis of fossils and research on burial characteristics from middle Permian middleTriassic, based on the combination of the feature of fossils in time and space, seventeen communities are recognized, the coposition, construction and palaeoenvironment of each community are expounded. Study shows that different ecological type biocoenose are distributed in different locations, which are mainly represented by sessile benthic community in the main research area, composed of Mianzhu, Mianyang, Deyang and Santai and nektonic community in marginal areas in the research area subdivided into two parts: Areas around Guangyuan-Nanjiang-Tongjiang, located at the margins in the northeast of the research area, and areas around Wenchuan-Maoxian-Dayidafeishui situated at the western borders of the research area. According to the combination of communities with sedimentary characteristics,six kinds of biofacies have been recognized and described in the study area and biofacies pattern are established. Category,ecotype, typical community and sedimentary facies of each biofacies are elucidated in this paper. The subdivision and analysis of community are meaningful for the studies of paleoenvironment ,paleogeography and their evolutions,The research of biaofacies is important for the recovery of paleobiogeography and paleoplate tectonic characteristics.     

蒙阴盆地的成生与演化

蒙阴盆地是在库拉板块向亚洲大陆下俯冲，中国东部隆升伸展板块裂解阶段发育起来的。在中生代，盆地的成生演化经历了侏罗纪拗陷盆地发育阶段和早白垩世拗陷—裂陷阶段。在相应沉积演化过程中，形成侏罗纪湖相红色碎屑岩建造，早白垩世早期滨浅湖—半深湖相灰绿色细粒陆屑岩沉积，早白垩世中期河湖相凝灰质复陆屑岩类夹火山碎屑岩类沉积，早白垩世晚期中基性火山熔岩、火山碎屑岩组合。沉积中心在侏罗纪和早白墨世早期皆偏于西北部，此后，向东南部迁移。晚白垩世，盆地处于风化剥蚀阶段。古近纪，受新生太平洋板块向亚洲大陆下俯冲影响，盆地又处于拗陷—裂陷阶段，相应形成山间河湖相—山麓堆积相类磨拉石建造。古近纪末期，该盆地整体隆起处于长期风化剥蚀状态。     

新疆博格达山北缘二叠纪中—晚期构造运动的沉积响应

博格达山北缘是准噶尔盆地与天山造山带之间的关键部位,是研究盆山关系的重点区域。博格达山北缘二叠纪中、晚期的构造演化与沉积时空演变关系存在较大争议。本研究通过野外实地勘测、镜下岩石薄片鉴定、粒度分析实验和地震资料解析等方法,针对博格达山北缘东、西部两条剖面—大龙口剖面和井井子沟剖面开展研究,分析其沉积类型和演变过程,解析盆山构造变形和发育特征,探讨构造运动的沉积响应。研究结果表明：瓜德鲁普统乌拉泊组为湖成三角洲相,井井子沟组至红雁池组为湖泊相,乐平统泉子街组为冲积扇—河流相沉积,梧桐沟组和锅底坑组为滨浅湖—三角洲相沉积;研究区可分为两个主要构造层,下构造层以伸展断陷为主要结构,上构造层以前陆冲断为主要构造变形;多期构造活动控制瓜德鲁普统、乐平统沉积演化过程,在挤压构造背景下,瓜德鲁普统的湖泊相转变为乐平统冲积扇—河流相沉积,晚期构造活动趋于稳定,区域进入准平原化作用阶段。     

新生代阿尔金断裂带的演化:来自沿线盆地沉积记录的启示SCIEI北大核心CSCD

阿尔金断裂带是青藏高原自印度与欧亚大陆碰撞后向北扩展的前缘断裂,其新生代活动性对于研究青藏高原隆升与扩展过程和机制具有重要意义。近些年,运用热年代学、断裂几何学和运动学、沉积学、磁性地层学和地震学等方法对阿尔金断裂带的性质、组成结构、断裂活动时代、走滑断裂运动特征、走滑位移量和走滑速率等进行了细致的研究,而对阿尔金断裂带沿线受其控制的新生代沉积盆地的地层年代、沉积演化特征虽然也有一定研究,但往往仅限于单个盆地,缺乏对沿线盆地整体的对比认识,造成对阿尔金断裂带走滑起始时间及阿尔金山的隆升历史存在不同的认识。本文对近二十年来阿尔金断裂带沿线新生代沉积盆地的磁性地层年代与沉积相演化的研究进展进行综述,建立阿尔金断裂带沿线盆地新生代沉积序列和年代框架;辅助热年代学等资料,提出阿尔金断裂带的三阶段演化模型:始新世-中中新世,阿尔金断裂带以大幅度的走滑运动为主,同时伴随着阿尔金山小范围的隆升;中中新世开始,阿尔金山开始大规模的隆升,伴随着较少量的走滑运动;晚中新世以来,阿尔金断裂带构造活动加强。     

新疆博格达山晚古生代地层的形成时代、物源及其演化:碎屑锆石U-Pb年代学证据

新疆博格达山主体由石炭系海相火山一沉积岩系组成,以发育两期双峰式火山岩,但不发育花岗岩为特征,对其晚古生代地层时代的划分和演化争议较大。本文重点对博格达山北部两个晚古生代砂岩进行了碎屑锆石U-Pb年代学分析,重新标定博格达山地区晚古生代地层的形成时代;利用物源区的演化,约束晚古生代构造演化。测年结果显示博格达上亚群砂岩的碎屑锆石表面年龄值分布范围较宽,主峰年龄为343~284 Ma(80%),次峰年龄为386~375 Ma(3%)、503~441Ma(7%)和871~735 Ma(10%);芦草沟组砂岩的碎屑锆石表面年龄值非常集中,主峰年龄为358~279 Ma(97%),次峰年龄为257~251 Ma(约3%)。博格达山中部原石炭纪博格达群上亚群与西部和南部下芨芨槽群相当,应属于早二叠世,中部一东部的石炭一二叠纪界线应在博格达下亚群一上亚群或居里得能组一沙雷塞尔克组之间的不整合面之中。博格达北部地区晚二叠世以南侧天山物源区供给为主,反映出晚古生代期间博格达山地区至少存在晚石炭世末和中二叠世两期构造隆升。结合区域火山岩与火山碎屑岩的研究,认为博格达山地区晚古生代主要经历4个演化阶段:早石炭世弧后盆地裂解阶段、晚石炭世碰撞拼贴阶段、早二叠世碰撞后伸展阶段、中-晚二叠世再次隆升到稳定阶段。     

长江三角洲晚第四纪地层沉积特征与生物气成藏条件分析

对长江三角洲晚第四纪地层沉积特征进行了精细研究,探讨了研究区层序地层格架,在此基础上分析了浅层生物气成藏条件、特征和分布规律。研究表明,长江三角洲晚第四纪发育3期下切河谷,形成了3套沉积层序;因后期河流的强烈下切破坏,早期沉积层序往往被剥蚀殆尽,仅残留下部的河床相粗粒沉积,造成不同期河床相的叠置;相对而言,末次冰期以来形成的下切河谷沉积层序以相对完整的沉积相组合被保存下来。长江三角洲浅层天然气是未经运移的原生生物气,其主要富集于末次冰期以来的沉积层序内,气藏为自生自储同生型的岩性圈闭。河口湾—河漫滩和浅海相泥质沉积物既是气源岩,又是盖层,后者可作为良好的区域盖层;河口湾—河漫滩和河床相砂质沉积物为主要储集层。因此,研究区晚第四纪多期下切河谷沉积层序有利于浅层生物气藏的形成,特别是晚期下切河谷内河口湾—河漫滩相砂质透镜体以及河床相砂体可作为优先勘探目标。     

鄂尔多斯盆地LFP区块长2段沉积相研究

储层的沉积相研究通常是油气藏勘探开发过程中一项十分重要的任务,它控制着储集砂体的成因类型及宏观分布。在岩芯观察的基础上,结合综合录井资料和野外露头剖面信息,运用沉积学、沉积构造、剖面结构、古生物及测井相等划分沉积相的标志,对研究区内钻井进行单井沉积相划分,对不同钻井之间的沉积相进行综合比对,结果认为LEP区块长2段主要从三角洲前缘高建设的水下分流河道骨架砂体沉积为主。     

Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.