含油气沉积盆地古地温研究方法

沉积盆地油气的生成与古地温有密切的关系,研究沉积盆地古地温的方法有许多,且各种方法都有其独特的优点.本文主要论述镜质体反射率、荧光光谱分析、裂变径迹及一些地质温度计等常用的研究沉积盆地油气源岩成熟度和热历史的方法及这些方法在研究盆地古地温地质模式。指导油气勘探中的应用.     

Analysis of the extinction of the Late Cretaceous foraminifer Afrobolivina afra

Afrobolivina afra, a Late Cretaceous bolivinid foraminifer, became extinct in the Early Paleocene. It was succeeded by the smaller, morphologically similar species Afrobolivina africana. Morphological variation in A. afra was in part correlated with environmental factors showing a pattern of random fluctuations about long-term ecological trends. A gradual, persistent and unbroken environmental trend, related to a eustatic fall in sea-level, is significantly correlated with the morphological evolution of the species. The micro-biogeography of A. afra at the time it was approaching extinction is consistent with its having given rise to A. afracana allopatrically in a manner which can be described by a fold-catastrophe adaptive model. This mode predicts that A. afra should undergo quantum evolution to A. africana in a restricted area in a near-shore environment.However, detailed study of borehole material reveals an apparent parabolic increase in the overall size of A. afra prior to extinction and it is argued that as a result, A. africana cannot be the direct descendant of A. afra without there having been some “discontinuity” in the environment or evolutionary process. This suggests that the sudden replacement of a species by a smaller, morphologically similar form may not be a straightforward succession. The apparent parabolic increase in size of A. afra can be modelled by the fold catastrophe of Thom theory if interpreted as representing the initial phase of a form of adaptive quantum evolution in which a gradual environmental change causes a fitness peak to be absorbed into the flank of a higher peak.In terms of such a model, the absence of a larger descendant species suggests that A. afra could have been replaced by A. africana before the quantum threshold had been reached. A possible cause for this could be that the changes in the environment might have lowered the height of the fitness function in the vicinity of the peak for A. afra to below that of the peak for A. africana, or vice versa.     

Identifying trends in groundwater quality using residence time indicators: an example from the Permian aquifer of Dumfries, Scotland

The Permian sandstone and breccia aquifer of Dumfries has an important role in supplying water to the principal town in southwest Scotland. The area comprises mainly pastoral farmland with some industry and fish farming. Ongoing development of the aquifer has revealed the existence of complex groundwater flow through fractures and increasing nitrate concentrations. To further investigate these issues, the age and quality of groundwater throughout the aquifer has now been assessed using standard hydrogeochemical techniques together with CFCs and SF₆ as residence time indicators. The aquifer consists of sandstone- and breccia-dominated units: the Locharbriggs Sandstone in the east and the Doweel Breccia in the west. Groundwater throughout the aquifer is of Ca–Mg–HCO₃ type and moderately mineralised; pH is near neutral. The observed groundwater chemistry is the product of maritime rainfall modified by the dissolution of carbonate material in the breccia, sandstone and surficial deposits. CFC and SF₆ concentrations are interpreted on the basis of mixing between older (>50 years) and recent (1990s) components. Although there is generally a higher proportion of older water within the Locharbriggs Sandstone compared to the Doweel Breccia, stable isotope evidence suggests that the older water component in the interbedded sandstones of the breccia is of much greater antiquity, possibly containing an element of palaeowater. Concentrations of nitrate across the aquifer can be directly related to the amount of recent recharge. Modern groundwater contains approximately 9 mg l^–1 NO₃-N and pre-1950s groundwater has approximately 2 mg l^–1 NO₃-N. Nitrate concentrations measured at individual boreholes are explained by the relative proportions of modern and pre-1950s groundwater. If current practices continue, the concentrations of nitrate measured across the Dumfries Basin will rise as the proportion of pre-1950s groundwater diminishes.

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Resumen El acuífero de areniscas y brechas Pérmicas de Dumfries desempeña un papel importante en el abastecimiento a la ciudad principal del Sudoeste de Escocia. El área comprende sobretodo tierras de pastoreo y granjas, junto con algunas industrias y piscifactorías. El desarrollo iniciado en el acuífero ha revelado la existencia de un complicado flujo subterráneo a través de las fracturas y de un aumento progresivo en la concentración de nitrato. Con el fin de profundizar en el conocimiento de estos temas, se ha determinado la edad y calidad de las aguas subterráneas en todo el acuífero por medio de técnicas hidrogeoquímicas estándar y de indicadores del tiempo de residencia como los clorofluorcarbonados (CFCs) y el fluoruro de azufre (SF₆). El acuífero está formado por las areniscas de Locharbriggs, al Este, y las brechas de Doweel, hacia el Oeste. Las aguas subterráneas son de tipo bicarbonatadas cálcico-magnésicas y presentan una mineralización moderada, mientras que el pH es prácticamente neutro. La química de las aguas subterráneas es el resultado del aerosol marino modificado por la disolución de materiales carbonatados en las brechas, areniscas y depósitos superficiales. Las concentraciones de CFCs y SF₆ se interpretan a partir de una mezcla de aguas entre una componente antigua (más de 50 años) y una reciente (de la década de 1990). Aunque en general se da una mayor proporción de aguas antiguas en las areniscas de Locharbriggs que en las Brechas de Doweel, los isótopos estables sugieren que la componente de aguas antiguas en las intercalaciones de areniscas que aparecen en la formación de brechas es mucho más antigua, y que, posiblemente, se trate de paleoaguas. Las concentraciones de nitrato en el acuífero pueden ser relacionadas directamente con la aportación de recarga reciente. Las aguas subterráneas modernas contienen aproximadamente 9 mg l^–1 de nitrato, mientras que las aguas subterráneas anteriores a 1950 tienen unos 2 mg l^–1. Se puede explicar las concentraciones de nitrato en pozos individuales por las proporciones relativas de aguas subterráneas modernas y anteriores a 1950. Si las prácticas actuales continúan, se producirá un aumento de las concentraciones de nitrato en la cuenca de Dumfries debido a la disminución de la proporción de aguas antiguas.

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Résumé L'aquifère des grès et brèches du Permien de Dumfries joue un rôle important dans l'alimentation en eau de la principale ville du sud-ouest de l'Écosse. La région est principalement soumise à de l'élevage pastoral avec quelques industries et des piscicultures. La progression de l'exploitation de cet aquifère a révélé l'existence d'un écoulement souterrain complexe en fractures et des concentrations en nitrate croissantes. Dans le but d'étudier ces deux points plus en détail, l'âge et la qualité de l'eau souterraine dans tout l'aquifère ont été évalués en utilisant des techniques hydrogéochimiques conventionnelles avec les CFC et SF₆ comme marqueurs du temps de séjour. L'aquifère est constitué par des unités dominées par des brèches et des grès: les grès de Locharbriggs à l'est et les brèches de Doweel à l'ouest. L'eau souterraine dans tout l'aquifère a un faciès bicarbonaté calcique et magnésien et est moyennement minéralisée; le pH est proche de la neutralité. Le chimisme observé de l'eau souterraine résulte des apports marins par la pluie modifiés par la dissolution du matériau carbonaté des brèches, des grès et des formations superficielles. Les concentrations en CFC et SF₆ sont interprétées sur la base d'un mélange entre des composantes ancienne (>50 ans) et récente (années 1990). Bien qu'il y ait en général une plus forte proportion d'eau ancienne dans les grès de Locharbriggs que dans la brèche de Doweel, les isotopes stables suggèrent que la composante d'eau ancienne dans les grès interstratifiés des brèches est beaucoup plus ancienne, contenant probablement un élément d'eau fossile. Les concentrations en nitrate dans l'aquifère peuvent être directement reliées au taux de recharge récente. L'eau souterraine moderne contient approximativement 9 mg l^–1 en NO₃-N et l'eau souterraine d'avant 1950 environ 2 mg l^–1 en NO₃-N. Les concentrations en nitrate mesurées dans des forages individuels sont expliquées par des proportions relatives d'eaux souterraines moderne et antérieure à 1950. Si les pratiques actuelles continuent, les concentrations en nitrate mesurées dans le bassin de Dumfries augmenteront alors que la part de l'eau souterraine d'avant 1950 diminuera.

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Subcritical compaction and yielding of granular quartz sand

Cylindrical samples of water-saturated, initially loose, St. Peter quartz sand were consolidated using triaxial deformation apparatus at room temperature, constant fluid pressure (12.5 MPa), and elevated confining pressures (up to 262.5 MPa). The samples were deformed along four loading paths: (1) hydrostatic stressing tests in which confining pressure was monotonically increased; (2) hydrostatic stress cycling similar to (1) except that effective pressure was periodically decreased to initial conditions; (3) triaxial deformation at constant effective pressure in which differential stress was applied after raising effective pressure to an elevated level; and (4) triaxial stress cycling similar to (3) except that the axial differential stress was periodically decreased to zero. Hydrostatic stressing at a constant rate results in a complex nonlinear consolidation response. At low pressures, large strains occur without significant acoustic emission (AE) activity. With increased pressure, the stress versus strain curve becomes quasi-linear with a corresponding nonlinear increase in AE rates. At elevated pressures, macroscopic yielding is marked by the onset of large strains, high AE rates, and significant grain failure. Stress cycling experiments show that measurable inelastic strain occurs at all stages of hydrostatic loading. The reload portions of stress cycles are characterized by a poro-elastic response and lower AE rates than during constant rate hydrostatic stressing. As the stress nears and exceeds the level that was applied during previous loading cycles, strain and AE rates increase in a manner consistent with yielding. Triaxial stressing cycles achieve greater consolidation and AE rates than hydrostatic loading at similar mean stress levels. By comparing our results with previously published studies, we construct a three-component model to describe elastic and inelastic compaction of granular sand. This model involves acoustically silent grain rearrangement that contributes significant inelastic strain at low pressures, poro-elastic (Hertzian) deformation at all pressures, and inelastic strain related to granular cracking and particle failure which increases in significance at greater pressures.     

西倾山隆起带龙家沟组的厘定及其沉积特征

通过大比例尺区域地质调研,对西倾山地区的一套粗碎屑岩地层,依据植物化石及含煤线等特征,厘定为下侏罗统龙家沟组(Jlj);根据岩石、岩性组合、沉积构造及沉积环境等特征的研究,认为该套地层为晚印支期西秦岭褶皱成山后,山间断陷盆地中由曲流河所形成的产物;近年来发现,该套地层中有金矿产出。客观地认识和识别该套地层,对拓宽该区金矿勘查,具有现实意义。     

鲁奎山铁矿逆冲推覆系与成矿

对鲁奎山向斜东西两翼构造变形、赋矿特征、成矿规律、控矿因素的分析，及在东翼开展地质物探综合找矿中发现，早期鲁奎山裂陷槽中、昆明群大龙口组的含菱铁质矿源层。卷入构造变形变质后已经历不同层间剥滑构造多次错移或碾碎。后期次生淋漓富集，含矿热液交代蚀变和层间滑剥构造再次叠加改造，改变原来沉积变质含菱铁质矿源层或贫矿体的属性，形成类似于原生沉积、又具有热液交代蚀变和构造岩特征的层状富铁矿体。经坑道进一步揭露证实，沿鲁奎山向斜东西两翼断续分布、已经二次富集成矿的各矿床(点)，实际上是在具层间构造性质的环形断裂带控制下所形成的沉积变质后生矿床类型。表～浅部脆性断裂形成的热液交代与充填脉状矿体，局部叠加在沿环形断裂带内“层状”矿体之上，增加了找寻厚大巢状矿体的可能性。这一新的成矿与控矿规律，为重新认识原“鲁奎山式沉积变质铁矿床”提供了实践基础，同时也为在该区域找矿指明方向。     

Investigation of the pyrolytic liberation of molecular nitrogen from Palaeozoic sedimentary rocks

Open-system non-isothermal pyrolysis up to 1,200°C in combination with elemental analysis was used to study the thermal liberation of molecular nitrogen (N₂) from sedimentary rocks and kerogen concentrates of Palaeozoic age from the Central European Basin system and an Eocene shale (Liaohe Basin, China) with a high content (36%) of ammonium feldspar (buddingtonite). The N/C_org (atomic) ratios of the kerogen concentrates ranged from 0.005 to 0.014, which represents the range commonly observed for coals. Bulk N/C_org ratios of the Palaeozoic shales extended from 0.035 to 0.108, indicating the presence of significant amounts of inorganic nitrogen. Namurian A and A-B (CnA; CnA-B) samples typically exhibited the earliest onset of N₂ generation with intense, characteristic peaks around 600°C. N₂ liberation from the buddingtonite-rich sample occurred at higher temperatures, with a broad peak around 700°C. Pyrograms of the kerogen concentrates showed no or strongly reduced N₂ generation in the 500–700°C range. On-line isotope-specific analysis of the pyrolytically liberated N₂ on one sample revealed a variability of ∼10‰ in the δ¹⁵N values and a steady increase in δ¹⁵N with temperature during the main phase of N₂ generation.     

Provenance of the Upper Cretaceous to upper Eocene clastic sediments of the Western Cordillera of Ecuador: Geodynamic implications

The Late Cretaceous–Eocene clastic deposits of the Western Cordillera of Ecuador record significant changes in the source areas, grain size, and location of the depocenters, related to the accretion of oceanic terranes that constitute the present-day Western Cordillera and Coast. Major changes in the source areas occurred in the ?late Maastrichtian and ?late middle Eocene. They are interpreted as corresponding to the accretion of the Guaranda and Macuchi oceanic terranes, respectively. Major increases in the grain sizes occurred in the ?late Maastrichtian, late Paleocene(?), and ?late middle Eocene, and seem to coincide with the accretion of the Guaranda, Piñón, and Macuchi terranes, respectively. The increasing occurrence of plutonic or metamorphic fragments and the westward shift of the depositional areas through the Paleocene–upper Eocene interval indicate an increasing uplift and erosion of the Cordillera Real. Continuous, although jerky, uplift of the latter during the Maastrichtian–Eocene period, supports the idea that the accreted oceanic material contributed to the crustal thickening and relief creation of the Ecuadorian Andes.     

河北张北M6.2地震前怀来地震台的中短期异常

基于强震前主破裂潜在变化过程中产生的地壳形变异常及伴随地壳形变而产生的地下水化学前兆现象随时间变化显示出的动态异常，依据河北怀来地震台形变、地下流体观测资料，研究了1998年河北张北M6．2地震前地形变、地下流体异常特性及同步性，认为其有由短期向临震演化的不同阶段的群体演化特征。形变异常早于流体异常出现，临震异常集中，反映明显。断层气CO2、水汞体应变异常同时在震前2个月出现，显示出异常的集中性、同步性。     

Evolution history of the Hidaka-oki (offshore Hidaka) basin in the southern central Hokkaido, as revealed by seismic interpretation, and related tectonic events in an adjacent collision zone

Off the southern coast of Hokkaido the Hidaka-oki (offshore Hidaka) basin has developed on the western flank of a collision suture under the influence of long-standing compressional plate motion and provoked tectonic stresses around the northwestern Pacific rim throughout the late Cenozoic. The basin forming history of the Japan arc and Kuril arc collision zone is described on the basis of seismic reflection data interpretation. We identify two stages of basin formation: the older (late Oligocene-Miocene) faulted en echelon graben (pull-apart basin) and younger (Plio-Pleistocene) regional downwarping. Paleoenvironmental changes recorded within the fore-arc sediments indicate that the older basin filled up by the late Miocene. We inferred the volumes of the distinctive basins from the depth-conversion of seismic data, which suggest episodic uplifts and massive erosion of the Hidaka Mountains in the middle-late Miocene and the Plio-Pleistocene. Estimated sediment supply rates into the basins have a similar level for the both stages. Cause of an episodic uplift in the older stage is attributed to the delayed opening of the Japan Sea. The eastern Eurasian margin underwent N-S right-lateral faulting at 25 Ma as a result of rifting of the Kuril back-arc basin. Formation of the Japan Sea back-arc basin since the early Miocene (ca. 20 Ma) caused eastward motion of the western Hokkaido block and transpressive regime along the pre-existing N-S shear deformation zone.