河北省崆山白云洞成因与演化

河北省崆山白云洞发育在以中寒武统张夏组为主的碳酸盐岩地层中,平面形态主要受NNW向、NE向和近EW向断裂控制,垂向上可分为3层,各层洞穴以沿陡倾断裂侵蚀、溶蚀而成的通道相连.第一层厅堂状溶洞(天堂、人间和地府)沿NNW向断裂展布,形成于早更新世中晚期;第二层格网状洞穴(迷宫和龙宫上部)沿NNW.和NE向断裂发育,形成于中更新世中期—晚更新世初;第三层形态曲折的廊道形洞穴(龙宫下部)主要追踪NE和NNW向断裂延伸,形成于晚更新世晚期—早全新世初期.在白云洞形成发育过程中,曾经历了多次构造运动破坏.现今的白云洞,景观损毁、岩石破裂严重,灾害承受力低,因此洞穴结构稳定性保护和洞穴地质环境治理是当前重要而紧迫的任务.     

Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system

The study of groundwater hydrogeochemistry of the Paleozoic Basses-Laurentides sedimentary rock aquifer system in Québec produced a large geochemical dataset. Groundwater samples were collected at 153 sites over a 1500 km² study area and analyzed for major and minor ions. The large number of data can lead to difficulties in the integration, interpretation and representation of the results. Two multivariate statistical methods, hierarchical cluster analysis (HCA) and principal components analysis (PCA), were applied to a subgroup of the dataset to evaluate their usefulness to classify the groundwater samples, and to identify geochemical processes controlling groundwater geochemistry. This subgroup consisted of 144 samples and 14 parameters (Ca²⁺, Mg²⁺, Na⁺, K⁺, , Cl⁻, , Fe²⁺, Mn²⁺, Br⁻, Sr²⁺, F⁻, Ba²⁺, HS⁻). Seven geochemically distinct clusters, C1–C7, resulted from the HCA. Samples from clusters C3, C4, C6 and C7 are mostly located in preferential recharge areas. The majority of these samples have Ca–Mg–HCO₃ recharge groundwater (C3, C6, C7) and Na–HCO₃ evolved groundwater (C4). Samples from the other three clusters (C1, C2, C5) are characteristic of an aquifer system under confined conditions. The majority of these samples have Na–HCO₃ evolved groundwater (C1, C5) and Na–Cl ancient groundwater that exhibits elevated concentrations in Br⁻ (C2). In addition to recognizing the importance of hydrogeological conditions on groundwater geochemistry, the distribution of clusters also showed the importance of the geological formations on minor and trace elements, such as Fe²⁺, Mn²⁺, Sr²⁺, F⁻ and Ba²⁺. The first five components of the PCA account for 78.3% of the total variance in the dataset. Component 1 is defined by highly positive loadings in Na⁺, Cl⁻ and Br⁻ and is related to groundwater mixing with Champlain Sea water and solute diffusion from the marine clay aquitard. The high positive loadings in Ca²⁺ and Mg²⁺ of component 2 suggest the importance of dissolution of carbonate rocks in this aquifer system. From their characteristic loadings, the first two components are defined as the “salinity” and “hardness” components, respectively. Components 3–5 are related to more local and geological effects. The integration of the HCA and the PCA, with conventional classification of groundwater types, as well as with the hydrogeological and geological contexts, allowed the division of the region into four main geochemical areas, providing an improved regional picture of the aquifer system dynamics and hydrogeochemical evolution of groundwater. The following factors were recognized as influencing the evolution of groundwater identified in every geochemical area: (1) geological characteristics including sedimentary rock type and till mineralogy; (2) hydrogeological characteristics represented by the level of confinement and the hydraulic gradient; and (3) the geological history including the latest glaciation and the Champlain Sea invasion. With its integrated approach, this hydrogeochemical study contributes to the characterization and understanding of complex groundwater flow systems, and provides an example of the long-term geochemical evolution of hydrogeological systems after a major perturbation, in this case seawater invasion.     

Multi‐process Late Quaternary landscape evolution modelling reveals lags in climate response over small spatial scales

Landscapes evolve in complex, non‐linear ways over Quaternary timespans. Integrated geomorphological field studies usually yield plausible hypotheses about timing and impact of process activity. Landscape Evolution Models (LEMs) have the potential to test and falsify these landscape evolution hypotheses. Despite this potential, LEMs have mainly been used with hypothetical data and rarely to simulate the evolution of an actual landscape. In this paper, we use a LEM (LAPSUS: LandscApe ProcesS modelling at mUlti dimensions and scaleS) to explore if it is possible to test and falsify conclusions of an earlier field study on 50 ka landscape evolution in Okhombe Valley, KwaZulu Natal, South Africa. In this LEM, five landscape processes interact without supervision: water driven erosion and deposition, creep, solifluction, biological weathering and frost weathering. Calibration matched model results to three types of qualitative fieldwork observations: individual process activity over time, relative process activity over time and net landscape changes over time. Results demonstrate that landscape evolution of the Okhombe valley can be plausibly simulated. A particularly interesting and persistent feature of model results are erosional and depositional phases that lag climatic drivers both by decades, and by several ka within a few hundred meters. The longer lag has not been reported for this spatial scale before and may be an effect of slow landscape‐soil‐vegetation feedbacks. The combined modelling and fieldwork results allow a more complete understanding of these responses to climate change and can fill in hiatuses in the stratigraphical record. Suggestions are made for methodological adaptations for future LEM studies. Copyright © 2009 John Wiley & Sons, Ltd.     

Electro‐Catalytic Degradation of Phenol Organics with SnO2‐Sb2O3/Ti Electrodes

The effect of extraordinary degradation of phenol organics on the SnO₂‐Sb₂O₃/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm^–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO₂/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO₂‐Sb₂O₃/Ti was superior to that of the PbO₂/Ti electrode. At the same time, the SnO₂‐Sb₂O₃/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb₂O₃ layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO₂ part.     

川东地区嘉陵江组四段膏盐岩分布的沉积环境分析

四川盆地东部地区嘉陵江组嘉四段沉积环境是局限海台地蒸发岩相,水体封闭,有利成盐。以川东地区油气勘探的500余口实际钻井资料为基础,通过岩性微相的研究,探讨川东地区的古地貌特征,寻找成盐的微环境因素,有助于从区域上预测盐类的分布。T1j4盐湖主要分布在蒸发岩沉积中心——膏盆相,但位于膏盆相的周缘地带和膏盆内部堤坝周围,少部分分布在膏盆边缘相,区域上则主要分布在宣汉、达州、万县、云阳、垫江及渠县等地区,有一定的继承性。     

Sedimentary pellets as an ice-cover proxy in a High Arctic ice-covered lake

Sediment aggregates (“sedimentary pellets”) within the sedimentary record of Lake A (83°00′ N, 75°30′ W), Ellesmere Island, Canada, are used to construct a 1000 year proxy record of ice-cover extent and dynamics on this perennially ice-covered, High Arctic lake. These pellets are interpreted to form during fall or early winter when littoral sediment adheres to ice forming around the lake’s periphery or during summer through the development of anchor ice. The sediment likely collects in ice interstices and is concentrated in the upper ice layers through summer surface ice melt and winter basal ice growth. The pellets remain frozen in the ice until a summer or series of summers with reduced ice cover allows for their deposition across the lake basin. Sedimentary pellet frequency within multiple sediment cores is used to develop a chronology of ice-cover fluctuations. This proxy ice-cover record is largely corroborated by a record of unusual sedimentation in Lake A involving iron-rich, dark-orange to red laminae overlying more diffuse laminae with a lighter hue. This sediment sequence is hypothesized to represent years with reduced ice cover through increased chemocline ventilation and iron deposition. During the past millennium, the most notable period of inferred reduced ice cover is ca. 1891 AD to present. Another period of ice cover mobility is suggested ca. 1582–1774 AD, while persistent ice cover is inferred during the 1800s and prior to 1582 AD. The proxy ice-cover record corresponds well with most regional melt-season proxy temperature and paleoecological records, especially during the 1800s and 1900s.

Empirical site-specific response-spectra correction factors for the Gubbio basin (central Italy)

Providing quantitative microzonation results that can be taken into account in urban land-use plans is a challenging task that requires collaborative efforts between the seismological and engineering communities. In this study, starting from the results obtained by extensive geophysical and seismological investigations, we propose and apply an approach to the Gubbio basin (Italy) that can be easily implemented for cases of moderate-to-low ground motion and that takes into account not only simple 1D, but also more complicated 3D effects.     

Sedimentary impacts from landslides in the Tachia River Basin, Taiwan

A case study of coseismic landslides and post-seismic sedimentary impacts of landslides due to rainfall events was conducted in the Tachia River basin, Taichung County, central Taiwan. About 3000 coseismic landslides occurred in the basin during the M_L 7.3 Chi-Chi earthquake in 1999. The deposits from these landslides provided material for numerous debris flows induced by subsequent rainfall events. The estimated 4.1 × 10⁷ m³ of landslide debris produced in the upland area caused sediment deposition in riverbeds, and flash floods inundated downstream areas with sediment during torrential rains. The landslide frequency-size distributions for the coseismic landslides and the subsequent rainfall-induced landslides were analyzed to determine the sediment budgets of the post-seismic geomorphic response in the landslide-dominated basin. Both the coseismic and the rainfall-induced landslides show a power–law frequency-size distribution with a rollover. It was found that the rainfall-induced landslide magnitude was smaller than the coseismic one, and that both have comparable negative scaling exponents in cumulative form, of about − 2.0 for larger landslides (> 10^− 2 km²). This may be attributed to ongoing movement or reactivation of old landslides, and a natural stabilisation of small landslides between 10^− 4 and 10^− 2 km². It is proposed that the characteristics of geological formations and rainfall as well as changes in landslide area are reflected in the power–law distribution.     

华北地下水位强震短期异常演化及前兆判别标志研究

对地下水位地震前兆异常开展了参数提取方法的研究, 并以其提取的结果为输入, 对1984～2002年华北地区地下水位异常参数分布做了全时空扫描, 继而将全部图像与华北地区构造活动性量化评估的数字化图像进行了叠加, 实现了地下水位异常动态扫描与区域构造活动性背景的结合。 在此基础上, 对1985年以来华北地区5级以上地震前的地下水位短期图像演化情况做了全面分析, 提取出了判别异常区的指标以及地震短期异常区的演化特征, 并最终建立了华北地区强震前地下水位短期前兆的判别标志。     

古河道沉积体系与赋铀性

本文地各类河流沉积特点的研究,结合铀的地球化学行为,探讨河流沉积体系的赋铀性。