羌塘盆地中部地区地壳S波速度结构及构造意义

羌塘盆地是我国最大的海相盆地.本文根据在羌塘盆地内布设的27个宽频带地震观测台站记录的远震波形数据,利用非线性复谱比反演算法得到各台站下方100 km深度范围内S波速度结构.结果表明.羌塘地区Moho深度较为平缓,平均深度为61 km;北羌塘地壳内低速层广泛分布;北羌塘具有两个较大的沉积盆地,龙尾错和白滩湖坳陷,沉积厚度分别有10 km和15 km.尽管北羌塘下地壳受到强烈的新生代火山岩作用改造,但是这种深部岩浆热作用会加速烃源岩中有机质的热演化历程.北羌塘两个盆地具有很好的油气前景.与北羌塘低速层分布相比,南羌塘下低速层更深,可能与班公怒江洋于中生代的俯冲消减及拉萨地体北向俯冲有关.     

江西相山酸性火山-侵入杂岩精确年代学与演化序列研究

相山火山盆地主体岩石为一套由熔结凝灰岩、流纹英安岩、流纹英安斑岩、碎斑熔岩、粗斑花岗斑岩及似斑状花岗岩组成的酸性火山-侵入杂岩体, 构成了两个完整的喷发-溢流(侵出)-侵入的岩浆活动亚旋回。本文在野外地质调查的基础上, 采用SIMS、LA-ICP-MS技术对主要岩类进行了高精度的锆石U-Pb年代学研究, 并建立了火山-侵入杂岩体的演化序列。结果表明, 打鼓顶组熔结凝灰岩代表了相山火山-侵入活动的最早期产物, 其锆石U-Pb年龄为140.7±2.7 Ma、140.1±1.8 Ma和138.2±1.6 Ma, 第一亚旋回主体流纹英安岩的锆石U-Pb年龄135.0±1.8 Ma。鹅湖岭组熔结凝灰岩代表了火山-侵入活动的第二亚旋回的开始, 其U-Pb年龄为135.6±1.2 Ma, 第二亚旋回主体碎斑熔岩的锆石U-Pb年龄133.6±1.3 Ma, 沙洲单元的粗斑花岗斑岩和似斑状花岗岩属于该亚旋回最晚期的侵入岩, 其锆石U-Pb年龄代表了相山火山-侵入活动的结束时间(分别为133.4±1.2 Ma和133.9±1.1 Ma)。相山早白垩世火山-侵入活动延续时间较短, 整体上呈现一个连续的过程, 初始时间在141 Ma附近, 结束时间在132 Ma左右。概言之, 第一亚旋回(141~135 Ma)以形成熔结凝灰岩、流纹英安岩和流纹英安斑岩为主, 第二亚旋回(135~132 Ma)以熔结凝灰岩、碎斑熔岩、粗斑花岗斑岩和似斑状花岗岩为主。岩石地球化学和野外地质特征也与两个亚旋回火山-侵入岩浆活动相吻合。     

Evaluating new fault-controlled hydrothermal dolomitization models: Insights from the Cambrian Dolomite,Western Canadian Sedimentary Basin

Fault-controlled hydrothermal dolomitization in tectonically complex basins can occur at any depth and from different fluid compositions, including ‘deep-seated’, ‘crustal’ or ‘basinal’ brines. Nevertheless, many studies have failed to identify the actual source of these fluids, resulting in a gap in our knowledge on the likely source of magnesium of hydrothermal dolomitization. With development of new concepts in hydrothermal dolomitization, the study aims in particular to test the hypothesis that dolomitizing fluids were sourced from either seawater, ultramafic carbonation or a mixture between the two by utilizing the Cambrian Mount Whyte Formation as an example. Here, the large-scale dolostone bodies are fabric-destructive with a range of crystal fabrics, including euhedral replacement (RD1) and anhedral replacement (RD2). Since dolomite is cross-cut by low amplitude stylolites, dolomitization is interpreted to have occurred shortly after deposition, at a very shallow depth (<1 km). At this time, there would have been sufficient porosity in the mudstones for extensive dolomitization to occur, and the necessary high heat flows and faulting associated with Cambrian rifting to transfer hot brines into the near surface. While the δ¹⁸O_water and ⁸⁷Sr/⁸⁶Sr ratios values of RD1 are comparable with Cambrian seawater, RD2 shows higher values in both parameters. Therefore, although aspects of the fluid geochemistry are consistent with dolomitization from seawater, very high fluid temperature and salinity could be suggestive of mixing with another, hydrothermal fluid. The very hot temperature, positive Eu anomaly, enriched metal concentrations, and cogenetic relation with quartz could indicate that hot brines were at least partially sourced from ultramafic rocks, potentially as a result of interaction between the underlying Proterozoic serpentinites and CO₂-rich fluids. This study highlights that large-scale hydrothermal dolostone bodies can form at shallow burial depths via mixing during fluid pulses, providing a potential explanation for the mass balance problem often associated with their genesis.     

Geochemical characteristics and sedimentary environment of the Middle Devonian organic-rich shales in the Northwest of Guizhong Depression,Southwest China

In order to figure out the redox conditions and paleo-sedimentary environment of the Middle Devonian shales in the northwest of Guizhong Depression, the trace element analysis was conducted on the Middle Devonian cores (320.35–938.50 m) of the typical shale gas investigation well (GY-1) at a 1.50 m sampling interval through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). According to the test result, the average values of V/(V+Ni), V/Cr and Ni/Co in Nabiao formation (Fm.) are larger than 0.67, 4.65 and 7.71 respectively, and Nabiao Fm. is rich in biological assemblages such as tabasheer, ammonite, etc. These evidences indicate the rising sea level rose relatively in the sedimentation period of Nabiao Fm. and a deepwater shelf environment, which was favorable for the preservation of organic matters. The V/(V+Ni), V/Cr and Ni/Co in Luofu Fm. and Tangting Fm. are 0.38–0.65, 0.73–4.10 and 3.70–6.72 respectively, indicating that the sea level dropped relatively in their sedimentation period, during which the water bodies became shallow, and the sedimentary environment was a weak oxidizing shallow water shelf environment. In addition, the variation of TOC has a high correlation with the enrichment degree of Ba element, indicating the favorable conditions for the enrichment and preservation of organic matters under an oxygen-deficient environment. Moreover, according to the identification of trace element indexes, the northwest of Guizhong Depression experienced the sedimentary cycle of relative rise to relative fall of sea level from bottom to top in the Middle Devonian sedimentation period. The relative sea level rose to the highest in the sedimentation period of Nabiao Fm., in which the organic-rich shales with stable thickness and high organic content were deposited. Hence, the Nabiao Fm. could be regarded as the favorable exploration target interval in this area.     

贵州省松桃县木耳溪锰矿地质特征及找矿方向

贵州松桃县木耳溪锰矿为典型的层控型锰矿床,矿体呈层状赋存于南华系下统大塘坡组第一段(Pt2b3d 1)底部的炭质页岩中,产出层位稳定,矿体产状与围岩产状一致。通过统计对比,锰矿层的矿化程度与含锰岩系的厚度呈正比,即当南华系大塘坡组地层厚度大于15m时,有可能成为锰矿的主要找矿方向。     

西昌盆地上三叠统白果湾组富有机质泥页岩沉积岩相古地理与孔隙特征

海陆过渡相富有机质泥页岩是页岩气勘查开发的重要领域。本文以西昌盆地上三叠统白果湾组富有机质泥页岩为研究对象,对研究区内富有机质泥页岩的沉积岩相古地理特征、微观孔隙类型、孔隙结构特征进行研究。白果湾组富有机质泥页岩段沉积相主要为湖泊相、三角洲相、河流相。发育不同类型的微孔隙,孔隙主要以小孔为主,微孔次之,平均孔径分布在5.56~56.89nm之间,比表面积平均为9.44m²/g,总孔体积平均为0.0187cm³/g。页岩气主要形成于滨浅湖亚相及半深湖亚相中,并主要吸附于富有机质泥页岩的小孔、微孔内;西昌盆地白果湾组富有机质泥页岩储集空间较好,具有良好的勘探潜力。     

豫西中元古代汝阳群微生物形成的沉积构造简介

豫西地区中元古代汝阳群砂岩中普遍发育微生物形成的沉积构造(Microbial Induced Sedimentary Strutures),简称MISS构造,这些MISS构造在过去通常被误认为前寒武纪后生动物遗迹化石。本文对豫西地区中元古代汝阳群MISS构造的形态、结构及显微构造特征进行了详细地分析研究,结果表明该区发育的MISS构造有4种类型:多边形网状裂隙构造、纺锤形裂隙、鸟足形裂隙和典型的正弦曲线型Manchuriophycus构造。豫西地区中元古代汝阳群微生物形成的沉积构造的发现,不仅表明这些砂岩层面上曾经存在微生物席活动,对今后与一些微生物席活动有关的沉积构造的研究有着重要的借鉴意义,为过去被误认为各种遗迹化石的修定提供了证据,而且对恢复前寒武纪沉积古地理具有重要的意义。     

广东新丰江水库XFJ-1孔DDTs和HCHs的沉积记录

以~(210)Pb对广东新丰江水库XFJ-1孔进行了定年,以GC-ECD测定新丰江水库沉积钻孔中DDTs和HCHs的含量,通过对比其剖面变化特征与该类农药在我国的生产、使用历史,探讨了水库中DDT、HCH的历史输入途径.过去30年来,XFJ-1孔平均沉积速率为1.42cm/a,沉积物中HCHs和DDTs的含量分别为1.26-3.90ng/g和1.00-3.96ng/g.DDTs、HCHs含量从20世纪80年代初逐渐下降,总体上与我国1983年开始禁止DDT、HCH的大规模生产和使用这一历史事件相符.DDTs、HCHs及其化合物比值的剖面变化特征均表明:流域内后期土壤侵蚀、搬运的再循环污染物质(即二次污染源)对水库DDT和HCH的贡献不明显;相反,农药历史使用(即一次污染源)是其主要来源,大气沉降是其主要输入途径.此外,γ-HCH、o,p′-DDT和p,p′-DDT含量的垂直变化表明,大规模禁用以后这些化合物仍有少量新的输入,需引起重视.     

Sedimentary control on the formation of a multi-superimposed gas system in the development of key layers in the sequence framework

Based on core observations, well logs and test results of siderite-bearing mudstone from the Benxi Formation to the Member 2 of the Shanxi Formations in the Linxing block, northeastern Ordos Basin, a logging identification model for siderite-bearing mudstone (key layer) was established. The porosity characteristics and sealing property were quantitatively evaluated by logging data. Sedimentary control on the formation of multi-superimposed gas-bearing system in the development of key layers in the sequence framework was also discussed. The results showed that the siderite-bearing mudstone has obvious logging response characteristics, e.g., high photoelectric absorption cross-section index (PE), high density (DEN), high amplitude natural gamma ray (GR), low acoustic (AC), low resistivity (M2RX) and low neutron porosity (CNCF). The quantitatively evaluated results of the porosity characteristics and sealing property for the key layer showed that the key layer has the characteristics of low porosity (with an average of 1.20 percent), low permeability (with an average of 2.29 × 10⁻⁸μm²), and high breakthrough pressure (with an average of 12.32 MPa) in the study area. This layer acts as an impermeable gas barrier in a multi-superimposed gas system. The results also indicated that the material composition of the multi-superimposed gas-bearing system can be established by the sequence stratigraphic framework. The sedimentary evolution results in a cyclic rhythm of material composition vertically. The spatial distribution of the corresponding transgressive event layer near the maximum flooding surface (MFS) in the sequence framework restricts the spatial distribution of the key layer with high breakthrough pressure and low porosity, which constitutes the gas-bearing system boundary. The siderite-bearing mudstone formed near the MFS in the second-order sequence and constitutes a stable comparison of the first-order gas-bearing system boundary, which has a wide range of regional distribution and stable thickness. The siderite-bearing mudstone formed near the MFS in the third-order sequence is often incompletely preserved due to the late (underwater) diversion channel erosion and cutting. This layer forms the coal-bearing reservoirs, which we termed as a second-order gas-bearing system in adjacent third-order sequences to form a uniform gas-bearing system.     

我国海洋经济劳动生产率区域差异与演变分析

劳动生产率差异是导致区域经济发展差异的重要原因,提高劳动生产率是促进经济增长的有效手段。分析我国海洋经济的劳动生产率的区域差异与演变对发展我国海洋经济具有积极意义。在分析我国海洋经济劳动生产率的特点基础上,文章运用基尼系数和泰尔指数计算我国沿海地区1997—2014年海洋经济劳动生产率区域差异,并进行σ-收敛性检验,结果表明区域差异呈现倒V字形走势,1997—2005年呈现σ-发散,2005—2014年呈现σ-收敛。采用泰尔指数分解方法测度表明,环渤海、长三角、泛珠三角三大经济区海洋经济劳动生产率地区内差异占总体差异的比重达80%以上,而地区间差异比重较小,环渤海经济区地区内差异最大。分阶段对我国各沿海地区海洋经济的劳动生产率进行排名并观察演变过程。提出提高我国海洋经济劳动生产率的相关建议:一是努力提高海洋经济全要素生产率;二是促进海洋产业合理布局,努力提高传统海洋产业劳动生产率;三是统筹区域海洋经济发展。