A comparison of the early diagenetic environment in intertidal sands and muds of the Manukau Harbour,New Zealand

The early diagenetic environment of intertidal sandy sediments (sands) and muddy sediments (muds) is described and compared from two cores taken from an unpolluted part of the Manukau Harbour, New Zealand. Extraction techniques characterized the form of the trace elements (Fe, Mn, S, C, Pb, Zn, Cu) at different depths in the sediment. Dissolved forms of Fe, Mn, and S were measured in interstitial water. Nonresidual metal concentrations, humic acid, FeS, and FeS₂ are an order of magnitude higher in the muds than in the sands because of dilution by unreactive sand particles. Muds contain a larger proportion of metals in the mobile fractions; exchangeable (Mn), carbonate (Mn, Fe, Zn), and easily-reducible oxide (Fe, Mn, Zn, Pb). This is due to greater surface area (for Mn adsorption); the favorable conditions for MnCO₃, FeCO₃, and FeS precipitation; and higher concentrations of easily reducible iron oxide and humic acid. Therefore, compared to the sands, muds are more important as reservoirs for toxic metals, both in terms of quantity and availability. At either site there was very little difference between the forms of Zn, Pb or Cu identified by sequential extraction as sediments changed from oxic to anoxic conditions. One reason for this is that the amounts and proportions of some of the important components that bind metals, viz., amorphous iron hydrous oxides, humic acids, and FeS₂, do not change much. Other components that do change with redox conditions, for example, manganese phases and FeS, are only minor components of the sediment. Redox conditions, then, have relatively little effect on trace-metal partitioning in the sediment matrix of these unpolluted sediments.     

Toxic metals in Venice lagoon sediments: model,observation, and possible removal

We have modeled the distribution of nine toxic metals in the surface sediments from 163 stations in the Venice lagoon using published data. Three entrances from the Adriatic Sea control the circulation in the lagoon and divide it into three basins. We assume, for purposes of modeling, that Porto Marghera at the head of the Industrial Zone area is the single source of toxic metals in the Venice lagoon. In a standing body of lagoon water, concentration of pollutants at distancex from the source (C ₀) may be given byC=C ₀e^–kx wherek is the rate constant of dispersal. We calculatedk empirically using concentrations at the source, and those farthest from it, that is the end points of the lagoon. Averagek values (ppm/km) in the lagoon are: Zn 0.165, Cd 0.116, Hg 0.110, Cu 0.105, Co 0.072, Pb 0.058, Ni 0.008, Cr (0.011) and Fe (0.018 percent/km), and they have complex distributions. Given thek values, concentration at source (C ₀), and the distancex of any point in the lagoon from the source, we have calculated the model concentrations of the nine metals at each sampling station. Tides, currents, floor morphology, additional sources, and continued dumping perturb model distributions causing anomalies (observed minus model concentrations). Positive anomalies are found near the source, where continued dumping perturbs initial boundary conditions, and in areas of sluggish circulation. Negative anomalies are found in areas with strong currents that may flush sediments out of the lagoon. We have thus identified areas in the lagoon where higher rate of sediment removal and exchange may lessen pollution.     

River adjustment to changes in sediment load: The effects of tin mining on the Ringarooma River,Tasmania, 1875–1984

The mining of alluvial tin in the Ringarooma basin began in 1875, reached a peak in 1900–20, and had virtually ceased by 1982. During that time 40 million m³ of mining waste were supplied to the main river, quickly replacing the natural bed material and requiring major adjustments to the channel. Based on estimates of sediment supply from more than 50 widely scattered mines and the frequency of flows capable of transporting the introduced load, the river's transport history is reconstructed using a mass-conservation model. Because of the lengthy time period (110 years) and river distance (75 km) involved, the model cannot predict detailed change but it does reproduce the main pattern of sediment movement in which successive phases of aggradation and degradation progress downstream. Peak storage is predicted in that part of the river where braiding and anastomosis are best developed. Aggradation was most rapid in the upper reaches close to major supply points, becoming slower and later with distance downstream. Channel width increased by up to 300 per cent where the valley floor was broad and braiding became relatively common. Bridges had frequently to be replaced. While bed levels were still rising in lower reaches, degradation began in upper ones, notably after 1950, and by 1984 had progressed downriver over 30 km. Rates of incision reached 0·5 m yr^?1, especially in the early 1970s when record high flows occurred. As a result of degradation the bed material became gravelly through either reexposure of the original bed or lag concentration of coarser fractions. Also a narrower unbraided channel has developed. The river is beginning to heal itself and upper reaches now have reasonably stable beds but at least another 50 years will be required for the river to cleanse its channel of mining debris.     

Physical and chemical characteristics of a metal-contaminated overbank deposit,west-central South Dakota,U.S.A.

A metal-contaminated overbank deposit in west-central South Dakota resulted from the discharge of a large volume of mine tailings into a river system between the late 1800s and 1977. The deposit along the Belle Fourche River is typically up to 2 m thick and extends about 90 m away from the channel along the insides of meander bends. The sediments contain above-background levels of copper, iron, manganese, zinc, and particularly arsenic, which is commonly two orders of magnitude above background level in the contaminated sediments. Carbonate minerals in the deposit limit the desorption of arsenic by preventing acid formation. Arsenic concentrations provide a measure of the dilution of mine tailings by uncontaminated sediment. The arsenic appears to have been transported and deposited as arsenopyrite, but is now at least partially associated with iron oxides and hydroxides. Within individual samples, arsenic concentration has an inverse relation with grain size that results from the more efficient accumulation of arsenic on the greater surface area of the smaller particles. Arsenic concentration is inversely related to the sample weight percent finer than 16 μm, however, as a consequence of the dilution of the contaminated sediments by uncontaminated sediment with a finer grain-size distribution. Dilution by uncontaminated sediment from tributaries cause arsenic concentrations to decrease by a factor of 3 along 100 km of floodplain. An influx at high streamflow of uncontaminated sediment from terraces and the premining floodplain as well as from tributaries causes arsenic concentrations in parts of the contaminated deposit that are farthest away from the channel to be two to three times less than arsenic concentrations in overbank sediment that is immediately adjacent to the channel.     

210Pb dating of scottish lake sediments,afforestation and accelerated soil erosion

Changes in the rate of soil erosion in lake catchments can be identified from changes in the rate of sediment accumulation in lakes. Here we compare recently afforested sites with non-afforested sites in the Galloway area of Southwest Scotland. We show that lakes with non-afforested catchments have slow, constant sediment accumulation rates, whereas lakes with recently afforested catchments have changes in accumulation that parallel the known history of afforestation. For Loch Grannoch the sediment accumulation rate increases from 0.1 cm yr^?1 to over 2 cm yr^?2 during the disturbance period. Data from L. Skerrow, however, suggest that the rate might decline to predisturbance levels after approximately 10 years as the forest canopy closes and drainage channels stabilize.     

Sediment yield estimated from reservoir siltation in the Ochil hills,Scotland

Measurements made on the floors of the temporarily-drained Glenfarg and Glenquey Reservoirs indicate that sediments with wet volumes of 63.94 × 10³ m³ and 12.64 × 10³ m³ were deposited in 56 and 73 years respectively. These figures represent 2.5 per cent and 1.1 per cent losses of original storage capacity. When corrected for water, organic, and diatom skeleton contents, and reservoir trap efficiency inorganic sediment yields of at least 31.3 tonnes km^?2 yr^?1 and of 9.0 tonnes km^?2 yr^?1 are suggested. The difference is probably related to contrasts of land use.     

Human influence upon sedimentation in Llangorse Lake,Wales

Palaeolimnological studies at Llangorse Lake, Wales, constitute part of the British contribution to IGCP Project 158 (The Palaeohydrology of the Temperate Zone in the Last 15000 Years). The lake has been adopted as the Reference Site for the South Wales region under Subproject 158B (Lake and Mire Environments) and is located in the Reference Area for Britain: the Severn Basin. Results of biological, physical, and multielement chemical analyses on a 12.35 m Livingstone core are presented and compared with previous analyses on short Mackereth cores taken from two troughs in the lake basin. Human impact upon post-glacial sedimentation is assessed with reference to sediment chemistry, physical properties, and sedimentation rates, based on relative pollen, ¹⁴C, and ²¹⁰Pb dating. Vegetational history of the catchment is inferred from a pollen diagram for a section of the core from c. 8 to 6.75 m depth in which evidence for human impact is first apparent. Water content, loss on ignition, and carbonate content are presented for the whole core; density, water content, loss on ignition, carbonates, and elemental analyses of P, Ca, Mg, K, Ti, Al, Fe, and Mn for the interval 6 75 and 8.25 m depth. Sedimentation rates were low during Boreal and Atlantic times (c. 9000- 5000 BP), rose significantly from the time of the elm decline (estimated at 5000 BP) and increased further at c. 1800 BP when nekron muds were succeeded by deposition of silty clay. Inferred rates of erosion of soils from the catchment are discussed and related to sediment chemistry.     

Fate of copper and cadmium in a sediment-water system,and effect on chitin degrading bacteria

Fate and effect of copper and cadmium on the degradation of chitin were studied in sediment microcosms. Artificial sediment was spiked with metals, and metal partitioning between sediment components, overlying water and bacteria was described. Most of the added metals were bound to sediment particles. Remarkable metal enrichments were found on Fe-oxide, Mn-oxide, and chitin. In sediments containing the nominal concentration of 100 mg/kg Cu, the chitin-degrading bacteria Cytophaga johnsonae showed a significant decrease in N-acetylglucoseaminidase activity. Toxicity of copper was attributed to free ions in the overlying water. The bacteria were more sensitive to copper than to cadmium. Inhibitory effects of cadmium were primarily caused by sediment-associated cadmium.     

PRESENT STATUS OF EXPERIMENTAL STUDY ON HEAVY METAL POLLUTANT ADSORPTION－DESORPTION BY SEDIMENT IN CHINA

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滆湖沉积物理化特征及磷释放腄

对滆湖表层底泥、柱状层祥和间隙水进行理化分析,模拟不同条件下的沉积物磷释放。结果表明,0～20cm深度范围内,各项理化指标变化较大;大于2cm后差异较小。当提高沉积物-水体系温度、降低氧含量(或Eh),提高pH及施以水动力作用时,可促进沉积物磷释放进程。无菌条件对磷释放有抑制作用。采用实验室模拟和间隙水浓度扩散模型计算得到的磷总释放量分别为10.65t/a和9.40t/a,其中湖面网围区释放量占全湖总量的28.2～35.4％。建议适度控制网围养殖规模,以减少内源磷污染。