湖南瑶岗仙矽卡岩型白钨矿床成矿流体演化特征研究

湖南瑶岗仙超大型钨矿床位于南岭成矿带中段,主要由石英脉型黑钨矿矿脉和矽卡岩型白钨矿矿体组成.前人对瑶岗仙石英脉型黑钨矿矿体开展了较为详细研究,但对矽卡岩型白钨矿的研究则相对较少,有关其矿体特征、成矿过程及其与石英脉型矿化的成因联系尚不清楚.本文在矿床地质研究基础上,将瑶岗仙矽卡岩型钨矿床分为早期石榴子石-透辉石-白钨矿...     

鄂东阮家湾矿床钨矿化过程的古水文地质—地球化学研究

在对阮家湾铜-钼-钨矿床白钨矿矿化进行野外及室内矿床地质工作的基础上,作者从古水文地质学和地球化学角度探讨了钨矿化机制。该矿床钨矿化具层控性,在沉积-成岩过程中,含矿地层中奥陶统碳酸盐岩中即有钨的初步富集,这主要和与含矿地层相邻的泥质岩所经历的水交替过程及地球化学作用有关,燕山晚期阮家湾岩体侵入后,钨得以再次富集,形成矿体。     

Geologic and geochemical features of the volatile-rich ore fluid and its tracing and dating in the Xuebaoding Beryl-Scheelite Vein Deposit, China

Laser Raman spectrochemical analysis on single inclusion reveals that multi-phase fluid inclusions exist in the Xuebaoding Beryl-Scheelite Vein Deposit. Besides the solid daughter mineral, there are vapor CO₂, liquid CO₂, water-deficient CO₂ and salt water solution from its center to the border. A close study on the fluid inclusion components and carbon, oxygen, helium and argon isotope tracing and dating suggests that the volatile-rich ore fluid might derive from postmagmatic fluid and rare element enrichment is the result of the mixture of the plutonic alkali granite with crustal material.     

Implications of U–Pb SHRIMP zircon data on the age and evolution of the Felbertal tungsten deposit (Tauern Window, Austria)

U–Pb SHRIMP analyses of zircons from various lithologies and ore bodies of the Felbertal scheelite deposit (western and eastern ore field) and neighbouring areas allow the reconstruction of the pre-Alpine magmatic and metamorphic processes responsible for the tungsten mineralization. The ore deposit belongs to the Magmatic Rock Formation, which is tectonically squeezed between the Habach Phyllite Formation and the Basal Schist Formation (all members of the Habach Group). In both the eastern and western ore field, the pre-mineralization geological processes are marked by the emplacement of basalts (547±27?Ma). Ensialic back-arc extension provided pathways for gabbroic and pyroxenitic melts as well as normal "I-type" granitoids (minimum crystallization age of 529±18?Ma). The rock assemblage forms a magmatic arc on an approximately 2?Ga continental Gondwana (?) margin. Post-emplacement tectonism and metamorphism have converted the basalts to fine-grained amphibolites, the gabbroic and pyroxenitic rocks to coarse-grained amphibolites and hornblendites, and the granitoids to leucocratic orthogneisses, respectively. Tungsten mineralization is intimately related to small patches and dikes of differentiated granitoids in the eastern ore field and the K2 ore body in the western ore field. The granitic melts have supposedly been generated by ongoing differentiation of calcalkaline magmas. They cut the older lithologies and intruded along the same pathways as the earlier melts. Fluids have been carried up along a major line in the eastern ore field. They caused the formation of an elongate ore body with a scheelite-quartz stockwork zone (scheelite-bearing quartz veinlets and veins) and an overlying, likewise elongate, 900-m-long, scheelite-rich quartzite lens. In the western ore field, accompanying fluids produced the K2 ore body. In this ore body, an eruption breccia occurs above a mineralized quartzite. The breccia (younger than 529±18?Ma) contains mineralized quartzite clasts as well as barren fine-grained amphibolite clasts and leucocratic orthogneiss-clasts that are similar to the surrounding host rock equivalents. The quartzite, which represents the main mineralization stage of the K2 ore body, is unsuitable for dating. However, the scheelite-rich quartzite lens of the eastern ore field is probably coeval. This lens locally lies on top of a differentiated and strongly mineralized gneiss. The crystallization age of this gneiss is 529±17?Ma, and marks the peak of tungsten input in the eastern ore field. Small, differentiated granitic dikes, which cut both the K2 eruption breccia and the K2 quartzite in the western ore field, contain only minor scheelite and mark a decrease in mineralization at 519±14?Ma. Thus, a period between 530 and 520?Ma and a setting between magmatic arc and (ensialic) back-arc may properly explain the likely scenario for the primary tungsten input (stage-1 scheelite) by differentiated granitic melts of calcalkaline character. Surprisingly, a second stage-2 scheelite formation was induced in the western ore field by a Variscan granite intrusion (K1–K3 gneiss; 336±19?Ma), the emplacement time of which is pre-dated by a cross-cutting dacitic dike of 340±5?Ma. This mineralization, which occurs in small quartz veins and within a quartz aureole atop the intrusion as well as an even younger mineralization in shear zones (yellowish-fluorescent stage-2 scheelite porphyroblasts), is bracketed between 355?Ma (the upper age limit of the K1–K3 gneiss precursor) and 335?Ma (the lower age limit of the dacitic dike, which is stage-2 scheelite free). Supposedly, long-lasting Variscan (amphibolite facies) metamorphic conditions till 282±2?Ma extended the scheelite remobilization. They caused a further dispersion of scheelite and induced the growth of individual grains and of rims around older grains (bluish-fluorescent stage-3 scheelite). The Alpine metamorphism of lower amphibolite to upper greenschist facies conditions caused a further, minor scheelite remobilization, especially along some faults and quartz veins, including sparse, but large, whitish-bluish-fluorescent crystals (stage-4 scheelite).     

渣滓溪大型脉状锑矿中钨矿化产出地质特征及找矿远景

渣滓溪大型脉状锑矿中异体共生有白钨矿化,受同一层位(岩性)、不同构造期次(类型)控制。矿区位于2条NE向区域性逆冲断层所挟持的抬升断块内,岀露地层为新元古界板溪群五强溪组浅变质的碎屑-火山碎屑沉积岩;已发现含钨矿化(体)层28层,层控(岩控)特征明显;白钨矿化主要呈细脉状产于岩石节理裂隙中。锑矿化富集段亦为钨矿脉富集段,钨与锑为同源不同期的产物。构造应力是完成元素活化、迁移和沉淀富集的主要成矿机制,矿床属于动力变质热液成因。区内含钨(体)层众多,成矿空间较大,具有侧伏延深、分段富集的特点,其找矿前景较好。     

江西香炉山钨矿床矽卡岩矿物和成矿花岗岩地球化学特征及其指示意义

江西香炉山大型钨矿床位于长江中下游成矿带南侧新识别的钨矿带西段,为一矽卡岩型白钨矿床.矽卡岩矿体主要产于中寒武统杨柳岗组含炭质灰岩和香炉山花岗岩接触部位.香炉山花岗岩具有细粒至中粗粒结构,主要由石英、钾长石、斜长石和黑云母组成,副矿物以钛铁矿为主.香炉山花岗岩的SiO2含量为66.37％～67.76％,并具有较高的Na...     

云南大坪金矿白钨矿惰性气体同位素组成及其成矿意义

利用高真空气相质谱系统测定了云南大坪金矿白钨矿流体包裹体的惰性气体同位素组成,得出其~3He/~4He为(0．988～1．424)×10~(-6),平均1．205×10~(-6),相应R/R_a为0．706～1．018,平均0．898,~(40)Ar/~(36)Ar为1801．8～2663．8,远高于大气~(40)Ar/~(36)Ar;~(20)Ne/~(22)Ne和~(21)Ne/~(22)Ne分别为9．600～11．56和0．028～0．0467,而~(134)Xe/~(132)Xe和~(136)Xe/~(132)Xe分别为0．394～0．692和0．301～0．462,均高于其相应大气值;He-Ar、Ne和Xe同位素组成显示大坪金矿成矿流体主要由深源地幔流体和地壳流体组成,其中基本不含大气饱和水。大坪金矿的形成与该区壳幔相互作用有关:该区喜山早期地壳拉张引起的地幔岩浆上涌和去气形成深源地幔流体,下地壳在上涌地幔烘烤下形成富含CO_2、~(40)Ar、~(134)Xe、~(136)Xe和~4He的地壳流体,它们混合以后沿韧性剪切带上升,水-岩反应和沸腾作用导致矿质沉淀。因此,大坪金矿属于剪切带控制的深源热液型金矿。     

延边杨金沟大型钨矿床白钨矿的微量和稀土元素地球化学特征与矿床成因

为确定杨金沟大型钨矿的成矿物质来源,本文运用白钨矿单矿物的微量元素、稀土元素特征加以示踪。ICP-AES测定结果显示:白钨矿亏损Mo、B i、Sn、Nb、Ta等,具有很低的Rb/Sr、Nb/Ta和Zr/H f值,指示其成矿物质具有壳源特征,而并非主要来自深源岩浆的结晶分异作用;不同白钨矿样品的REE组成基本一致,Eu元素出现明显的正Eu异常(δEu 2.21~4.43),基本未见Ce元素异常(δCe为0.92~1.08),表明白钨矿与流体之间稀土元素发生了强烈分异;白钨矿与赋矿围岩的REE球粒陨石标准化配分曲线形态相似,进一步显示五道沟群浅变质岩对杨金沟钨矿成矿物质的贡献。综合分析认为,杨金沟钨矿的成矿流体为源自上地幔的富含CO2的中高温流体,沿构造上升并与五道沟群浅变质岩发生交代作用引起黑云母等含钾矿物分解产生N2,最终形成富含W等成矿物质的NaC l-H2O-CO2-N2流体体系。随着构造减压作用,CO2不断逸出,破坏了矿液内物理化学体系的平衡,导致WO42-与Ca2+在适当物理化学条件下形成白钨矿。     

甘肃寨上金矿床中白钨矿矿体的发现及其特征

位于西秦岭礼（县）-岷（县）成矿带西段的寨上金矿床,是近年发现的一个大型微细浸染型金矿。在研究甘肃寨上金矿床物质组分的过程巾,笔者通过对岩矿石的等离子质谱分析和对矿物的反光显微镜下观察、电子探针分析,发现寨上金矿床存在白钨矿的富集体。根据化学成分圈定出了独立的白钨矿矿体．确认该矿床为金-钨-锑（自然金-白钨矿-辉锑矿）建造矿床。其与四川西北部马脑壳金－钨－锑矿床在地质背景、含矿岩石、矿化形式、矿物组合、元素组合和成矿过程相似。鉴于在川甘陕三角地带泥盆系－三叠系中类似寨上的金矿床、矿点众多．注意在此类金矿中分析和评价钨等有用组分,对提高金矿的综合利用价值是十分重要的。     

湖南包金山矿区白钨矿的地球化学特征及Sm-Nd同位素年代学

包金山金钨矿床位于湘中白马山-龙山-紫云山金矿带的东段,是近年新发现的一个赋存于前寒武纪浅变质岩中的金矿床.在野外调研和室内镜下研究的基础上,本文利用XRD、EMPA、ICP-MS、ID-MS等多种分析手段,对其进行了元素地球化学和同位素地球化学研究,进而揭示了该区金矿床的形成时代和矿床成因.研究表明,该区白钨矿的化学...