春风油田石炭系火山岩油气层综合判识研究

火山岩油气藏是一种特殊类型油气藏,受岩性、岩相、储集空间类型等因素影响较大。常规测井仅能对储层进行评价,录井仅能对岩性及油气显示进行评价。利用测录井资料无法快速判识油气层现状,制约了现场完井方式及试油方案的及时决策,并影响钻井周期、成本及对区块的潜力评价。通过岩心描述、镜下薄片储集空间及含油性观察,结合测井解释和试油结果,总结了春风油田石炭系火山岩油藏岩石类型及含油性特征;火山岩储集空间类型、影响因素、识别方法及物性有效性;孔隙、裂缝等储集空间有效性电性识别方法;建立了春风油田石炭系油气层综合判识准则。本次研究可快速对该区石炭系完钻探井进行油气层综合判识,指导现场完井方式决策,提高勘探效益。     

湖南省九龙山铅锌矿物化探异常综合分析与找矿前景

为进一步摸清九龙山地区区域化探异常与铅锌矿化之间的因果关系、成矿规律和控矿因素,投入1∶1万地质调查、土壤地球化学测量、岩石地球化学测量和激发极化法测量工作,通过综合分析,发现区内4个激电异常区与土壤异常形态相似,平面位置基本重叠吻合,且反映强烈。利用浅表槽探工程在异常中心处揭露到铅锌矿脉,长约760 m,平均厚度为1.40 m,铅平均含量为3.03%,锌平均含量为2.78%,说明九龙山勘查区成矿条件良好,矿产富集,未来深部找矿工作潜力较大。     

Rock Mass Characteristics in Beishan, A Preselected Area for China’s High-Level Radioactive Waste Disposal

Geological and hydrological characteristics, joint geometric features, rock physical and mechanical properties and rock mass quality are studied in the Beishan area, preselected for China’s high-level radioactive waste (HLW) disposal engineering. A comprehensive survey method is developed to study joint geometric features in the outcrop and samples from borehole BS06 into the Xinchang rock mass were tested. The optimal joint sets are determined by rose diagrams and equal-area lower hemisphere plots of joint poles. Results show that: 1) the distribution of joint occurrence obeys a normal distribution, while the distribution of joint spacing obeys a negative exponential distribution; 2) concentric circular and tangent circular sampling windows are applied to study the trace length and the trace midpoint density. Results indicate that tangent circular sampling window is more stable and reasonable; 3) Beishan granite shows high density, low porosity and high strength based on many laboratory tests and the physical properties and mechanical properties are closely related; and 4) a synthesis index, Joint Structure Rating (JSR), is applied to evaluate the quality of rock mass. Through the research results of rock mass characteristics, the Xinchang rock mass in the Beishan preselected area has the favorable conditions for China’s HLW disposal repository site.     

Late Triassic Biotite Monzogranite from the Western Litang Area,Yidun Terrane,SW China: Petrogenesis and Tectonic Implications

The Late Triassic igneous rocks in the Yidun terrane can provide vital insights into the evolution of Plaeo-Tethys in western China. We present new zircon U-Pb, whole-rock geochemistry, and Sr-Nd-Pb-Hf isotopic data for the Litang biotite monzogranites, Yidun terrane. The biotite monzogranites have a zircon U-Pb age of 206.1±1.0 Ma(MSWD=1.9,n=30), which indicates Late Triassic magmatism. The biotite monzogranites display I-type affinity, high Na_2O(3.38-3.60 wt%) contente,medii SiO_2(67.12-69.13 wt%), and low P_2 O_5 contents(0.10～0.12 wt%). They enriched in Rb,and Ba and depleted in Nb and Ta, with negative Eu anomalies(Eu/Eu*=0.74—0.81). They have evolved Sr-Nd-Pb-Hf isotopic composition, i.e.,(~(87) Sr/~(86 )Sr)i=0.714225 to 0.714763, negative ?_(Nd(t)) values of -2.0 to-2.6 with two-stage Nd model ages ranging from 1.01 to 1.05 Ga, negative ?_(Ht)(t)) values o f-3.4 to-4.1 with two-stage Hf model ages of 1.85 to1.88 Ga, suggesting a matured crustal sources. Their low Al_2O_3/TiO_2 ratios and medium Cao/Na_2O ratios, medium Mg~# and SiO_2 contents, low [molar Al_2O_3/(MgO+FeO~T)] values, and high [molar Cao/(MgO+FeO~T)] values indicate that the Litang biotite monzogranite was formed by partial melting of metabasaltic rocks. Based on the previous studies, we propose that the Litang biotite monzogranite derived from the westward subduction and closure of the Ganzi-Litang ocean during the Late Triassic-The mantle wedge-derived mafic melts provided sufficient heat for partial melting of ancient metabasalt protolith within the middle-lower crust.     

Geochemical Characteristics of Wuyang Siliceous Rocks in the Southern Margin of North China Craton and its Constraint on the Formation Environment of BIF of Tieshanmiao Formation

Precambrian banded iron formation(BIF) is one of the most important mineral resources in China, mostly abundant in the North China Craton(NCC) with relatively less common in South China. Since the BIF and siliceous rocks both originated from chemical deposition, the syngenetic BIF and Siliceous rocks can help evaluate their environment of formation. We examine here the mineralogy and geochemistry of siliceous rocks associated with the Tieshanmiao Formation BIF, aiming to decipher the conditions of formation of both BIF and Siliceous rocks in the Wuyang area in the NCC. Analysis of the geochemical characteristics of whole rock shows that the Si O2 content of the siliceous rock ranges from 90.11% to 94.85% and is relatively high overall. Trace element contents of Ba and U are also high, the Ba/Sr ratio ranges from 3.89 to 25.28 and the U/Th ratio ranges from 0.09 to 0.20. Finally, the ΣREE value of rare earth elements ranges from 57.03 ppm to 152.59 ppm, and these indexes all indicate that siliceous rock resulted from hydrothermal deposition. Plots of Al2 O3-Si O2, Si O2/(K2 O+Na2 O)-Mn O2/Ti O2 and Mn-10×(Cu+Co+Ni)-Fe in discrimination diagrams also verify this interpretation. However, both the Mg O content, ranging from 0.16 to 0.32, and the Fe/Ti ratio, ranging from 2.50 to 9.72, suggest that terrigenous material was added during the depositional process. Major and trace element parameters of siliceous rock, such as the Al/(A1+Fe+Mn) ratio(from 0.81 to 0.93), Mn O/Ti O2(from 0.00 to 0.17), Al/(Al+Fe)(from 0.82 to 0.93), Sc/Th ratio(from 0.21 to 0.50), U/Th(from 0.09 to 0.20),(La/Yb)N(from 0.83 to 3.04), and the(La/Ce)N(from 0.01 to 0.02) all imply that the siliceous rock formed in a continental margin. In addition, the Sr/Ba ratio from 0.08 to 0.26, the δCe value from 0.31 to 0.90, and the δEu value from 0.14 to 0.58, all indicate that the siliceous rock was formed at a relatively deeper water depth and under weak hydrodynamic conditions. Siliceous rock and BIF formed in the same geological setting, with the Si O2/(K2 O+Na2 O) ratio of siliceous rock ranging from 28.61 to 47.43, the Si O2/Al2 O3 ratio from 16.53 to 32.37, and the Si O2/Mg O ratio from 287.28 to 592.81, which are all in agreement with chemical deposition associated with volcanic eruptions. The Al2 O3/Ti O2 ratio from 37.82 to 50.30 indicates that the magma source of siliceous rock was of slightly intermediate composition. During the Late Archean in the Wuyang area, the high concentration and high purity Si O2 quickly precipitated from hydrothermal fluids to finally result in the accumulation of siliceous rock in a marginal sea, while the input corresponding to iron formation components was deposited to form iron formation layers, and limestone was only the product formed during the deposition intervals of siliceous rock and iron formations. In this study, the synsedimentary siliceous rocks of BIF act as a new way to provide direct evidence to understand the formation environment of BIF due to its high geochemical stability.     

济南西北部碳酸盐岩热储浅埋区热异常机理研究

为了探寻济南岩体北部碳酸盐岩热储浅埋地热异常区形成机理,利用地质钻探编录、抽水试验、测温、水质分析测试等手段,对碳酸盐岩浅埋地热异常区地质特征、热储物性特征、地温场特征、水化学特征等进行研究,结果表明：碳酸盐岩浅埋区热储层发育在奥陶纪灰岩地层中,热储层岩溶裂隙发育,热储埋深150~1000m,地热异常区盖层地温梯度为7. 2~11. 5℃/100m,水化学类型为SO4- Ca型,TDS为1. 3~1. 5g/L,地热水中含有对人体有益的微量元素,地热水来源为大气降水,地热水中50年以前入渗的“古水”占主导;明确了热源除正常的地温传导之外,济南岩体阻挡迫使水流深循环加热后上涌,断裂沟通深部热源等也是地热异常区形成的重要因素。     

蚀变粗面岩中再平衡结构黑云母的电子探针分析

黑云母的化学成分中蕴含着重要的成因信息,对具有交代结构的黑云母进行微区成分分析,能够精细反映交代蚀变过程中元素迁移情况,为解决矿床形成机制方面的科学问题提供矿物学证据。本文以北大巴山平利地区蚀变粗面岩中具有再平衡结构的黑云母斑晶为研究对象,进行电子探针面扫描和剖面成分分析。结果表明,斑晶内部为岩浆成因黑云母,边缘为"扩散-反应"过程所致的再平衡成因黑云母。斑晶边缘与内部相比,TiO_2含量由平均5.78%降至2.22%,表明在交代蚀变过程中黑云母中Ti等高场强元素被淋滤出进入流体;而CaO含量由平均0.06%升至0.14%,F含量由平均0.60%升至0.80%,指示蚀变流体内富含Ca、F等组分。本研究揭示了粗面岩中铌矿床的形成与热液作用关系密切,成矿流体中Ca、F等组分在铌元素的迁移及富集过程中具有重要作用。     

动能歧视模式ICP-MS测定地球化学样品中14种痕量元素

应用传统ICP-MS法测定勘查地球化学样品中Ag、Cd等痕量元素,基体效应和多原子离子干扰严重,准确测定的难度较大。本文基于当前ICP-MS消除干扰技术,分析了ICP-MS标准模式(STD)及动能歧视模式(KED)测定地球化学样品中Ag、Cd等14种痕量元素的有效性,通过比较这两种模式的测定效果,在此基础上确定了各元素的有效测定模式。结果表明:在KED模式下,基体元素如Zr、Nb氧化物的产率降低,基本上消除了Zr、Nb氧化物对痕量元素Ag、Cd的多原子离子干扰。KED模式提高了信噪比,降低了方法检出限,如Ag、Cd的检出限分别为0. 004mg/kg、0. 005mg/kg,其他12种元素的检出限也低于多目标地球化学调查76种元素分析方案中的检出限。测定痕量元素的准确度显著优于STD模式。实验中采用简单的硝酸-氢氟酸-高氯酸消解样品,残渣用王水复溶,结合KED模式下优选出干扰较小的同位素作为测定同位素,以Rh作为内标校正仪器产生的信号漂移,将样品溶液稀释至1000倍,基体效应降低至最小。本方法经国家一级标准物质的验证,测定结果与认定值相符,可为勘查地球化学提供高质量数据。     

云南省石漠化区耕地休耕对策研究

我国石漠化得到初步遏制的同时,发生在耕地上的石漠化面积却在增加。石漠化区的云南省和贵州省是我国休耕制度试点区域之一,但传统的石漠化治理缺乏休耕环节,耕地利用方式未能实现根本转型。基于休耕试点区域的实地调研,总结概括了云南省休耕试点工作的主要特点:（1）因地制宜整片推进;（2）签订休耕协议强化约束;（3）政府与农户联动落实休耕区域和面积;（4）休耕培肥方式元化化;（5）与农业结构调整对接;（6）与经济社会发展相统筹。但云南休耕试点也存在一些问题,主要是:（1）休耕区域的选择存在主观性;（2）配套资金缺口大;（3）休耕补助大幅减少造成群众心理落差;（4）休耕工作队伍建设薄弱。基于以上问题,建议:（1）建立休耕地诊断识别技术体系,明确休耕的规模和时序安排;（2）加强涉农项目和资金整合,增加配套资金投入,缓解基层财政压力;（3）建立动态的、反映土地市场价格的休耕补助机制,优化补助方式;（4）充实完善基层休耕组织机构,加强基层休耕工作队伍建设;（5）加快休耕监测体系建设,适时开展休耕制度运行绩效评估。      

西南地区某岩溶水库渗漏分析

西南地区某水库位于云贵高原中北部,库区可溶盐岩分布较广且岩溶较发育,中部有一条近南北走向的区域性断裂（F1）穿过两岸,为论证此水库成库的可能性,通过地表调查及物探,结果表明:此水库向低邻谷渗漏的可能性小,沿F1断裂带向南部或向下游渗漏的可能性问题不大,存在沿灰岩溶蚀通道向下游和向库外渗漏的可能性,沿左岸大理岩与灰绿岩接触带或大理岩向坝下游绕坝渗漏的可能性不大;水库正常蓄水位在Kc1底板高程以下有成库的可能。